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71.
将液晶基团引入到载流子传输材料中合成了新型液晶性噁二唑类衍生物E3和E6,利用偏光显微镜、差热扫描和广角X射线衍射的方法对其液晶性进行了研究,结果表明,E3为单向近晶型液晶,E6为双向近晶型液晶。同时,利用紫外—可见吸收光谱和电化学方法测定了材料的能级结构参数,其高的LUMO能级。低的HOMO能级(相对真空能级)及较大的带隙表明,它们不仅有利于电子从阴极的注入,还对空穴和激子具有一定的阻挡作用。由于材料在有序的近晶相比在无序的各向同性相将具有高的载流子迁移率,因此将液晶性与传输性相结合对提高材料载流子迁移率具有非常重要的意义。 相似文献
72.
采用分子动力学(MD)模拟方法,研究了二元体系中相分离过程、粒子的扩散系数以及相分离域尺寸大小随温度的变化规律.发现,相分离域随温度的生长过程可以分为两个阶段,分别是温度比较高的快速生长阶段和低温时的稳定生长阶段;相分离体系中系统的扩散激活能不是常数,而是一个随温度变化的函数,并且当温度高于60 K时,满足关系式E(T)=a+bTc.讨论了组元尺寸的变化对相分离过程的影响.结果表明,随两组元中某一组元
关键词:
相分离
扩散
分子动力学模拟 相似文献
73.
本文利用多尺度方法研究了包含孔洞金属材料在冲击加载条件下的动力学行为. 该多尺度方法结合了分子动力学和有限元方法,分子动力学方法运用于局部缺陷区域,而有限元方法运用于整个模型区域,两种方法之间使用桥尺度函数进行连接. 计算结果既包括了系统宏观的物理信息,如应变场、应力场、温度场等,也得到了微观原子的物理信息,如原子能量和位置坐标等. 结合以上的模拟结果,发现孔洞的坍塌与材料屈服强度和冲击强度有关,而孔洞坍塌和坍塌过程中对微喷射原子的压缩过程是形成局部热点的主要原因. 同时也发现孔洞坍塌形成的位错和局部热点可以导致局部绝热剪切带更容易形成.
关键词:
微孔洞
热点
冲击加载
多尺度方法 相似文献
74.
As is well known, the exact evolution equation of the curvature perturbation plays a very important role in investigation of the inflaorresponding exacttion power spectrum of the flat universe. However, the c extension for the non-flat universes has not yet been given clearly. Interest in the non-flat, specially closed, universes has been aroused recently. The need for this extension is pressing. We start with the most elementary physical consideration and obtain finally this exact evolution equation of the curvature perturbation for the non-flat universes, as well as the evolutionary controlling parameter and the exact expression of the variable mass in this equation. We approximately perform a primitive and immature analysis on the power spectrum of non-flat universes. This analysis shows that the exact evolution equation of the curvature perturbation for the non-flat universes is very complicated, and we need to carry out many numerical and analytic works for this new equation in the future to judge whether the universe is fiat or closed by comparison of theories with observations. 相似文献
75.
We present chaos synchronization between two new different chaotic systems by using active control. The proposed controller ensures that the states of the controlled chaotic response system asymptotically synchronizes the states of the drive system. Numerical simulations are shown to verify the result. 相似文献
76.
Effect of Alumina and Chromium Interlayers on Microstructures and Optical Properties of Thin Ag Films on Glass Substrates 下载免费PDF全文
Effects of alumina and chromium interlayers on the microstructure and optical properties of thin Ag films are investigated by using spectrophotometry, x-ray diffraction and AFM. The characteristics of Ag films in Ag/glass, Ag/l2O3/glass and Ag/Cr/glass stacks are analysed. The results indicate that the insertion of an Al2O3 or Cr layer decreases the grains and influences the reflectance of Ag films. The reflectance of the Ag film can be increased by controlling the thickness of alumina interlayer. The stability of Ag films is improved and the adhesion of Ag films on glass substrates is enhanced by alumina as an interlayer. 相似文献
77.
Molecular dynamics simulations are performed to investigate the behaviour of helium atoms in titanium at a temperature of 30OK. The nucleation and growth of helium bubble has been simulated up to 50 helium atoms. The approach to simulate the bubble growth is to add helium atoms one by one to the bubble and let the system evolve. The titanium cohesion is based on the tight binding scheme derived from the embedded atom method, and the helium-titanium interaction is characterized by fitted potential in the form of a Lennard-Jones function. The pressure in small helium bubbles is approximately calculated. The simulation results show that the pressure will decrease with the increasing bubble size, while increase with the increasing helium atoms. An analytic function about the quantitative relationship of the pressure with the bubble size and number of helium atoms is also fitted. 相似文献
78.
In this paper, the collective motion of self-driven robots is studied experimentally and theoretically. In the channel,the flowrate of robots increases with the density linearly, even if the density of the robots tends to 1.0. There is no abrupt drop in the flowrate, similar to the collective motion of ants. We find that the robots will adjust their velocities by a serial of tiny collisions. The speed-adjustment will affect both robots involved in the collision, and will help to maintain a nearly uniform velocity for the robots. As a result, the flowrate drop will disappear. In the motion, the robots neither gather together nor scatter completely. Instead, they form some clusters to move together. These clusters are not stable during the moving process, but their sizes follow a power-law-alike distribution. We propose a theoretical model to simulate this collective motion process, which can reproduce these behaviors well. Analytic results about the flowrate behavior are also consistent with experiments. 相似文献
79.
Using the diluted S1813 UV photoresist as a sacrificial layer, we successfully fabricate a superconducting suspended parallel-plate capacitor, in which the top layer of aluminum film acts as a membrane mechanical resonator. Together with a superconducting octagonal spiral inductor, this parallel-plate capacitor constitutes a superconducting microwave resonator. At m K temperature, the transmission characteristic and spectrum of the microwave resonator are measured.Sideband frequencies caused by the vibration of the membrane mechanical resonator are clearly demonstrated. By downconverting with a mixer, the dependence of fundamental frequency and its harmonics on the input microwave power are clearly demonstrated, which is consistent with the numerical simulation. 相似文献