磷化氢与烯烃反应的原位NMR谱研究

本文应用加压原位(in-situ)核磁共振技术,在反应温度70～75℃,压力1.0～2.0MPa,氘代苯为溶剂,偶氮二异丁腈(AIBN)为引发剂的条件下探索了磷化氢与丙烯腈,4-乙烯基吡啶,烯丙基胺,丙烯酰胺,氨基吡啉和N-乙烯基咔唑的自由基加成反应,结果表明除氨基吡啉之外的其它五种含氮化合物均能与磷化氢发生反应,从而找到合成含氮有机膦的良好路线。     

Improvement of Security of Three-Party Quantum Secure Direct Communication Based on GHZ States

A protocol for three-party quantum secure direct communication based on Greenberger-Horne-Zeilinger （GHZ） states was recently proposed by 3in et al. [Phys. Lett. A 354 （2006） 67] By analysing the protocol we find some security loopholes, e.g. one bit of secret messages of a party （Alice in the original paper） can always be leaked straight to the public without any eavesdropping. These problems suggested previously are discussed and possible solutions are presented to improve the security of the original protocol.     

Experimental Study on Electrostatic with Two Guiding of Supersonic D20 Molecular Beam Charged Wires

We demonstrate the guiding of a supersonic heavy-water （D2O） molecular beam using a hollow electrostatic field generated by the combination of two parallel charged-wires and two grounded metal-plates, and report some new and preliminary experimental results. In the experiment, we detect the guiding signals by using the method of time-of-flight mass spectrum and study the dependence of the relative transmission of the beam guide on the guiding voltage. Our study shows that the relative transmission of the beam guide is increased linearly with increasing guiding voltage Vguid, and the number of the guided D20 molecules is at least increased by 89.4% when the guiding voltage is ＋20.0k V. Finally, some potential applications of our guiding scheme in the molecule optics are briefly discussed.     

Hydrogen Passivation Effect on Enhanced Luminescence from Nanocrystalline Si/SiO2 Multilayers

Nanocrystalline Si/SiO2 multilayers are prepared by thermally annealing amorphous Si/SiO2 stacked structures. The photoluminescence intensity is obviously enhanced after hydrogen passivation at various temperatures. It is suggested that the hydrogen trapping and detrapping processes at different temperatures strongly influence the passivation effect. Direct experimental evidence is given by electron spin resonance spectra that hydrogen effectively reduces the nonradiative defect states existing in the Si nanocrystas/SiO2 system which enhances the radiative recombination probability. The luminescence characteristic shows its stability after hydrogen passivation even after aging eight months.     

对用稳定图识别真假模态的一点改进

利用单位样值响应矩阵和自由响应的特征值分解形式中的特征值前的系数矩阵的范数作稳定判据，结合稳定图识别真假模态，计算表明，本方法具有较好的分解能力。     

高温超导体Bi_(1.6)Pb_(0.4)Ca_2Sr_2Cu_3O_y中的表面超导相

在 Bi_(1.6)Pb_(0.4)Ca_2Sr_2Cu_3O_y 样品中存在着110K 和85K 两个超导相,样品的零电阻温度为105K.磁化率、比热以及不同温度下的 M-H 曲线测量结果均表明85K 相为表面超导相,在样品中占有较小的体积分数.文中还报道了样品的H_(c1)(0).     

半导体和金属表面的超快动力学

时间标度为Ps(微微秒)和fs(毫微微秒)的超快激光光谱在研究固体的动力学性质方面已经取得很大的进展.在体材料和人造层状结构材料(如超晶格)中,用这种方法已经细致地研究了各种弛豫和输运现象.但是直到最近,超快激光技术才应用于研究表面和界面的动力学现象,这是因为大多数光学技术对表面现象是不敏感的.以前要取得表面动力学过程情况的唯一手段是测量光谱线的线宽,这种实验取决于假定光谱线宽纯粹是由寿命加宽引起的.但是在固体中常常遇到光谱线的各种非均匀加宽,使得实验分析变得困难和复杂.所以,最好的方法就是采用时间过程的直接测量.…     

基于免疫磁性纳米球快速高效准确检测淋巴结转移癌细胞

发展了一种基于免疫磁性纳米球(IMNs)快速、高效、准确检测淋巴结转移癌细胞(LNMCCs)的策略.首先利用本课题组发展的方法制备了具有磁性和生物靶向双功能的IMNs,然后利用IMNs通过免疫磁分选对淋巴结转移癌病人淋巴结穿刺物中的LNMCCs进行分离和富集,最后采用瑞氏染色法和免疫细胞化学(ICC)对富集的LNMCCs进行鉴定,实现对LNMCCs的快速高效准确检测.免疫磁分选实现了LNMCCs的分离和富集,可以有效降低淋巴结穿刺物中的背景干扰;瑞氏染色法和ICC鉴定为准确诊断提供了更多可靠依据,因此,传统细胞学敏感性、特异性和诊断准确率不高的问题得到明显改善.其次,淋巴结穿刺物与IMNs的孵育只需5 min,简便快速,完整保留了LNMCCs的形态学特征,为淋巴结转移癌(LNMC)的分类和后续病理学分析提供了重要基础.此外,IMNs对淋巴结穿刺物中上皮来源癌细胞的特异性捕获可以确诊捕获的细胞为LNMCCs,实现了LNMC和恶性淋巴瘤的鉴别诊断.最后,采用本方法检测了110例病人淋巴结穿刺物中的LNMCCs,总诊断准确率高达98.2%,特异性为100.0%,敏感性为98.0%,相比于传统细胞学诊断都有明显的提高.因此,IMNs用于LNMC病人淋巴结穿刺物中LNMCCs的检测是一次新的尝试,为LNMC的诊断和研究提供了新思路.