用改进的sol-gel法制备锆钛酸铅薄膜及其物相转化的研究

利用改进的solgel法,在Pt/Ti/SiO2/Si衬底上制备了PbZr0.5Ti0.5O3(PZT50/50)薄膜.采用了一种新的方式,从同一前驱体溶液得到了厚度各异的单一退火层.研究了薄膜的结构和性质随单层退火厚度的改变而发生的变化,发现随着单一退火层厚度的降低,薄膜(111)取向的程度增大,同时薄膜的剩余极化和介电常量也逐渐增高.当单一退火层厚度降低到约为40nm时,可得到高度(111)择优取向的PZT薄膜.从薄膜成核机理的基础上讨论了薄膜结构变化的内在因素,认为随单一退火层厚度的增加薄膜由单一的 关键词：     

载流线圈的磁矩及其在均匀磁场中所受磁力矩公式的普遍证明

文章从对电流元所受磁力矩的积分出发,得出了任意载流线圈的磁距及其在均匀磁场中所受磁力矩。     

Optical Properties of Plate-Shaped ZnO Nanocrystals Grown by a Facile and Environmentally Friendly Molten Salt Method

Plate-shaped ZnO nanocrystals are prepared by a facile and environmentally friendly molten sMt method, in which ZnD（CO3）2（OH）6 nanorods are first synthesized via a facile one-step, solid-state reaction route at room temperature and then decomposed in NaCI flux. Photoluminescence property demonstrates that the as-prepared plate-shaped ZnO nanocrystals exhibit a strong blue emission centered at about 483nm. Raman scattering spectrum reveals that the as-prepared plate-shaped ZnO nanocrystals have the oxygen deficiency, which can be confirmed by the appearance of oxygen-deficiency-related vibrationM mode at 583 cm-1 in the Raman spectrum. The oxygen deficiency existing in the plate-shaped ZnO nanocrystals results in the formation of the oxygen vacancy, which is most likely responsible for the strong blue emission of the plate-shaped ZnO nanocrystals. These new plate-shaped ZnO nanocrystals with strong blue emission are expected to show considerable potential applications in luminescence, lasing and optoelectronic devices.     

Ⅱ-Ⅵ族半导体研究概观

回顾了Ⅱ－Ⅵ族半导体材料的研究状况．结合国际上的最新研究动态,总结出Ⅱ－Ⅵ族半导体材料研究的主要方向：（１）ｐ型掺杂研究;（２）ｐ型Ⅱ－Ⅵ族半导体的欧姆接触;（３）Ⅱ－Ⅵ族外延结构中的电子、激子与增益;（４）量子线、量子点及稀磁半导体。     

高压类氢原子能量与极化率的另一种计算

 本文采用新的试探波函数，对于关闭在半径为r₀球壳内的类氢原子模型，计算了其能量和极化率随球壳半径r₀和相应压强的变化规律。同文献[1]的结果相比，有明显的改善。     

Intertwisted fibrillar diamond-like carbon films prepared by electron cyclotron resonance microwave plasma enhanced chemical vapour deposition

In this paper, the structures, optical and mechanical properties of diamond-like carbon films are studied, which are prepared by a self-fabricated electron cyclotron resonance microwave plasma chemical vapour deposition method at room temperature in the ambient gases of mixed acetylene and nitrogen. The morphology and microstructure of the processed film are characterized by the atomic force microscope image, Raman spectra and middle Fourier transform infrared transmittance spectra, which reveal that there is an intertwisted fibrillar diamond-like structure in the film and the film is mainly composed of sp^3 CH, sp^3 C—C, sp^2 C═C, C═N and C_{60}. The film micro-hardness and bulk modulus are measured by a nano-indenter and the refractive constant and deposition rate are also calculated.     

Comparison of Properties of Pt/PZT/Pt and Ru/PZT/Pt Ferroelectric Capacitors

Pb（Zr0.4Ti0.6）O3 film prepared by sol-gel spin coating on a Pt/Ti/SiO2/Si substrate is applied to ferroelectric capacitors with Pt or Ru as the top electrode. For the Pt/PZT/Pt and Ru/PZT/Pt ferroelectric capacitors, although with the same ferroelectric film, different top electrode materials incur different properties of PZT capacitors, such as fatigue, leakage, remanent and saturated polarization, except the similar crystal orientations of the PZT film. After 10^10 switch cycles, the remanent polarizations of the Ru/PZT/Pt and Pt/PZT/Pt capacitors decrease to 70% and 84%, respectively. The leakage current density of the latter increases obviously at positive bias after 108 switch cycles, compared with the former. Different materials for the top electrode bring different conditions at the PZT/top electrode interface. The influence of oxygen-vacancy concentration at the PZT/electrode interface and the influence of oxides of the electrode material at the PZT/electrode interface to charge injection can explain the difference of properties of the PZT capacitors with Pt or Ru as the top electrodes.     

讲授电磁波辐射与传播的一种方法

本文从电流激发的磁场出发，通过变化的磁场激发电场描述了电磁波的发射与传播，学生易于理解，电磁波的性质也易于说明。     

有限元法模拟混合物的冲击压缩特性

 将混合物作为组元颗粒在空间的随机排列,采用三维动力有限元程序模拟其冲击压缩特性。给出了以铜和铝两种金属单质组成的混合物算例,与用“叠加原理”计算的结果作了比较。     

锂硼钒酸盐玻璃的11B核磁共振研究

用¹¹B连续波核磁共振谱研究了锂硼钒酸盐玻璃的结构,测量了BO₄,BO_3s和BO_3A各结构单元的比例。实验表明,锂硼钒酸盐玻璃中N₄的最大值近似为一常数,与V₂O₅的含量无关。Li₂O被V₂O₅和B₂O₃分享。并推测V₂O< 关键词：