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DNA-binding properties of the dinitratobis(phen) cadmium complex [Cd(phen)2(NO3)2] (where phen = 1,10-phenanthroline) have been investigated with absorption titration, fluorescence spectroscopy, viscosity measurement, molecular modeling and density functional theory (DFT) calculations. The results indictate DNA-binding mode of the complex to be weak groove binding rather than partial intercalative interaction expected of the extended planar aromatic phen ring. In addition, the DNA cleavage study was carried out by gel electrophoresis experiment. The results showed that the complex both hardly cleaves pBR322 DNA in the absence and present ascorbate. So it is suggested that the formation of cadmium complex can decrease cadmium toxicity to some extents. 相似文献
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针对具有共因故障的温贮备并联可修系统模型,用范数指标泛函作为衡量系统可控性的标准,利用Banach空间理论讨论了系统稳态解达到预期概率分布的最优控制问题. 相似文献
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In this paper, we show that the invertible operator T, which is a bounded linear functional on a separable Hilbert space H, could factor as T=US, where U is unitary and 5 belongs to width-two CSL algebra alg(?)((?)= M∨N) when nest M or N is a countable nest, or S belongs to alg(?)-1 when nests M and N are countable nests. For the factorization of nest,we obtain that T factors as T=US where S∈DN-1 and U is unitary as N be a countable nest. 相似文献
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Motion estimation based on an improved block matching technique 总被引:2,自引:0,他引:2
An improved block-matching algorithm for fast motion estimation is proposed. The matching criterion is the sum of absolute difference. The basic idea is to obtain the best estimation of motion vectors by an optimization of the search process which can terminate the time-consuming computation of matching evaluation between the current block and the ineligible candidate block as early as possible and eliminate the search positions as many as possible in the search area. The performance of this algorithm is evaluated by theoretic analysis and compared with the full search algorithm (FSA). The simulation results demonstrate that the computation load of this algorithm is much less than that of FSA, and the motion vectors obtained by this algorithm are identical to those of FSA. 相似文献
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两种[Ln(TTA)4].HP (Ln =Yb, Er)配合物被合成并表征。通过紫外可见光谱、荧光光谱、粘度和分子模拟研究了他们与DNA的键合特征。研究结果表明:它们能插入双链的DNA。更重要的是它们的荧光强度能被DNA增强,因此,一种灵敏的荧光检测DNA的方法被发展。两种配合物与质粒DNA的切割反应在凝胶电泳上展开。有意义的是,我们发现在pH=7.2 和 37℃下,两种化合物都能切割超螺旋质粒DNA。另外,我们选择BDNPP作为模型化合物进一步研究了它们对质粒DNA的切割机理,从一级动力学方程,我们间接证明可能是水解切割机理。 相似文献
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利用中频非平衡磁控溅射技术在单晶硅基底上沉积了类石墨碳膜, 采用Raman光谱、高分辨透射电子显微镜、原子力显微镜分析了薄膜微观结构和表面形貌; 采用纳米压痕仪和CSM摩擦磨损试验机测试了碳膜力学性能和摩擦学性能. 结果表明: 利用中频非平衡磁控溅射技术沉积的碳膜是一种以sp2键合碳为主、结构非晶、硬度适中、应力较低、表面粗糙度较大、摩擦性能优异的薄膜. 脉冲占空比对薄膜微观结构和性能有显著影响, 随着脉冲占空比的增大, Raman光谱D峰和G峰的强度比ID/IG先减小后增大, 而硬度随脉冲占空比的增大却呈现出相反的变化趋势, 即先增大后减小; 大气氛围中的摩擦性能测试表明, 本实验制备的薄膜具有优异的抗磨性能(~10-11 cm3/N-1. m-1)和承载能力(~2.5 GPa). 随脉冲占空比的增大, 薄膜摩擦系数变化甚微而磨损率却呈现先显著减小后轻微增大的变化趋势. 类石墨碳膜优异的摩擦学性能主要归因于其独特的结构、较低的内应力及良好的结构稳定性. 相似文献
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针对实验中磁场对超冷原子团温度和密度的测量的影响,提出了用三组轴向相互垂直的线圈产生的磁场来补偿的理论模型,并根据实验条件对理想模型进行修正.通过这个理论模型,不仅能达到空间某点磁屏蔽的要求,而且可以准确预计有关实验环境的磁感应强度分布. 相似文献