美、法化学家分享1987年诺贝尔化学奖

1987年诺贝尔化学奖被授予法国路易斯巴斯德大学的Jean-Marie Lehn、美国加利福尼亚大学的Donald J.Cram和杜邦公司现已退休的Charlcs J.Pedersen。他们由于创建了“超分子的”化学或称“主宾”化学(guest-host)荣膺此誉。     

“FLUID ROLLER BEARING” EFFECT AND FLOW CONTROL

Owing to the rapid development of smart materials, flow control by travelling waves (TW) produced on flexible skin is becoming a very promising new area of research. One of the most revolutionary concepts of using TW technique is to trap a row of controllable vortices over the body surface, which plays a role of “fluid roller bearing” (FRB) between the external flow and the solid wall. The FRB can replace the conventional boundary layer and hence remove the latter‘‘s various unfavorable effects. This paper reports our preliminary numerical study of the FRB effect on flow over several typical walls, especially an airfoil with FRB at the stall angle of attack, which has never been considered before. Significant improvement of aerodynamic performance on the FRB-airfoil is observed, which strongly suggests that the FRB effect may open a brand new avenue to the 21th-Century aerodynamics.     

Investigation of side chain liquid crystal polymers bearing cholesterol and bile acid derivatives

Cholic acid (or 3α,7α,12α-trihydoxyl-5β-cholan-24-oic acid) and lithocholic acid (or 3α-hydroxyl-5β-cholanic-24-oic acid) are commonly occurring bile acids synthesized from cholesterol in the liver in mammals. They all possess a steroid skeleton containing four rings, three with six carbons and one with five carbons. The transformation of cholesterol to cholic acid results in two major structural changes that affect the steroid skeleton. The first is the hydrogenation of the double bond …     

两种晶型酞菁氧钒纳米颗粒的制备及形成机理

在水溶液中利用激光消融制备了酞菁氧钒(VOPc)相I型纳米颗粒，在加入一种非离子型表面活性剂的情况下通过激光消融制备得到了其相II型纳米颗粒.X射线衍射(XRD)、紫外可见吸收光谱(UV-Vis)和傅立叶变换红外光谱(FT-IR)表征了其纳米颗粒中的晶体结构.扫描电子显微镜(SEM)观察显示相I和相II型酞菁氧钒纳米颗粒的直径分别约为100和60 nm.对相II型酞菁氧钒纳米颗粒的形成机理进行了讨论.     

尿中五种麻黄素类药物的气相色谱分离与测定

麻黄素类药物具有较强的中枢兴奋作用,但在体育运动竞赛中大剂量地使用,是不正当的,国际奥委会已将麻黄素、去甲麻黄素、去甲伪麻黄素、甲基麻黄素列入禁用的兴奋剂药物之内,这些药物化学结构相近,其中麻黄素与伪麻黄素、去甲麻黄素与去甲伪麻黄素为两对非对映异构体,甲基麻黄素、麻黄素与去甲麻黄素三者之间和伪麻黄素与去甲伪麻黄素二者之间具有药物代谢关系,因此寻找一个既能分离又能同时准确定量这5种麻黄素类药物     

空间中半光滑算子方程的不精确牛顿法}

In this paper, we propose two inexact Newton methods forlocally Lipschitzian semismooth function and prove their local convergence results under some conditions. The present inexact Newton methods could be viewed asthe extensions of previous ones with same convergent results in finite-dimensional space.     

On the number of \(n\)-dimensional invariant spheres in polynomial vector fields of \(\mathbb{C}^{n+1}\)

We study the polynomial vector fields \(\mathcal{X}= \displaystyle \sum_{i=1}^{n+1} P_i(x_1,\ldots,x_{n+1}) \frac{\partial}{\partial x_i}\) in \(\mathbb{C}^{n+1}\) with \(n\geq 1\) . Let \(m_i\) be the degree of the polynomial \(P_i\). We call \((m_1,\ldots,m_{n+1})\) the degree of \(\mathcal{X}\). For these polynomial vector fields \(\mathcal{X}\) and in function of their degree we provide upper bounds, first for the maximal number of invariant \(n\)-dimensional spheres, and second for the maximal number of \(n\)-dimensional concentric invariant spheres.