光刻与等离子体刻蚀技术

介绍了光刻与等离子体刻蚀技术的特点与进展,阐述了等离子体刻蚀的物理机制与前沿问题。     

再生大骨料自密实混凝土梁裂缝开展机理研究

再生大骨料自密实混凝土梁的裂缝开展机理作为梁结构可靠性设计的理论基础,具有重要的工程意义。本文对不同再生大骨料取代率的再生大骨料自密实混凝土梁进行了数值仿真模拟,分析了再生大骨料自密实混凝土梁的裂缝开展情况和荷载-挠度曲线。结果表明,采用随机骨料模型对再生大骨料自密实混凝土梁进行裂缝开展模拟的方法可行;裂缝主要沿着再生大骨料和自密实混凝土交界面扩展,少部分经过再生大骨料;不同再生大骨料取代率的再生大骨料自密实混凝土梁的裂缝开展机理相同;相比自密实混凝土,再生大骨料自密实混凝土梁的承载力降低,脆性增强。     

固体中时间反转法的声束自聚焦

时间反转是一种很有用的自适应聚焦技术。本文中我们进行了声束在固体中运用时间反转方法的自适应聚焦研究。理论分析和实验结果表明时间反转可补偿固体中各声线的程差,从而同时实现纵波和横波的自聚焦。聚焦增益的理论值和实验结果较好地符合。     

焦度计综述

介绍各种国产焦度计的原理,对国外自动焦度计作了较为详细的叙述.对目视式焦度计、投影式焦度计和自动焦度计的结构和工作原理分别作了详细的介绍,最后论述了各种焦度计的主要特点及优缺点.     

Bi4O5Br2光催化剂的制备及可见光降解卡马西平的活性研究

采用水解法合成了Bi_4O_5Br_2光催化剂,并通过XRD、SEM和DRS等手段对催化剂的结构、形貌和光吸收性质进行了表征。结果表明,催化剂呈不规则片状结构,其带隙能为2.1eV,价带电位E_(VB)和导带电位E_(CB)分别为2.61和0.51 eV。基于反应原理和表征结果,提出了催化剂形成机理。在可见光照射下,Bi_4O_5Br_2对卡马西平表现出高效的光催化氧化活性,光照120min后,卡马西平的降解率超过90%,反应动力学速率常数k达到0.018min~(-1)。捕获剂实验结果表明卡马西平降解过程中的主要活性物质是光生空穴(h~+)和超氧自由基阴离子(·O~-_2)。致畸作用实验结果表明,可见光照射120min后,卡马西平溶液基本上没有污染。此外,Bi_4O_5Br_2光催化剂在光催化降解卡马西平过程中表现出较高的化学稳定性和可重复性,表明其具有实际应用的潜力。     

Numerical study of converting beat-note signals of dual-frequency lasers to optical frequency combs by optical injection locking of semiconductor lasers

The optical injection locking of semiconductor lasers to dual-frequency lasers is studied by numerical simulations. The beat-note signals can be effectively transformed to optical frequency combs due to the effective four wave-mixing in the active semiconductor gain medium. The low-noise Gaussian-like pulse can be obtained by locking the relaxation oscillation and compensating the gain asymmetry. The simulations suggest that pulse trains of width below 30 ps and repetition rate in GHz frequency can be generated simply by the optical injection locking of semiconductor lasers. Since the optical injection locking can broaden the spectrum and amplify the optical power simultaneously, it can be a good initial stage for generating optical frequency combs from dual-frequency lasers by multi-stage of spectral broadening in nonlinear waveguides.     

温和条件下钌/氮掺杂碳纳米笼的苯乙酮选择性催化加氢性能

共轭羰基化合物的羰基选择性加氢反应被广泛用于制备重要的药物和化学中间体.利用氮掺杂碳纳米笼（hNCNC）大的比表面积和掺杂氮原子的锚定作用,构建了10 wt% Ru负载量的Ru/hNCNC催化剂,尺寸约2.4 nm的Ru纳米颗粒高度均匀地分散在hNCNC表面.用于催化苯乙酮选择性加氢制1-苯乙醇,在50.0℃、2.0 MPa H₂的温和条件下,展现出优异的催化加氢性能：反应2.0 h后的苯乙酮转化率和1-苯乙醇选择性分别达到96.2%和95.8%,远优于未掺杂碳纳米笼（hCNC）和活性炭负载的Ru催化剂;循环使用6次后,其苯乙酮转化率仅略有下降（从96.2%到94.0%）,明显优于Ru/hCNC.Ru/hNCNC的优异催化性能可归因于：hNCNC大的比表面积和掺杂氮原子的锚定作用有利于Ru纳米粒子的分散和固载、独特的微孔-介孔-大孔共存的分级孔结构有利于传质、掺杂氮原子有效调变了Ru催化剂的电子结构.     

High quality PdTe_2 thin films grown by molecular beam epitaxy

PdTe_2,a member of layered transition metal dichalcogenides(TMDs),has aroused significant research interest due to the coexistence of superconductivity and type-II Dirac fermions.It provides a promising platform to explore the interplay between superconducting quasiparticles and Dirac fermions.Moreover,PdTe_2 has also been used as a substrate for monolayer antimonene growth.Here in this paper,we report the epitaxial growth of high quality PdTe_2 films on bilayer graphene/SiC(0001)by molecular beam epitaxy(MBE).Atomically thin films are characterized by scanning tunneling microscopy(STM),X-ray photoemission spectroscopy(XPS),low-energy electron diffraction(LEED),and Raman spectroscopy.The band structure of 6-layer PdTe_2 film is measured by angle-resolved photoemission spectroscopy(ARPES).Moreover,our air exposure experiments show excellent chemical stability of epitaxial PdTe_2 film.High-quality PdTe_2 films provide opportunities to build antimonene/PdTe_2 heterostructure in ultrahigh vacuum for future applications in electronic and optoelectronic nanodevices.     

一类具有标准发生率和双垂直传播的媒介传染病模型分析

建立了一类具有标准发生率和双垂直传播的媒介传染病模型,通过构造Lyapunov函数,利用LaSalle不变集原理等理论,证明了无病平衡点和地方病平衡点的存在性和稳定性,并对其进行数值模拟.得出通过采取降低人群与媒介之间接触率或者提高医疗水平等措施,能够控制疾病的蔓延.     

Enzymatic Enantioselective Synthesis of （R）－2－Trimethylsilyl－2－hydroxyl－propionitrile by Defatted Apple Seed Meal

IntroductionOverthepastyears ,thesynthesisofchiralaldehyde cyanohydrinswaswellstudied .1Incontrasttochiralalde hyde cyanohydrins ,therewereonlyfewreportsaboutthepreparationofopticallyactiveketone cyanohydrins ,2 whichareusefulstartingmaterialsandintermediatesforthesyn thesisofmanychiralnaturalproducts .3Wethereforefo cusedonthepreparationofopticallyactivesiliconcontain ing (R ) ketone cyanohydrin ((R ) 2 trimethylsilyl 2 hy droxyl propionitrile)usingacetonecyanohydrinastran scyanationagen…