Solid solubility and photoluminescence of Y_3Al_5O_(12):Ce~(3+)prepared by using(Y_(1-x)Ce_x)_2O_3 as precursor

Trivalent cerium-doped yttrium aluminum garnet(YAG:Ce3+) phosphors are synthesized by solid-state reaction method through using(Y1-xCex)2O3 solid solutions as precursors. Solid solubility limits of Ce3+replacing Y3+in Y2O3and YAG are determined to be 40% and 7.5%, respectively, based on the relationship between the lattice parameter and chemical composition. Using(Y1-xCex)2O3 as precursors we synthesize YAG:Ce3+single phase at 1450°C and N2atmosphere. However, under the same conditions using CeO2there exists a second phase YAlO3as impurity. The photoluminescence intensity of YAG:Ce3+increases monotonically with the increase of Ce concentration until it reaches a maximum at solid solubility limits of Ce3+in YAG.     

预制层中Zn和ZnS对CZTS薄膜太阳电池的影响

采用磁控溅射后硫化的方法制备Cu2 ZnSnS4 (CZTS)薄膜,分别用Zn和ZnS作为锌源,在镀钼的钠钙玻璃衬底上以Zn(或ZnS)/Sn/Cu的顺序制备出不同的CZTS薄膜预制层.首先对预制层进行低温合金,然后以硫粉作为硫源进行高温硫化,得到CZTS薄膜.通过X射线衍射仪(XRD)、扫描电镜(SEM)及能谱仪(EDS)分别对所制备薄膜的晶体结构、表面形貌和薄膜组分进行分析表征;并用拉曼光谱表征了CZTS相的纯度.最后用CZTS薄膜制备了太阳电池,发现在预制层中以ZnS作为锌源得到的太阳电池有较高的性能参数,其开路电压:V =651 mV,短路电流密度:Jsc=11.4 mA/cm2,光电转换效率达到2.8;.     

不同镉源制备铜锌锡硫电池缓冲层的研究

目前制备CZTS薄膜太阳电池的缓冲层绝大多数采用硫酸镉作为镉源.本文将主要介绍用醋酸镉((Ch3COO)2Cd)、氯化镉(CdCl2)和硝酸镉(Cd(NO3)2)和硫酸镉(CdSO4)四种不同的镉源制备硫化镉薄膜.通过X射线衍射仪(XRD)、扫描电子显微镜(SEM)和紫外可见分光光度计对硫化镉薄膜的结构、表面形貌和光学性能进行分析研究.分析结果表明以硝酸镉为镉源制备的硫化镉薄膜最适合作为缓冲层使用.将不同镉源制备的硫化镉薄膜作为CZTS薄膜电池的缓冲层,制备出的电池效率分别为:1.83;((Ch3COO)2Cd)、2.89;(CdCl2)、3.4;(Cd(NO3)2)、3.19;(CdSO4).     

Controlling chaos in power system based on finite-time stability theory

Recent investigations show that a power system is a highly nonlinear system and can exhibit chaotic behaviour leading to a voltage collapse, which severely threatens the secure and stable operation of the power system. Based on the finite-time stability theory, two control strategies are presented to achieve finite-time chaos control. In addition, the problem of how to stabilize an unstable nonzero equilibrium point in a finite time is solved by coordinate transformation for the first time. Numerical simulations are presented to demonstrate the effectiveness and the robustness of the proposed scheme. The research in this paper may help to maintain the secure operation of power systems.     

具有两类失效模式和修理工休假的重试系统可靠性分析

本文考虑具有两类失效模式和Bernoulli休假的可修表决重试系统,系统中每个部件或者正常工作,或者以概率p类型a失效,或者以概率1-p类型b失效.修理工修理完一个部件后,可能以概率h进行休假,也可能以概率1-h在系统中空闲.系统中没有等待空间,失效部件如果不能立即得到修理,则进入重试空间,一段时间后再进行重试,直到得到修理.利用马尔可夫过程理论和拉普拉斯变换等方法,得到了系统的稳态可用度、可靠度函数和系统首次故障前平均寿命等可靠性指标.通过数值例子分析了系统参数对可靠性指标的影响.     

Y3AlsO12.t：e prepared Solid solubility and photoluminescence of YeAl5O12：Ce3＋ preparedby using （Y1-xCex）203 as precursor

Trivalent cerium-doped yttrium aluminum garnet （YAG：Ce3＋） phosphors are synthesized by solid-state reaction method through using （Yl-xCex）203 solid solutions as precursors. Solid solubility limits of Ce3＋ replacing y3＋ in Y203 and YAG are determined to be 40% and 7.5%, respectively, based on the relationship between the lattice param- eter and chemical composition. Using （Y1-xCex）203 as precursors we synthesize YAG：Ce3＋single phase at 1450 ~C and N2 atmosphere. However, under the same conditions using CeO2 there exists a second phase YA103 as impurity. The photoluminescence intensity of YAG：Ce3＋ increases monotonically with the increase of Ce concentration until it reaches a maximum at solid solubility limits of Ce3＋ in YAG.     

球面稳定同伦群中的一族新元素及h0b12在π*V(1)中的收敛性

对连通有限型谱X,Y,存在着Adams谱序列(ASS){Ers,t,dr}满足(1)drErs,t→Ers+r,t+r-1是谱序列的微分,(2)E2s,t≌ExtAs,t(H*(X),H*(Y)),(3)并且收敛到[∑t-sY,X]p.当X是球谱S,Moore谱M,Toda-Smith谱V(1)时,(πt-sX)p分别为S,M,V(1)的稳定同伦群.本文通过Adams谱序列,发现了球谱S的稳定同伦群中的一族非零元素~γth0b02及Toda-Smith谱V(1)的稳定同伦群中的非零元素h0b12.在利用Adams谱序列求解同伦群的过程中,需要计算有关ExtAs,t(H*X,H*Y)的结果.利用谱的上纤维序列导出的Ext群的正合序列和May谱序列,得出ExtAs,t(H*X,H*Y)的某些结果.本文令p≥7为奇素数,q=2(p-1).     

电导率各向异性金属薄板感应式磁声图像的仿真

为了给金属薄板感应式磁声(MAT-MI)成像算法的研究提供数据源,提出一种电导率各向异性金属薄板表面MAT-MI图像的数值仿真方法。建立含缺陷的电导率各向异性金属薄板仿真模型,并将其置于静磁场中。将通入交变电流的折线线圈置于金属薄板上方,对金属薄板在静磁场和交变磁场共同作用下产生的感应涡流以及声源(即洛伦兹力)进行数值仿真,得到金属薄板表面波位移分布的灰度图像。仿真实验结果表明,根据表面波位移在缺陷处迅速衰减的特性,可从图像中准确地识别并定位金属薄板表面的缺陷。忽略金属材料的电导率各向异性会降低成像质量,进而导致对缺陷的误判。通过提高表面波位移信号的信噪比可改善成像质量。减小提高距离或增大激励电流频率,可提高系统对微小缺陷和不规则缺陷检测的分辨力。