Synthesis and Crystal Structure of a Palladium(II) Coordination Polymer [Na_2Pd(2,6-pydc)_2(H_2O)_6]_n

A novel coordination polymer [Na2Pd(2,6-pydc)2(H2O)6]n (2,6-H2pydc = 2,6-pyri- dinedicarboxylic acid) has been synthesized and its crystal structure was determined by single-crystal X-ray diffraction. The crystal belongs to the monoclinic system, space group P21/c, with a = 11.962(2), b = 6.5552(13), c = 12.673(3) , β = 91.72(3)°, V = 993.3(3) 3, Z = 2, Mr = 590.68, Dc = 1.975 g/cm3, μ = 1.059 mm-1, F(000) = 592, the final R = 0.0211 and wR = 0.0454. In the crystal the Pd(II) ion adopts a distorted four-coordinated square-planar geometry and bonds to two bidentate 2,6-pyridinedicarboxylate molecules through caronyl oxygen and pyridine nitrogen atoms. The title complex exhibits a novel three-dimensional network structure.     

一类具有饱和感染率和胞内时滞的病毒感染模型的稳定性和Hopf分支

本文研究一类具有饱和感染率以及胞内时滞的病毒感染模型.通过计算,得到模型的基本再生数.通过构造适当的Lyapunov函数,利用La Salle不变原理,证明当基本再生数小于1时,未感染平衡点是全局渐近稳定的;当基本再生数大于1时,得到病毒感染平衡点全局渐近稳定的充分条件.利用分支理论,证明当τ=τ~*时,系统在病毒感染平衡点处存在Hopf分支.     

分布式抽运连续光纤激光器研究

为了避免高功率光纤激光器中光纤端面出现热效应问题,依据多点级联结构的耦合器,对分布式抽运的光纤激光器进行了研究。首先,介绍了实验室自主研制的级联耦合器。然后,分析了耦合器插入对光纤激光器的影响。最后,选用自制的耦合器搭建了分布式抽运的光纤激光器。实验结果表明:对耦合器插入损耗的研究,能够促进高功率级联耦合器的实现。在光纤激光器结构中,975 nm泵浦功率注入1.1 k W时,1 080nm激光功率输出为770 W,光-光转换效率为77%。在主控振荡功率放大结构中,激光功率输出为635 W,放大级的光-光转换效率为78%。分布式抽运方式可以使泵浦光多点注入,避免了热量的集中,能够获得千瓦级的激光功率输出。     

铊玻璃自聚焦透镜的两步离子交换分辨率测量

本文是通过电脑眼及配套计算机测试系统所得的清晰的分辨率图像,来反映两步离子交换得到的铊玻璃自聚焦秀镜在成像质量上优于一步离子交换所得的铊玻璃自焦透镜。     

苯甲酸在水-乙醇混合物溶剂中的电离焓

本文测定了苯甲酸在水-乙醇混合溶剂中的电离焓, 并就此进行了讨论。     

浅谈物理演示实验

在物理教学中用一支粉笔在黑板上画图做“实验”和不精心研究如何做好演示实验,而是象变戏法似的将实验仪器堆满了讲台的演示实验,以及用计算机课件代替所有的演示实验,都不能充分发挥演示实验的独特效果．物理演示实验教学由于自身所具有的独特优越性,不仅能够达到使...     

火焰原子吸收法间接测定汞

Hg(Ⅱ)在适当条件下可定量置换螯合物DDTC-Cu中的Cu(Ⅱ).通过火焰原子吸收测定被置换入水相中的Cu(Ⅱ)而间接得出Hg(Ⅱ)的含量.     

从诺贝尔化学奖看20世纪的化学发展

本文通过对oble析统计,来揭示20世纪化学发展的水准和脉络,着重阐述了20世纪化学的发展特征和趋势。     

α-石英表面自由基和离体肺泡巨噬细胞内游离Ca2+、Mg2+浓度的关系

本文用ＡＲ－ＣＭ－ＭＩＣ阳离子测定系统及Ｆｕｒａ－２荧光技术，研究了研磨后表面存在自由基的α－石英，和离体肺泡巨噬细胞作用后细胞内游离Ｃａ＾２＾＋浓度（［Ｃａ＾２＾＋）ｉ）和游离Ｍｇ＾２＾＋浓度（［Ｍｇ＾２＾＋］ｉ的关系。发现在含Ｃａ＾２＾＋和Ｍｇ＾２＾＋的介质中，α－石英表面自由基越多，［Ｃａ＾２＾＋］ｉ和［Ｍｇ＾２＾＋］ｉ升高越大；在无Ｃａ＾２＾＋和Ｍｇ＾２＾＋的介质中，新研磨的α－石英能引起     

Structural and optical investigation of nonpolar α-plane GaN grown by metalben organic chemical vapour deposition on r-plane sapphire by neutron irradiation

Nonpolar (1120) α-plane GaN films are grown by metal-organic chemical vapour deposition (MOCVD) on r-plane (1102) sapphire. The samples are irradiated with neutrons under a dose of 1 × 10¹⁵ cm^-2. The surface morphology, the crystal defects and the optical properties of the samples before and after irradiation are analysed using atomic force microscopy (AFM), high resolution X-ray diffraction (HRXRD) and photoluminescence (PL). The AFM result shows deteriorated sample surface after the irradiation. Careful fitting of the XRD rocking curve is carried out to obtain the Lorentzian weight fraction. Broadening due to Lorentzian type is more obvious in the as-grown sample compared with that of the irradiated sample, indicating that more point defects appear in the irradiated sample. The variations of line width and intensity of the PL band edge emission peak are consistent with the XRD results. The activation energy decreases from 82.5 meV to 29.9 meV after irradiation by neutron.