The stimulated Raman scattering competition between solute and solvent in Rhodamine B solution

The competition between the stimulated resonance Raman scattering (SRRS) of Rhodamine B (RhB) and the stimulated Raman scattering (SRS) of ethanol (C₂H₅OH) is observed at the RhB in C₂H₅OH solution. For different concentrations of the solution, the peak wavelengths of the SRRS, the amplified spontaneous emission (ASE), the fluorescence and the absorption of RhB are different. The SRRS of RhB and the SRS of C₂H₅OH are simultaneously generated when the concentration of the solution is 10^-5 mol/L and the energy of the excitation laser is 20.4 mJ. Otherwise, only either the SRRS of RhB or the SRS of C₂H₅OH is generated. The SRRS can be amplified by the ASE gain when the SRRS is near the peak of the ASE, and the peak wavelength of the SRRS coincides with the wavelength of the maximal intensity ASE.     

溶液浓度对CCl4费米共振的影响

测量了四氯化碳在苯中不同浓度的拉曼光谱,分析了不同浓度下四氯化碳v₁+v₄~v₃费米共振的变化。结果表明:随着浓度的降低,两费米双光谱强度比R增加,而频差Δ减小、费米共振耦合系数W减小、非谐力常数K增加。这种费米共振随浓度的变化是由溶剂效应引起的,即随着四氯化碳在苯中的浓度降低,其拉曼散射系数(光谱强度)增加,使两费米双线光谱强度增加而减弱了费米共振。     

高压对β-胡萝卜素分子结构及π-电子离域影响的拉曼光谱研究

利用金刚石对顶砧在常压至12.85 GPa条件下对β-胡萝卜素进行了原位高压拉曼光谱测量,讨论了β-胡萝卜素分子特征峰频率随压力的变化规律及其π-电子离域受压力的影响。实验结果表明,β-胡萝卜素的各特征峰均向高波数移动,其主要的三个特征峰的拉曼频率与压力的关系为：ν₁(CC)=4.74P+1 511.4, ν₂(C—C)=2.55P+1 157.6和ν₃(CH₃)=2.25P+1 011.3,β-胡萝卜素的ν₁+ν₂和频峰在5.38 GPa的压力条件下发生劈裂。对实验结果进一步分析发现随压力增大β-胡萝卜素分子的β环扭转变化使其π-电子离域程度变弱, 导致β-胡萝卜素分子主链上的碳碳双键比碳碳单键更容易压缩。     

Intersubband absorption with difference-frequency generation in GaAs asymmetric quantum wells

An asymmetric quantum well(AQW) is designed to emit terahertz(THz) waves by using difference frequency generation(DFG) with the structure of GaAs/Al 0.2 Ga 0.8 As/Al 0.5 Ga 0.5 As.The characteristics of absorption coefficients are analysed under the parabolic and non-parabolic energy-band conditions in detail.We find that the absorption coefficients vary with the two pump optical intensities,and they reach the maxima when the pump wavelengths are given as λ p1 = 9.70 μm and λ p2 = 10.64 μm,respectively.Compared with non-parabolic conditions,the total absorption coefficient under parabolic conditions shows a blue shift,which is due to the increase in the energy difference between the ground and excited states.By adjusting the two pump optical intensities,the wave vector phase-matching condition inside the AQW is satisfied.     

Low Threshold and High Conversion Efficiency Nanosecond Mid-Infrared KTA OPO

Based on a Type II non-critically phase-matched KTA crystal, a low-threshold and high conversion efficiency mid-infrared optical parametric oscillator （OPO） pumped by a diode-end-pumped Nd：YVO4 laser is demonstrated. The OPO threshold is only 0.825W. The maximum output power of 435mW at 3.47μm is achieved with the repetition rate of 30kHz, corresponding to an optical-to-optical conversion efficiency of 4.4%. The photon conversion efficiency is as high as about 64%. The pulse width is 3.5ns with a peak power of 4kW for the maximum output power.     

变换溶剂方法研究溶剂对C==O费米共振的影响

费米共振是振动光谱中常见的现象,变换溶剂法是一种研究费米共振的主要方法.利用傅里叶变换红外光谱法研究了对苯醌在13种溶剂中的费米共振现象.研究发现溶剂的介电常数与费米共振的强度比之间存在一定的函数关系,通过曲线拟合得到费米共振的强度比与溶剂介电常数之间关系的经验公式.并把KirKwood-Bauer-Magat(KBM)方程引入到费米共振研究中,得到费米共振的强度比与介电常数的关系,这与实验得到的经验公式一致.作者对Nyquist和Seehra的红外光谱数据分别进行处理也得到了类似的结果.     

几种天然铝硅酸盐矿物的成分及结构测定

铝硅酸盐是一类重要的矿产资源。在石油炼制、塑料加工、建材工业和轻工业等行业有着广泛的用途。硅和氧是自然界中平均含量最高的元素。这两种元素主要形成络阴离子。其中的硅可以部分被铝取代,然后与其他金属阳离子结合生成铝硅酸盐矿。由于铝的取代程度不同,结合的其他金属阳离子的种类与多寡不一,加之矿物中原子间结合方式的     

周期结构GaAs晶体ps脉冲差频产生窄带THz辐射的研究

计算模拟了在ps脉冲抽运周期结构GaAs晶体差频产生窄带THz波过程中,对于不同波长、不同脉宽的抽运光,周期结构GaAs晶体的走离长度和最佳周期长度的变化,并对计算结果进行了理论分析.研究了周期结构GaAs晶体的畴数对THz波光谱的影响.根据GaAs晶体温度色散公式,计算并分析了晶体最佳周期长度的温度调谐特性,研究了温度变化对THz波光谱的影响,提出了通过温度调谐实现在周期结构GaAs晶体中产生宽调谐、窄带宽THz波的新方法,该计算结果为下一步的实验研究提供了理论基础. 关键词： ps脉冲 差频产生窄带THz波 周期结构GaAs晶体 温度调谐     

物理课堂教学的结课设计

在物理课堂教学中,教师除了精心设计“导入”新课外,也应注意课堂教学的结课设计,做到善始善终．     

Investigation of inter-molecular hydrogen bonding in the binary mixture (acetone + water) by concentration dependent Raman study and ab initio calculations

This paper reports that vibrational spectroscopic analysis on hydrogen-bonding between acetone and water comprises both experimental Raman spectra and ab initio calculations on structures of various acetone/water complexes with changing water concentrations. The optimised geometries and wavenumbers of the neat acetone molecule and its complexes are calculated by using ab initio method at the MP2 level with 6-311+G(d,p) basis set. Changes in wavenumber position and linewidth (fullwidth at half maximum) have been explained for neat as well as binary mixtures with different mole fractions of the reference system, acetone, in terms of intermolecular hydrogen bonding. The combination of experimental Raman data with ab initio calculation leads to a better knowledge of the concentration dependent changes in the spectral features in terms of hydrogen bonding.