All-solid-state quasi-continuous-wave high power dispersion cavity tunable Ti:sapphire laser

An all-solid-state quasi-continuous-wave dispersion cavity tunable Ti:sapphire laser pumped by a laser diode pumped frequency-doubled Nd:YAG laser is reported. Using a dense flint glass prism as the dispersion element, a tuning range from 730 to 880 nm with the linewidth of 3 nm and the pulse width of 17.2 ns was obtained. The maximum output, power of this laser system was 5.6 W at 786.3 nm corresponding to an optical-to-optical conversion efficiency of 25.5% under the pump power of 22 W.     

Angle-tuned signal-resonated optical parametric oscillator based on periodically poled lithium niobate

We demonstrate an angle-tuned signal-resonated optical parametric oscillator (OPO) with periodically poled lithium niobate (PPLN) pumped by a diode-pumped Nd:YVO4 laser. 1499.8 - 1506.6 nm of signal wavelength is achieved at 140℃ by rotating a 29-μm period PPLN from 0° - 10.22° in the x-y plane while keeping the pump wave vertical to the resonator mirrors. Two pairs of the signal and idler waves of the same wavelengths can be achieved symmetrically for each pair of angles of rotation with same absolute value and opposite sign. Theoretical analyses on angle-tuned PPLN-OPO with pump wave vertical to the resonator mirrors are presented and in good agreement with our experimental results. It is also found that all interacting waves in the cavity (not inside the crystal) are always collineax for PPLN-OPO with the pump wave vertical to the resonator mirrors while phase-matching is noncollinear within the crystal.     

聚氨酯/POSS纳米复合材料的制备及阻燃性能

利用笼形倍半硅氧烷(POSS)纳米粒子与二苯基甲烷-4,4'-二异腈酸酯之间的相容性,采用聚合法合成聚氨酯/POSS纳米复合材料.扫描电镜及红外光谱测试表明POSS粒子均匀分散在聚氨酯基体中,热重分析、氧指数及垂直燃烧测试表明：POSS能使复合材料的热稳定性和阻燃性能得到提升.     

28.2 W波长锁定878.6 nm激光二极管共振抽运双晶体1064 nm激光器

报道了一种由波长锁定878.6 nm半导体激光器共振抽运两块不同掺杂浓度Nd:YVO4晶体串接的1064nm激光器,并与使用单块的低掺杂浓度晶体和高掺杂浓度晶体情况进行比较,实验表明利用波长锁定878.6nm半导体激光器共振抽运双晶体串接的方式,有利于降低晶体的热效应,提高光光转换效率.当抽运功率为40 W时,获得了28.2 W的1064 nm激光输出,光光转换率为70.5%,斜率效率为70.6%,相对吸收光的光光转换率76%,斜率效率为76.4%,同时该激光器在10?C—40?C的温度变化范围内具有极好的温度稳定性.     

由动态Stark效应诱导的氢原子涡旋动量分布

采用强场近似方法,对处于两个具有时间延迟的圆偏振激光场中氢原子的涡旋状光电子动量分布进行了数值模拟。在两个延时激光脉冲的作用下,电子吸收光子后克服电离阈值,从基态经由两个不同的通道跃迁到连续态,产生的电子波包之间会发生干涉。模拟结果表明,所产生的光电子动量涡旋的旋向与两脉冲的偏振方向有关,涡旋臂的数目与激光载波频率有关。动态Stark效应是一种典型的强场现象。若在电离发生的同时考虑动态Stark效应,将会观察到动量涡旋的扭曲。对顺时针的动量涡旋及其扭曲进行分析,发现扭曲现象是由动态Stark效应引入的附加相位的时间非线性特性引起的。     

An all-solid-state high power quasi-continuous-wave tunable dual-wavelength Ti：sapphire laser system using birefringence filter

This paper describes a tunable dual-wavelength Ti:sapphire laser system with quasi-continuous-wave and high-power outputs. In the design of the laser, it adopts a frequency-doubled Nd:YAG laser as the pumping source, and the birefringence filter as the tuning element. Tunable dual-wavelength outputs with one wavelength range from 700~nm to 756.5~nm, another from 830~nm to 900mn have been demonstrated. With a pump power of 23~W at 532~nm, a repetition rate of 7~kHz and a pulse width of 47.6~ns, an output power of 5.1~W at 744.8~nm and 860.9~nm with a pulse width of 13.2~ns and a line width of 3~nm has been obtained, it indicates an optical-to-optical conversion efficiency of 22.2{\%}.     

用非球面透镜制作光纤约1∶1空间耦合器

针对光纤的泵浦耦合问题,对由两片非球面透镜组成的接近1∶1光纤间空间耦合器进行了计算和实验验证.利用高斯光束的变化规律对光路进行了分析研究,并根据二极管输出光相干性不好的特点,对非球面透镜进行了光路追迹的模拟计算.研究发现,在泵浦光波长等因素发生变化时,利用椭球面透镜组成的耦合系统较双曲面透镜有更高的稳定性.实验中选用符合计算结果要求的非球面透镜组成耦合装置,利用一台二极管激光器(尾纤输出端面直径约200μm,N.A.约0.2)泵浦一段芯径约200μm(N.A.约0.42)的多模光纤,耦合装置的透过率约95%,在光纤端面有反射的条件下约90%的泵浦光耦合进光纤.     

原位组装在碳纸上的有机金属骨架材料衍生的NC/Co/CoP催化剂用于碱性环境水分解（英文）

随着世界工业经济的发展,作为不可再生能源的化石燃料消耗日趋增大并带来严重的环境污染.氢能具有能量密度高、燃烧无污染等优点,被认为是替换传统化石燃料的理想能源之一.通过电化学方法实现水裂解制氢是既满足环境要求又符合氢气生产需要的一种潜在有效方法,受到人们广泛关注.基于铂、钌等贵金属的电催化剂在水裂解中具有很高的活性,然而其稀缺性和高成本是阻碍其大规模实际应用的重要因素.水裂解制氢包括二电子转移的质子还原和四电子转移的水氧化两个过程.相对于质子还原,水氧化反应动力学过程缓慢,是决定水裂解速率的关键.通常,质子还原反应倾向于在酸性条件下进行,而水氧化反应在碱性环境下更有利,反应条件的差异阻碍了水裂解制氢的发展.因此,制备在碱性环境下具有高催化性能、高稳定性和低成本的催化剂是促进水裂解制氢能源技术进一步发展的关键.金属有机骨架(MOF)衍生的复合催化剂具有良好的催化性能和广阔的应用前景,在催化反应中得到越来越多的重视.传统的催化剂组装方式是通过全氟磺酸聚合物等辅助剂将催化剂组装到工作电极上,这些辅助剂具有较强的酸性,而且会覆盖催化剂表面的催化活性位点,降低催化剂比表面积,阻碍催化剂活性的进一步提升.本文通过电泳的方法,将ZIF-67负载到碳纸上,进一步通过碳化、部分磷化过程得到NC/Co/Co P/CP催化电极.研究发现,在碱性环境(1 mol/LKOH)下,催化电流达到10 m A/cm^2的析氢过电位只有208 m V,析氧反应的过电位为350 m V,在二电极体系中所需的电压也只有1.72 V,催化活性明显高于通过传统方法组装的电极.在长时间的电化学稳定性测试中,经过20h的电流测试和1000次的CV测试后,该电极的催化活性没有明显下降.我们报道了一种基于MOF材料的复合电极组装新方法,为MOF材料在能源储存与转化领域应用提供了新思路.     

Diode end-pumped 1123-nm Nd:YAG laser with 2.6-W output power

We present a compact and high output power diode end-pumped Nd:YAG laser which operates at the wavelength of 1123 nm. Continuous wave (CW) laser output of 2.6 W was achieved at the incident pump power of 15.9 W, indicating an overall optical-optical conversion efficiency of 16.4%, and the slope efficiency was 18%.     

High-power and high-efficiency operation of an all-solid-state,quasi-continuous-wave,titanium sapphire laser system

High-power and high-efficiency operation of an all-solid-state, quasi-continuous-wave, titanium sapphire laser is obtained with a diode-laser-pumped frequency-doubled Nd:YAG laser as the pump source. A maximum output power of 2.5 W is obtained for 16-W power of 532-nm pump light. A much higher conversion efficiency of 15.7% is obtained when at the maximum output power.