Study on interaction between Dy(Ⅲ)(NR)_3 complex and herring sperm DNA by spectroscopy

<正>The action mode between Dy(III)(NR)_3 and herring sperm DNA is studied by ultraviolet-visible(UVvis) and fluorescence spectra as well as electrochemistry.Double-reciprocal method studies show that the binding stoichiometry between Dy(III)(NR)_3 and DNA is 1:1,the binding constants at different temperatures are 1.15×10~5 L/mol at 25℃and 2.09×10~5 L/mol at 35℃,and the corresponding thermodynamic parameters are△_rH_m~(?) = 2.48×10~4 J/mol,△_rG_m~(?)= -2.34×10~4 J/mol,△_rS_m~(?) = 161.7 J/(mol-K),△_rS_m~(?) is the driving force in this reaction.Combined with Scatchard method and melting method,the results suggest that the interaction mode between Dy(III)(NR)_3 and herring sperm DNA is intercalation fashion and groove fashion.     

Boundary Conditions of Wigner-Seitz Cell in Inner Crust of Neutron Stars with Relativistic Mean Field Approach

The microscopic structure of the Wigner-Seitz （W-S） cell in the inner crust of neutron stars is investigated with the relativistic mean field （RMF） approach. The W-S cell is composed of a cluster of neutrons and protons localized in a region around the centre and surrounded by a neutron gas of approximately uniform density. In order to generate the density of the W-S cell, appropriate boundary conditions in the calculation of the single-particle wavefunctions are necessary. We emphasize on the choice of the boundary conditions in the RMF approach. Three kinds of boundary conditions are suggested. The properties of the W-S cell with the three kinds of boundary conditions are investigated. The neutron density distributions in the RMF and Hartree-Fock-Bogoliubov （HFB） models are compared. It is found that the neutron gas densities of the W-S cell in the RMF model is higher than those obtained in the HFB model.     

重视物理过程 正确运用规律

学习任何一门基础学科,都是为了要掌握知识,提高能力.解题是为了巩固和活化所掌握的知识,同时也是培养分析问题、解决问题能力的一种途径.在解题时,必须分析物理过程,要从基本概念出发,考虑过程的特点,选用所遵循的规律.     

线性三原子分子振动激发控制的李代数方法

采用李代数方法研究线性三原子分子在强红外激光场中的多光子激发及其控制,实现了态选择激发,并讨论了激光脉冲对控制的影响. 关键词： 多光子 李代数 激光     

Hybrid control of bifurcation and chaos in stroboscopic model of Internet congestion control system

Interaction between transmission control protocol (TCP) and random early detection (RED) gateway in the Internet congestion control system has been modelled as a discrete-time dynamic system which exhibits complex bifurcating and chaotic behaviours. In this paper, a hybrid control strategy using both state feedback and parameter perturbation is employed to control the bifurcation and stabilize the chaotic orbits embedded in this discrete-time dynamic system of TCP/RED. Theoretical analysis and numerical simulations show that the bifurcation is delayed and the chaotic orbits are stabilized to a fixed point, which reliably achieves a stable average queue size in an extended range of parameters and even completely eliminates the chaotic behaviour in a particular range of parameters. Therefore it is possible to decrease the sensitivity of RED to parameters. By using the hybrid strategy, we may improve the stability and performance of TCP/RED congestion control system significantly.     

二极管侧面泵浦薄片激光器泵浦均匀性分析

 建立了二极管侧面泵浦复合薄片激光介质Nd:YAG/YAG的数值模型：二极管阵列的快轴垂直于薄片激光介质表面的排布,二极管对称排列在增益介质的周围,从侧面进行泵浦,通过微柱透镜对二极管的快轴进行准直。模拟并实验研究了激光二极管慢轴方向的远场分布特性,结果发现在近距离时激光二极管慢轴方向上的远场分布近似为高斯分布。对于二极管参量,研究发现泵浦二极管越多,增益介质内泵浦光分布就越理想;增益介质吸收系数越小,泵浦的均匀性就越好,但总的吸收效率下降;二极管与工作物质的距离越近,工作物质靠近中心的区域对泵浦光的吸收就越多,但泵浦的均匀性就越差。选用增益介质为Nd:YAG/YAG的复合薄片介质,当掺杂原子分数以及增益介质的吸收系数不同时,发现0.6%掺杂的增益介质(吸收系数为0.24 cm^-1)的泵浦均匀性比1%掺杂(吸收系数为0.51 mm^-1))有明显改善,实验结果与模拟结果一致。     

横肋变截面U通道内换热特性的实验研究

本实验选取航空发动机涡轮叶片中段内部冷却通道为研究对象,对不同肋间距的横肋变截面U型通道的换热特性进行了研究。实验模型中,矩形肋对称布置在上下两个表面,肋高为1.5 mm,肋宽为2 mm,肋与流体流向夹角为90°。实验结果表明,当节距比为10时,通道的平均换热效果最佳,节距比为16.6时,通道的平均换热效果次之,节距比为13.3和20时,通道的平均换热效果相当,且较差。     

壮阳药与补血药中微量元素比例关系的测定与分析

研究了壮阳药、补血药中微量元素含量的比例的关系。原子吸收光谱法测定常用的 5种壮阳药和补血药中 Zn、Cu、Fe、Mn 4种微量元素 ,只有比例上符合生理要求才能发挥作用     

石墨烯纳米带电子结构的紧束缚法研究

在推导出的一般复式格子的π电子紧束缚能量色散关系的基础上,通过假定石墨烯纳米带的电子横向限制势为无穷大硬壁势,导出石墨烯纳米带的能量色散关系及石墨烯纳米带或为金属或为半导体的条件.结果表明：石墨烯纳米带的电子结构与其几何构型（对称性及宽度）密切相关,所以通过控制几何构型,可将其调制成金属或不同带隙的半导体.这意味着石墨烯纳米带对于发展新型纳米器件具有重要意义. 关键词： 石墨烯纳米带 复式格子 紧束缚模型 电子结构     

利用级联式能量传递的有机电致发光器件

为了提高掺杂型有机电致发光器件(OLED)中主体发光材料与客体荧光染料间能量传递的效率,2-对联苯-8-羟基喹啉锌(Zn ₂)作为NPB : DCJTB掺杂体系的能量助传递剂,制备了结构如:ITO/NPB/NPB : DCJTB/Zn ₂/BCP/Al的有机电致发光器件。助传递剂Zn ₂的加入,能够两次利用Frster能量转移,实现NPB向DCJTB级联式的能量传递过程,提高低浓度时掺杂染料DCJTB红光发射的纯度;此外,还探讨了三者间能量传递的有效距离,即当助传递剂与掺杂体系的距离在小于10 nm的范围内,其参与能量传递的效率随着距离的增加而逐渐下降。