Weakly nonlocal irreversible thermodynamics

Weakly nonlocal thermodynamic theories are critically revisited. A relocalized, irreversible thermodynamic theory of nonlocal phenomena is given, based on a modified form of the entropy current and new kind of internal variables, the so called current multipliers. The treatment is restricted to deal with nonlocality connected to dynamic thermodynamic variables. Several classical equations are derived, including Guyer‐Krumhansl, Ginzburg‐Landau and Cahn‐Hilliard type equations.     

The Calogero–Bogoyavlenskii–Schiff Equation in 2+1 Dimensions

We use the classical and nonclassical methods to obtain symmetry reductions and exact solutions of the (2+1)-dimensional integrable Calogero–Bogoyavlenskii–Schiff equation. Although this (2+1)-dimensional equation arises in a nonlocal form, it can be written as a system of differential equations and, in potential form, as a fourth-order partial differential equation. The classical and nonclassical methods yield some exact solutions of the (2+1)-dimensional equation that involve several arbitrary functions and hence exhibit a rich variety of qualitative behavior.     

Extrinsic Killing spinors

 Under intrinsic and extrinsic curvature assumptions on a Riemannian spin manifold and its boundary, we show that there is an isomorphism between the restriction to the boundary of parallel spinors and extrinsic Killing spinors of non-negative Killing constant. As a corollary, we prove that a complete Ricci-flat spin manifold with mean-convex boundary isometric to a round sphere, is necessarily a flat disc. Received: 2 February 2002; in final form: 1 August 2002 / Published online: 1 April 2003 Mathematics Subject Classification (1991): 53C27, 53C40, 53C80, 58G25 The authors would like to thank Lars Andersson for helpful discussions and for bringing to our knowledge the information regarding Remark 4. We are also grateful to the referee for pointing out that Corollary 5 and Corollary 6 are only valid when the boundary is at least 2-dimensional. Research of S. Montiel is partially supported by a Spanish MCyT grant No. BFM2001-2967     

Zur Synthese und Struktur von K3N

Synthesis and Structure of K₃N Two phases in the binary system K/N have been obtained via co‐deposition of potassium and nitrogen onto polished sapphire at 77 K and subsequent heating to room temperature. The powder diffraction pattern of one of these phases can be satisfactorily interpreted by assuming the composition K₃N, and the anti‐TiI₃ structure‐type, which is also adopted by Cs₃O. The resulting hexagonal lattice constants are: a = 779.8(2), c = 759.2(9) pm, Z = 2, P6₃/mcm. Comparison with possible structures of K₃N generated by computational methods and refined at Hartree‐Fock‐ and DFT level, reveals that the energetically most favoured structure has not formed (presumable Li₃P‐type), but instead one of those with very low density. In this respect, the findings for K₃N are analogous to the results on Na₃N. The thermal evolution of the deposited starting mixture has been investigated. Hexagonal K₃N transforms to another K/N phase at 233 K. Its XRD can be fully indexed resulting in an orthorhombic cell a = 1163, b = 596, c = 718 pm. Decomposition leaving elemental potassium as the only residue occurs at 263 K.     

Proper Efficiency in Vector Optimization on Real Linear Spaces

In this paper, we use an algebraic type of closure, which is called vector closure, and through it we introduce some adaptations to the proper efficiency in the sense of Hurwicz, Benson, and Borwein in real linear spaces without any particular topology. Scalarization, multiplier rules, and saddle-point theorems are obtained in order to characterize the proper efficiency in vector optimization with and without constraints. The usual convexlikeness concepts used in such theorems are weakened through the vector closure.     

Photonic crystals--a step towards integrated circuits for photonics.

The field of photonic crystals has, over the past few years, received dramatically increased attention. Photonic crystals are artificially engineered structures that exhibit a periodic variation in one, two, or three dimensions of the dielectric constant, with a period of the order of the pertinent light wavelength. Such structures in three dimensions should exhibit properties similar to solid-state electronic crystals, such as bandgaps, in other words wavelength regions where light cannot propagate in any direction. By introducing defects into the periodic arrangement, the photonic crystals exhibit properties analogous to those of solid-state crystals. The basic feature of a photonic bandgap was indeed experimentally demonstrated in the beginning of the 1990s, and sparked a large interest in, and in many ways revitalized, photonics research. There are several reasons for this attention. One is that photonic crystals, in their own right, offer a proliferation of challenging research tasks, involving a multitude of disciplines, such as electromagnetic theory, nanofabrication, semi-conductor technology, materials science, biotechnology, to name a few. Another reason is given by the somewhat more down-to-earth expectations that photonics crystals will create unique opportunities for novel devices and applications, and contribute to solving some of the issues that have plagued photonics such as large physical sizes, comparatively low functionality, and high costs. Herein, we will treat some basics of photonic crystal structures and discuss the state-of-the-art in fabrication as well give some examples of devices with unique properties, due to the use of photonic crystals. We will also point out some of the problems that still remain to be solved, and give a view on where photonic crystals currently stand.     

Parametric Centers for Trigonometric Abel Equations

This article is devoted to one-dimensional perturbative theory on R × S ¹. There is a recursive formula for the successive obstructions to parametric center at any order of the perturbation parameter. The first obstruction is studied by means of complex analysis techniques. This extends to the trigonometric case what was done previously for the polynomial case (Israel J. Math. 142, 273–283, 2004). This article is dedicated to Professor Zhang Zhi-Fen on the occasion of her 80th Birthday     

Static and dynamic detection of axial surface defects on metallic wires by conical triple laser reflection

The quality of the surface of metallic wires is relevant for different applications. The reflection of a laser beam on the surface of a metallic cylindrical wire provides an efficient way to inspect the quality of its surface. Our interest is focused in the detection of axially oriented defects, which are the most relevant for the wire drawing process. We present a simple interference-geometrical model to describe the light pattern reflected from a wire with defects. This model adequately accounts for the observed results from an industrial prototype developed for the purpose. It incorporates three-laser beams incident on the wire at equidistant locations in its perimeter, which produce three reflection cones with a CCD. This configuration permits to explore the whole perimeter of the wire. Several results are presented, both in static operation and in production line, in agreement with qualitative and quantitative predictions.     

Local chain‐configuration dependence of the mechanisms of the chemical reaction of poly(vinyl chloride). IX. Novel results on stereoselectivity of chlorination reaction

A poly(vinyl chloride) (PVC) sample was chlorinated in solution in the presence of 2,2′‐azobisisobutyronitrile and by the fluid‐bed method. The aim was to evaluate the scope of the stereoselectivity of the chlorination reaction. The quantitative microstructural analysis of the residual PVC with a degree of chlorination was followed by ¹³C NMR spectroscopy. From the evolution of the content of isotactic (mm), heterotactic (mr), and syndiotactic (rr) triads and of mmmm, mmmr, and rmmr isotactic pentads in the unchlorinated parts of the polymer, it was unambiguously inferred that the chlorination reaction proceeds by a stereoselective mechanism in that the mr heterotactic triads are the most reactive structures followed by the isotactic triad at mmmr and rmmr pentads. This conclusion was confirmed on the basis of the Fourier transform infrared results. The results provide valuable information regarding the effect of tacticity and related local conformations in the chemical reactions of PVC. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 508–519, 2003