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31.
V. V. Dvorkin N. N. Dzbanovskii A. F. Pal’ N. V. Suetin A. Yu. Yur’ev P. Ya. Detkov 《Physics of the Solid State》2004,46(4):729-732
A suspension of ultrafine-dispersed nanodiamond was used for introducing (in particular, selectively) high-density centers of diamond nucleation on various substrates. High-quality doped diamond films to be used as electrochemistry electrodes were deposited from the gas phase in a microwave discharge on certain substrates treated using ultrafine-dispersed nanodiamond. A uniform distribution of nucleation centers with concentrations greater than 1010 cm-2 on silicon substrates was obtained. Electrochemical current-potential curves were measured for continuous films. Diamond meshes of different transparency were grown using selective nucleation. Successful production of high-quality doped diamond meshes gives grounds to consider them the most promising electrodes for use in electrochemistry. 相似文献
32.
33.
M. Ya. Izrailovich 《Acoustical Physics》2004,50(2):163-168
On the basis of the method of equivalent linearization combined with the method of moments, laws of self-oscillation excitation are obtained that provide the modes with maximum intensity of resonance (or quasi-resonance) oscillations in one-dimensional systems with distributed parameters. A restriction of a general type is imposed on the law of excitation. In the particular case of an integral quadratic restriction, the law of excitation leads to the generation of purely harmonic self-oscillations. The use of an extended (multiplicatively stabilizing) control provides the uniqueness and stability of the quasi-optimal mode of self-oscillation. 相似文献
34.
The electrochemical reduction of 1-([(4-halophenyl)imino]methyl)-2-naphthols on graphite electrodes was studied using cyclic voltammetry, chronoamperometry, constant-potential coulometry and preparative constant-potential electrolysis techniques. The data revealed that the reduction on graphite was irreversible and followed an EC mechanism. The diffusion coefficients and the number of electrons transferred were determined using the chronoamperometric Cottrell slope and the ultramicro disc Pt-electrode steady-state current. The number of electrons was also determined by bulk electrolysis. The compounds were subjected to constant-potential preparative electrolysis and the electrolysis products were purified and identified by spectroscopic methods. Based on these findings, a mechanism for the electro-reduction process is proposed. 相似文献
35.
Ri Cheng XUAN* Wei Xiao HU Zhong Yu YANG Ya Ping LU College of Pharmaceutical Sciences Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(2)
2-Chloro-5-methylpyridine is an important intermediate for the preparation of biological active compounds, especially insecticides1, e.g. imidacloprid2, and is usually manufac- tured from 3-methylpyridine N-oxide. However, the manufacturing process also forms the by-products: 3-methylpyridine and its isomer 2-chloro-3-methylpyridine3. The pro- perties of the isomers are similar, it is difficult to separate by ordinary methods, such as distillation. Scheme 1 79.4%13.6%5.2%NClCH3NCH3ClNC… 相似文献
36.
Stefan Cobzaş 《Acta Appl Math》2004,80(3):363-363
37.
Dmitri V Sevenard Vyacheslav Ya SosnovskikhAlexander A Kolomeitsev Martin H KönigsmannGerd-Volker Röschenthaler 《Tetrahedron letters》2003,44(41):7623-7627
In a convenient and efficient procedure, the nucleophilic 1,4-trifluoromethylation of several α,β-enones using (trifluoromethyl)trimethylsilane was achieved. The high regioselectivity of the reaction has been reached by blocking the carbonyl moiety of the electrophile with a bulky aluminum-centered Lewis acid. 相似文献
38.
The nearest-neighbor two-point correlation function of the Z-invariant inhomogeneous eight-vertex model in the thermodynamic limit is computed using the free-field representation.
Pis’ma Zh. éksp. Teor. Fiz. 68, No. 3, 243–247 (10 August 1998)
Published in English in the original Russian journal. Edited by Steve Torstveit. 相似文献
39.
A. Ya. Kazakov 《Theoretical and Mathematical Physics》1998,117(1):1182-1193
We investigate a Cauchy problem in the Fock space for a system consisting of a two-level atom, a quantum field, and a classical
field. A solution estimate is obtained for the Cauchy problem with initial data from a special class. This class is invariant
with respect to the dynamic semigroup of the system. We propose an averaging method for solving the Cauchy problem in the
case where the Hamiltonian parameters differ greatly in the order of magnitude. An estimate of the averaging error is obtained.
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 117, No. 1, pp. 92–106, October, 1998. 相似文献
40.