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71.
Thomas Özgün Dr. Klaus Bergander Dr. Lei Liu Dr. Constantin G. Daniliuc Prof. Dr. Stefan Grimme Dr. Gerald Kehr Prof. Dr. Gerhard Erker 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(34):11958-11961
The energy profile of a frustrated Lewis pair (FLP) dihydrogen splitting system was determined by a combined experimental kinetic and DFT study. A trimethylene‐bridged phosphane–borane FLP was converted into its endothermic H2‐cleavage product by sequential H+/H? addition. The system could be handled at low temperature, and the kinetics of the H2 elimination were determined to give a rate constant of kHH,exp(299 K)=(2.87±0.1)×10?4 s?1 in solution. The primary kinetic isotope effects were determined; for example, (kHH/kDD)exp=3.19. The system was accurately analyzed by DFT calculations. 相似文献
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Ukrainian Mathematical Journal - The method of Green’s functional is a little-known technique for the construction of fundamental solutions to linear ordinary differential equations (ODE)... 相似文献
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Ukrainian Mathematical Journal - We determine some classes of left modules satisfying the radical formula in a noncommutative ring. We also show that, under a certain condition, a finitely... 相似文献
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Journal of Thermal Analysis and Calorimetry - In the original publication of the article, peak numbers were not given in figure 4. The corrected figure 4 is given below. 相似文献
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Semra Öztürk Kaptanoğlu 《Algebras and Representation Theory》2014,17(5):1437-1455
We introduce the class of restricted k[A]-modules and p t -Jordan types for a finite abelian p-group A of exponent at least p t and a field k of characteristic p. For these modules, we generalize several theorems by Benson, verify a generalization of conjectures stated by Suslin and Rickard giving constraints on Jordan types for modules of constant Jordan type when t is 1. We state conjectures giving constraints on p t -Jordan types and show that many p t -Jordan types are realizable. 相似文献
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Some growth conditions of the resolvent function of a Banach space operator are investigated using higher order Cesàro means. More precisely, Abel and Nevanlinna estimates are obtained under the condition of boundedness of some weighted Cesàro averages. Also, certains results related to the (strong or uniform) convergence of Cesàro means are mentioned. 相似文献
80.
M. Isakov J. Kokkonen K. Östman V.-T. Kuokkala 《The European physical journal. Special topics》2016,225(2):231-242
In this paper, methods to produce rapid strain rate changes for strain rate sensitivity measurements in Split Hopkinson Bar arrangements are presented and discussed. Two different cases are considered: a strain rate change test within the high strain rate region in compression, and a tension test incorporating a large strain rate jump directly from the low strain rate region to high strain rates. The former method is based on the loading wave amplitude manipulation, while the latter method is based on the incorporation of a low strain rate loading device into a Tensile Split Hopkinson Bar apparatus. 相似文献