全文获取类型
收费全文 | 5332篇 |
免费 | 1332篇 |
国内免费 | 262篇 |
专业分类
化学 | 3150篇 |
晶体学 | 5篇 |
力学 | 169篇 |
综合类 | 45篇 |
数学 | 1056篇 |
物理学 | 2501篇 |
出版年
2023年 | 80篇 |
2022年 | 905篇 |
2021年 | 324篇 |
2020年 | 15篇 |
2019年 | 39篇 |
2018年 | 58篇 |
2017年 | 139篇 |
2016年 | 136篇 |
2015年 | 105篇 |
2014年 | 45篇 |
2013年 | 39篇 |
2012年 | 44篇 |
2011年 | 14篇 |
2010年 | 62篇 |
2009年 | 31篇 |
2008年 | 45篇 |
2007年 | 187篇 |
2006年 | 292篇 |
2005年 | 378篇 |
2004年 | 173篇 |
2003年 | 143篇 |
2002年 | 150篇 |
2001年 | 289篇 |
2000年 | 452篇 |
1999年 | 645篇 |
1998年 | 535篇 |
1997年 | 258篇 |
1996年 | 286篇 |
1995年 | 259篇 |
1994年 | 262篇 |
1993年 | 161篇 |
1992年 | 80篇 |
1991年 | 37篇 |
1990年 | 58篇 |
1989年 | 52篇 |
1988年 | 48篇 |
1987年 | 14篇 |
1986年 | 11篇 |
1985年 | 12篇 |
1984年 | 8篇 |
1983年 | 10篇 |
1982年 | 8篇 |
1981年 | 10篇 |
1976年 | 2篇 |
1964年 | 3篇 |
1963年 | 2篇 |
1958年 | 2篇 |
1957年 | 4篇 |
1956年 | 2篇 |
1954年 | 2篇 |
排序方式: 共有6926条查询结果,搜索用时 15 毫秒
131.
ZENG Xiang-Chao② XU Shi-Hai LIU Po-Runa DENG Qin-Ying 《结构化学》2005,24(3):299-302
1 INTRODUCTION Indole and its derivatives have attracted much at-tention due to their chemical properties as well asbiological activities[1, . They have been widely used 2]as the materials for producing pigment, perfume,plant growth regulators, etc. Recently, it has alsobeen found that some indole derivatives present anti-tumor and antiviral activities[3~5]. During our sear-ches for bioactive compounds, a series of indole deri-vatives were synthesized, among … 相似文献
132.
SynthesesandStudiesofPEG┐b┐PNIPABlockPolymersCAOWei-xiao**andZHANGTao(ColegeofChemistryandMolecularEnginering,PekingUniversit... 相似文献
133.
IntroductionInthcsclcctivcoxidationofalkanes.suchas'theoxidativccouplingofmcthanc(0CM)andthcoxidativcdch}'drogenationofcthanc(0DE)t0prcparccth}'lene.bothoxidcionsofthelatticeandtheox}'genspeciesovercataIystsuffocepla}'animportantrole.Althoughcxtcnsivcinvcstigationshavcbeengivcntothecharactcrizationofox}'gcnspccicsandthcreactionofox}'gcnspecicsx`ithalkanes,itisstilldifficulttosayt`hichoncsofox}'gcnspcciesarcthcactivcspecicsinthcactivation0falkancs.bccauscthenaturcofcatal}'stsandthecxperimcntc… 相似文献
134.
BEHAVIOR OF SUPPORTED NANO-COPPER CATALYST IN CO OXIDATION 总被引:1,自引:0,他引:1
IntroductionNanomaterialisanewkindofmaterialwithparticlesizebetWeenIurnand100urn.Becauseofthesmallparticlesizeandthelargespecificsufficearea,nanomaterialpossessesmanyparticularproperties,suchashighersufficeenergyandhighersurfaceactivity.t.[l]Thehigheracti… 相似文献
135.
1INTRoDUrnoNSomecomplexessynthesizedaccordingtotheideaof"combiningtheinorganicdistOrtedpoyhedronwithasymmetricconjugateorganicmo1ecules"areacategoryof,..promisingnonlinearopticalmaterialtl3.Thecomplexcrystalsareundoubtedlyanewimportantfieldfortheexplorationoffrequencydoublingandotherfunctionalmateri-alswhichwillbecomethefocusoftheworld'sattentiont2i.Inordertostudytherela-tionshipbetweenthestructure,synthesis,propertiesandapplicationsfurthermore,wereportthesynthesisandcrystalstructureofanewt… 相似文献
136.
TheBeckInannrearrangement,theacid-mediatedisomerizationofoximestoamides,wasfirstdiscoveredinl886l.Asoneoftheoldestandmostfamiliartransformationsinorganicchemistry,ithasbeenwidelystudiedandagreatvarietyofmethodstoconductthistfansformationhavebeenreported'.However,mostofthesemethodswerecarriedoutbyusingalargeamountofsolventswithlongreactiontime.Whatismore,thepriorpreparationofthecorrespondingketoximesisusuallyrequired,whichmakestheseprocessesinconvenientandlessattractive.Bytakingadvantageofboth… 相似文献
137.
CMAO Jiang-Gao 《结构化学》1998,(5)
1INTR0DUCTI0NLanthanidecarboxylatecomplexeshavebeenwidelystudiedt1iandm0starefoundtoexhibitavarietyofdimericorinfinitechainstructures.Recentstudiesinourlaboratoryhavedem0nstratedthattheprototypetertiaryaminebetaine(Me,N CHzC0z-)anditsderivativesareusefulinthegenerationoflanthanidecarb0xylate-likecomplexeswithnewstructuralfeaturesduetotheiroverallchargeneutralityandpossibleinclusionofvariouskindsofcounteranionsinthestructuret2~4i.Thelan-thanidecomplexesisolatedsofarhavebeenfoundtobemononu… 相似文献
138.
YE Ruo-Bai HUANG Chang-Cang ① ZHANG Han-Hui LI Hao-Hong YANG Qi-Yu SUN Rui-Qing 《结构化学》2005,24(6):679-683
1 INTRODUCTION Recently, the organic-inorganic hybrid Ⅳa groupmetal halides with low-dimensional structure haveattracted much attention of chemists and physicistsdue to their particular properties and applications.For example, they are akin to “natural quantum-well”architectures and have tunable excitonic propertiesusually governed by the inorganic substructure andorganic component[1]; they have been applied assome technologically important materials, such assemiconductor materials in … 相似文献
139.
Formation and Structure of [Al_(13)(μ_3-OH)_6(μ_2-OH)_6(μ_2-OH)_(12)(H_2O)_(24)]Cl_(15)·13H_2O 总被引:1,自引:0,他引:1
1 INTRODUCTION At present, the polyaluminium compounds are mainly studied by single-crystal X-ray diffraction method to obtain the components, structures and exis- tence forms of aluminium in hydrolysis system, and then hydrolysis courses and mechanisms of each hydrolytic polyaluminium cation could be further dis- closed[1~5]. Generally, the single crystals suitable for X-ray diffraction are obtained from the crystallization of polyaluminium cations into sulfates or selenates. Following … 相似文献
140.
InteractionbetweenMetalinMetalloEnzymeandSmallBiologicalMolecules¥HuJie-Han;ShuZan-Yong;TaoLi-Mei;ChengGuo-Bao(DalianInstitut... 相似文献