全文获取类型
收费全文 | 150篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 49篇 |
晶体学 | 1篇 |
力学 | 11篇 |
数学 | 80篇 |
物理学 | 12篇 |
出版年
2023年 | 2篇 |
2021年 | 5篇 |
2020年 | 6篇 |
2019年 | 4篇 |
2018年 | 3篇 |
2017年 | 5篇 |
2016年 | 6篇 |
2015年 | 7篇 |
2014年 | 12篇 |
2013年 | 19篇 |
2012年 | 7篇 |
2011年 | 8篇 |
2010年 | 8篇 |
2009年 | 9篇 |
2008年 | 5篇 |
2007年 | 7篇 |
2006年 | 6篇 |
2005年 | 4篇 |
2004年 | 2篇 |
2003年 | 9篇 |
2002年 | 7篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1991年 | 1篇 |
排序方式: 共有153条查询结果,搜索用时 15 毫秒
1.
We provide a rigorous derivation of an asymptotic formula for perturbations in the eigenvalues caused by the presence of a finite number of inhomogeneities of small diameter with conductivity different from the background conductivity. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
2.
We consider the inverse problem of identifying locations and certain properties of the shapes of small elastic inclusions
in a homogeneous background medium from dynamic boundary measurements for a finite interval in time. Using particular background
solutions as weights, we present an asymptotic method based on appropriate averaging of the dynamic boundary measurements
and propose non-iterative algorithms for solving our inverse problem. 相似文献
3.
Mohammed Boutayeb Soufiane El Imadi El Mokhtar Essassi Nour-Eddine Es-Safi Lahcen El Ammari 《合成通讯》2013,43(14):2130-2137
New pyrazolo[1.5.4-de]quinoxaline derivatives were prepared by the action of 7-aminoindazole 1 on diethyl and dimethyl acetylene dicarboxylates. The structures of the obtained compounds and the direction of cyclization were investigated through a crystallographic study of compound 2. Further alkylation, hydrogenation, and bromination were also explored. The action of potassium thiocyanate on the obtained halo product led to a tetracyclic compound of 1.3-thiazolo[3.4-a]pyrazolo[1.5.4-de]quinoxaline series. 相似文献
4.
Thermo‐ and pH‐sensitive triblock copolymers with tunable hydrophilic/hydrophobic properties
下载免费PDF全文
![点击此处可从《Journal of polymer science. Part A, Polymer chemistry》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Christophe Pottier Gaëlle Morandi Virginie Dulong Zied Souguir Luc Picton Didier Le Cerf 《Journal of polymer science. Part A, Polymer chemistry》2015,53(22):2606-2616
Polymers consisting of poly(acrylic acid) (PAA) and statistical poly[(acrylic acid)‐co‐(tert‐butylacrylate)] (P(AA‐co‐tBA)), attached to both extremities of Jeffamine® (D series based on a poly(propylene oxide) (PPO) with one amine function at each end) using atom transfer radical polymerization (ATRP) are presented in this article. An original bifunctional amide‐based macroinitiator was first elaborated from Jeffamine®. tBA polymerization was subsequently initiated from this macroinitiator. This polymerization occurs in a well‐controlled manner leading to narrow molecular weights distribution. Amphiphilic copolymers were finally obtained after complete or partial hydrolysis of the PtBA blocks into PAA. The control of the partial hydrolysis of tBA units, conducted in a concentrated HCl/tetrahydrofuran mixture, is demonstrated. The properties of the triblock copolymers were preliminary investigated in aqueous solution by absorbance, DLS measurements and SEC/MALS/DV/DRI analysis as a function of temperature and pH modifications, providing evidences of thermo‐ and pH‐sensitive self‐assembly of the copolymers. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 2606–2616 相似文献
5.
Evangelos I. Tolis Dikaia E. Saraga George Z. Ammari Evangelos I. Gkanas Theofilos Gougoulas Christina C. Papaioannou Anastasios K. Sarioglou Eleftherios Kougioumtzidis Athina Skemperi John G. Bartzis 《Central European Journal of Chemistry》2014,12(6):643-651
Eordaia basin located in northwest of Greece, comprises an area which is characterized by intense energy related activities, including coal burning at four power plants and the associated mining operations. Air samples of inhalable (PM10) and respirable particles (PM2.5) were collected in cold and warm periods in 2010 at an urban background site of Kozani, the major city and capital of the region which is located close to the power plants. Particulate matter concentration, particle-bound polycyclic aromatic hydrocarbons and anionic species concentrations were determined using gravimetric, GC-MS in SIM mode and Ion Chromatography analysis, respectively. For the cold period, the mean PM10 and PM2.5 mass concentration was found to be 19.62 and 14.68 µg m?3, respectively. Correspondingly, for the warm period, the mean PM10 and PM2.5 values were 35.29 and 25.75 µg m?3, respectively. In general, the results indicated that the major sources of air pollution in Kozani are traffic, combustion from agricultural activities and lignite power plants emissions, contributing by different percentages to each particle fraction. 相似文献
6.
Parks Conor D. Gaieb Zied Chiu Michael Yang Huanwang Shao Chenghua Walters W. Patrick Jansen Johanna M. McGaughey Georgia Lewis Richard A. Bembenek Scott D. Ameriks Michael K. Mirzadegan Tara Burley Stephen K. Amaro Rommie E. Gilson Michael K. 《Journal of computer-aided molecular design》2020,34(2):99-119
Journal of Computer-Aided Molecular Design - The Drug Design Data Resource (D3R) aims to identify best practice methods for computer aided drug design through blinded ligand pose prediction and... 相似文献
7.
Two synthetic protocols leading to novel γ-aminophosphonate and phosphine oxide derivatives, by reductive amination of γ-phosphonylketones, are reported. The first method involved a two-step procedure. Imine intermediates were first isolated from the p-toluenesulfonic acid-catalyzed reaction of primary amines with γ-ketophosphonates and phosphine oxides, then reduced with NaBH4 in refluxing ethanol. The second method consists of a one-pot procedure which includes the condensation of γ-ketophosphonates and phosphine oxides with primary amines, in the presence of molecular sieves, followed by reduction with NaBH4. These methods offer significant advantages over prior reports, such as efficiency, generality, and good yields. Furthermore, they are green protocols avoiding hazardous hydrides and solvents. 相似文献
8.
Habib Ammari Hyeonbae Kang Eunjoo Kim Hyundae Lee Kaouthar Louati 《Studies in Applied Mathematics》2009,122(1):85-104
The vibration behavior of structures can be characterized in terms of resonance frequencies and mode shapes, which describe properties of the tested object in a global way but do not, in general, provide information about structural details. Following an asymptotic formalism, in much the same spirit as the work in [ 3 ] and recent text [ 1 ], we develop an efficient method to address the inverse problem of identifying an internal corrosive part of small Hausdorff measure in a two-dimensional structure by vibration analysis. The viability of our reconstruction method is documented by a variety of numerical results from synthetic, noiseless and noisy data. 相似文献
9.
We establish an asymptotic expansion of the steady-state voltage potentials in the presence of a diametrically small conductivity inhomogeneity that is nearly touching the boundary. Our asymptotic formula extends those already derived for a small inhomogeneity far away from the boundary and is expected to lead to very effective algorithms, aimed at determining location and certain properties of the shape of a small inhomogeneity that is nearly touching the boundary based on boundary measurements. Viability of the asymptotic formula is documented by numerical examples. 相似文献