Photoelectrochemical properties of MWCNT-TiO2 hybrid materials as a counter electrode for dye-sensitized solar cells

The MWCNT-Ti02 hybrid materials were prepared by a simply mixing method and used as a counter electrode （CE） for dye-sensitized solar cells. Compared with the platinum CE, MWCNT-TiO2 CE has the similar redox voltage and current response in the cyclic voltammetry. The electrochemical catalytic activity was characterized by the electrochemical impedance spectroscopy and Tafel curve, including the equivalent circuit, the exchange current density, the limiting diffusion current density, and the diffusion coefficient of triiodide/iodide redox species. The results indicate that the reduction process from triiodide to iodide is determined by the kinetic-controlled and diffusion-limited processes. The device performance is optimal based on the MWCNT-TiO2 （mass ratio of 2：1） CE, such as the open-circuit voltage of 0.72 V, the short-circuit photocurrent density of 15.71 mA/cm2, the fill factor of 0.68, and the photon-to-electron conversion efficiency of 7.69%.     

“神龙一号”直线感应加速器物理设计

 介绍了 “神龙一号”直线感应加速器物理设计的主要考虑。“神龙一号”加速器是一台电子直线感应加速器，由3.6MeV感应迭加型注入器、72个感应加速腔、脉冲功率系统、束流输运和聚焦系统、控制系统和真空、绝缘油、绝缘气体以及去离子水系统组成。能产生20MeV、束流大于2.5kA，脉冲宽度为60ns的强流脉冲电子束，X光焦斑均方根直径为1.5mm。     

用于印刷电路板缺陷检测的光学视觉

本文提出了一种利用光学形态变换探测印刷电路板缺陷的新方法。以非相干光学相关器为基础,构成了一个实现印刷电路板微小缺陷检测的形态变换光学视觉系统给出了原理性实验结果。     

扰动Chebyshev结点上的Hermite－Fejer插值

本文发现当Ｃｈｅｂｙｓｈｅｖ结点产生某些扰动时，只要扰动量不超过，则基于扰动后的Ｃｈｅｂｙｓｈｅｖ结点的Ｈｅｒｍｉｔｅ－Ｆｅｊｅｒ插值过程仍然保持对［－１，１］上任意连续函数的一致收敛性，此外，文中还给出了这种收敛性的收敛速度估计。     

一维大气边界层光学折射率结构常数的数值模式

 提出了一种大气光学折射率结构常数的数值模式。通过解大气边界层风速、位温度、绝对湿度预报方程,表面热平衡方程和土壤热传导方程，得到地表温度、表面层的动量通量、显热通量和潜热通量。再由Monin Obukhov相似理论，从湍流通量和温度结构常数的经验关系计算出折射率结构常数。     

强正则图与Seidel变换

本文通过对图的Seidel变换进一步研究，得到了一些新的强正则图。     

介质参数对受激布里渊散射脉宽压缩的影响

 利用KrF激光和SF₆介质从理论和实验上研究了声子寿命和增益系数等介质参数对SBS脉宽压缩比和能量反射率的影响。理论上采用一维瞬态模型对SBS过程进行数值模拟，考虑了瞬态过程、介质吸收以及泵浦耗空的影响，计算了SBS介质不同参数对脉冲压缩影响的规律。实验表明，在实验参数的变化范围内声子寿命越短、增益系数越小，越有利于脉宽压缩。在0.68MPa下，脉宽压缩比达到8。数值模拟了声子寿命和介质增益系数单独变化时对SBS过程影响的规律，发现在声子寿命和增益系数同时变化时，SBS对泵浦脉冲的压缩有最佳点。     

液压泵试验台测控系统的设计与实现

为测试液压泵性能参数,设计了以工业计算机和PCI数据采集卡为核心,LabWindows/CVI为软件开发平台的液压泵试验台测控系统;以多线程技术设计程序,采用线程安全变量同步线程;采集、分析、显示系统参数,并利用滞环控制算法将油温控制在35~45℃之间,利用遇限削弱积分PID算法实现出油口、回油口压力控制;设计了人性化的报警功能;通过ODBC接口,每隔1s将系统运行参数存入数据库,以便分析故障;软件调试界面大大缩短现场调试时间;经过运行测试,系统满足设计要求。     

Total synthesis of two isoflavone C-glycosides (6-tert-butyl puerarin and 6-tert-butyl-4′-methoxypuerarin) through the deoxybenzoin pathway

The total synthesis of two isoflavone C-glycosides (6-tert-butylpuerarin and 6-tert-butyl-4′-methoxypuerarin) was achieved through the deoxybenzoin pathway with overall yields of 14.6% and 14.2%. The key intermediate 12 was obtained by de-tert-butylation of 10 with trifluoroacetic acid and Friedel-Crafts acetylation of 2-C-β-d-glucopyranoside 11. The ring closure of 12 with the POCl₃/DMF reagent resulted glucosyl isoflavone formation 13, which was debenzylated and demethylated by BBr₃ to obtain 14 and 15. This pathway represents a novel synthetic pathway based on Friedel-Crafts acetylation and Vilsmeier-Haack cyclization to achieve isoflavone C-glycosides in high yields.     

涂覆在堇青石上的负载贵金属催化剂催化氧化甲醛的性能研究

将催化性能优异的负载贵金属催化剂与拟薄水铝石(Al OOH)溶胶混合,制备得到均匀的料浆,采用料浆涂覆法将其负载到堇青石蜂窝陶瓷基体上,考察了Al OOH含量对涂层形貌、负载量、涂层牢固度的影响,并对合成的整体式催化剂进行催化氧化甲醛性能测试。结果表明,合成的负载贵金属催化剂Pt粒子粒径为1.14nm时,可在17℃完全降解甲醛;涂覆过程中Al OOH含量越高,载体负载量越大,但过高易导致孔道堵塞,涂覆不均和涂层龟裂;超声振荡测试表明,Al OOH含量对涂层牢固度影响不大,当Al OOH含量为8(wt)%时,负载型蜂窝陶瓷的催化效果和涂覆效果最佳,可以在60℃下完全降解甲醛。