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41.
42.
Xiu‐Li Wang Ke‐Ke Yang Yu‐Zhong Wang Zhi‐Xuan Zhou Yong‐Dong Jin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(14):3417-3422
A new biodegradable starch graft copolymer, starch‐g‐poly(1,4‐dioxan‐2‐one), was synthesized through the ring‐opening graft polymerization of 1,4‐dioxan‐2‐one onto a starch backbone. The grafting reactions were conducted with various 1,4‐dioxan‐2‐one/starch feed ratios to obtain starch‐g‐poly(1,4‐dioxan‐2‐one) copolymers with various poly(1,4‐dioxan‐2‐one) graft structures. The microstructure of starch‐g‐poly(1,4‐dioxan‐2‐one) was characterized in detail with one‐ and two‐dimensional NMR spectroscopy. The effect of the feed composition on the resulting microstructure of starch‐g‐poly(1,4‐dioxan‐2‐one) was investigated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3417–3422, 2004 相似文献
43.
44.
A three-dimensional Ising-like model doped with anti-ferromagnetic (AFM) bonds is proposed to investigate the magnetic properties
of a doped triangular spin-chain system by using a Monte-Carlo simulation. The simulated results indicate that a steplike
magnetization behavior is very sensitive to the concentration of AFM bonds. A low concentration of AFM bonds can suppress
the stepwise behavior considerably, in accordance with doping experiments on Ca3Co2O6. The analysis of spin snapshots demonstrates that the AFM bond doping not only breaks the ferromagnetic ordered linear spin
chains along the hexagonal c-axis but also has a great influence upon the spin configuration in the ab-plane.
相似文献
45.
Jin Kyu Park Dong Hun Lee Bok Ju Song Jae Buem Oh Hwan Kyu Kim 《Journal of polymer science. Part A, Polymer chemistry》2006,44(3):1326-1342
We have designed and synthesized novel perfluorinated polyimides with 3D controlled structure. At first, we successfully developed the new synthetic routes to diamines with pendant bulky perfluorinated aromatic units in a multi‐step synthetic procedure. Novel perfluorinated polyimides were prepared in a two‐step reaction in N‐methyl‐2‐pyrrolidinone (NMP) solution: The first step was for the synthesis of polyamic acids (PAAs) and the second reaction was for the imidization of PAA. The polymer yield was over 89% and the inherent viscosity of PAAs was in the range of 0.24–0.36 dL/g. The thin films were prepared by spin‐coating the PAA solution in NMP onto various substrates such as a Si wafer or a KBr pellet, dried at 80 °C and further cured at 230 °C. The resultant polyimides are thermally stable over 400 °C. The refractive index and birefringence of the resultant polyimides are 1.5858–1.6452 and 0.01–0.005, respectively. The refractive index of polyimide decreases with increasing the fluorine content. The copolymerization and the ether linkages into the backbone reduce the birefringence of polyimides. Surprisingly, the pendant ether linkage is not a crucial factor in reducing the polyimide birefringence. Their birefringence is comparatively very low, compared with that of previous polyimides. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 1326–1342, 2006 相似文献
46.
Xiaoqing Liu Chuncheng Li Dong Zhang Yaonan Xiao 《Journal of Polymer Science.Polymer Physics》2006,44(6):900-913
This article investigated the melting behaviors, crystallization kinetics, and spherulitic morphologies of poly(butylene succinate) (PBS) and its copolyester (PBSR) modified with rosin maleopimaric acid anhydride, using wide‐angle X‐ray diffraction, differential scanning calorimeter (DSC), and polarized optical microscope. Subsequent DSC scans of isothermally crystallized PBS and PBSR exhibited two melting endotherms, respectively, which was due to the melt‐recrystallization process occurring during the DSC scans. The equilibrium melting point of PBSR (125.9 °C) was lower than that of PBS (139 °C). The commonly used Avrami equation was used to describe the isothermal crystallization kinetics. For nonisothermal crystallization studies, the model combining Avrami equation and Ozawa equation was employed. The result showed a consistent trend in the crystallization process. The crystallization rate was decreased, the perfection of crystals was decreased, the recrystallization was reduced, and the spherulitic morphologies were changed when the huge hydrogenated phenanthrene ring was added into the chain of PBS. The activation energy (ΔE) for the isothermal crystallization process determined by Arrhenius method was 255.9 kJ/mol for PBS and 345.7 kJ/mol for PBSR. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 900–913, 2006 相似文献
47.
A. Subramanian T.-Y. Choi L.X. Dong J. Tharian U. Sennhauser D. Poulikakos B.J. Nelson 《Applied Physics A: Materials Science & Processing》2007,89(1):133-139
We report on a novel method for local control of shell engineering in multiwalled carbon nanotubes (MWNTs) using Joule-heating
induced electric breakdown. By modulating the heat dissipation along a nanotube, we can confine its thinning and shell breakdown
to occur within localized regions of peak temperatures, which are distributed over one-half of the NT length. The modulation
is achieved by using suitably designed nanomachined heat sinks with different degrees of thermal coupling at different parts
of a current-carrying nanotube. The location of electric breakdown occurs precisely at the regions of high temperatures predicted
by the classical finite-element model of Joule heating in the MWNT. The experiments herein provide new insight into the electric
breakdown mechanism and prove unambiguously that shell removal occurs due to thermal stress, underpinning the diffusive nature
of MWNTs. The method demonstrated here has the potential to be a powerful tool in realizing MWNT bearings with complex architectures
for use in integrated nanoelectromechanical systems (NEMS). In addition, the breakdown current and power in the nanotubes
are significantly higher than those observed in nanotubes without heat removal via additional heat sinks. This indicates future
avenues for enhancing the performance of MWNTs in electrical interconnect and nanoelectronic applications.
PACS 73.63.Fg; 65.80.+n 相似文献
48.
In this paper we prove the semialgebraic version of Palais' covering homotopy theorem, and use this to prove Bredon's covering mapping cylinder conjecture positively in the semialgebraic category. Bredon's conjecture was originally stated in the topological category, and a topological version of our semialgebraic proof of the conjecture answers the original topological conjecture for topological G-spaces over “simplicial” mapping cylinders. 相似文献
49.
K. -H. Speidel M. Knopp W. Karle U. Kilgus M. -L. Dong H. -J. Simonis F. Hagelberg J. Gerber 《Zeitschrift für Physik A Hadrons and Nuclei》1988,331(1):29-36
Transient field precessions have been measured with the first excited 2 1 + -state as probe for ions of28Si traversing Fe at vion?1v0 and 13v0(v0=c/137) and62Ni being stopped in Fe. The degree of polarization deduced for the Si ions, p1s=0.19(6), is consistent with low-velocity data. There is clear evidence that the field strength is attenuated by heavy ion beams. For the62Ni(2 1 + ) state at 1.173 MeV a g-factor value of g=0.34(7) was obtained in good agreement with a previous result. 相似文献
50.
In order to better understand the early continental evolution of the Anshan area, one ofthe typical Precambrian distribution areas of the North China Craton, the geochronology and REEcomposition of the zircons from the meta-argillo-arenaceous rock occurred as enclave in 3.1 GaLishan trondhjemite are studied by using SHRIMP ll ion microprobe. It is indicated that the Pa-leoarchaean is a very important continental formation period in the Anshan area and 3.2 Ga can beregarded as the boundary between the Paleoarchaean and Mesoarchaean. 相似文献