Electrodeposition of CuInSe<Subscript>2</Subscript> films onto a molybdenum electrode

Joint reduction of Cu(II), Se(IV), and In(III) ions at a molybdenum electrode from a solution based of sulfosalicylic acid solution was studied. The optimal range of potentials for deposition of the CuInSe₂ compound was chosen. The composition of the films obtained was confirmed by X-ray phase and electron microprobe analyses.     

固体酸对醇酸树脂聚酯反应的催化作用

本文研究了固体酸对醇酸树脂缩聚酯反应的催化作用,讨论了催化剂的表面酸度、制备条件及反应物分子构型等对催化聚酯反应的影响。在接近生产条件下研究了醇酸树脂聚酯反应动力学,发现多相酸催化聚酯反应与均相酸催化聚酯反应具有相似的动力学规律。     

甲醇在超临界环已烷中形成簇团的Monte Carlo初探

用Ｍｏｎｔｅ Ｃａｒｌｏ方法研究了甲醇－环己烷体系的微观结构随压力（密度）的变化情况，结果表明，在临界区域甲醇分子的聚集最为明显，形成的甲醇团簇尺寸最大，溶剂分子在甲醇周围的局部密度则在低于临界区或亚临界区较大。     

Effect of nucleating agent on the structure and properties of polypropylene/poly(ethylene-octene) blends

The effect of the sorbital nucleating agent on properties of the ethylene-octene copolymer (POE) toughened polypropylene (PP) was studied. The results show that the addition of POE increases notched Izod and Charpy impact strength significantly but impair the tensile strength and flexural modulus. As a nucleating agent (1,3,2,4-di(p-methylbenzylidene) sorbitol, DM) was added, the toughness and stiffness of toughed PP increased simultaneously at the same content of POE. This result shows that the toughness and stiffness of toughed PP are in balance. Polarized light microscopy analysis shows that with the addition of POE and nucleating agent, only a low level of PP spherulites were observed.     

茶叶中三氯螨杀醇残留量的快速HPLC测定法

用微量化技术处理茶叶样品，样品经石油醚提取、浓硫酸磺化后，用反相液相色谱分离、测定样品处理液中的三氯杀螨醇残留量，２３４ｎｍ检测，外标法定量。测定低限为０．５ｍｇ／ｋｇ，回收率为９１．５％～９９．３％，变异系数为１．５３％～６．９２％之间。     

固体酸催化醇酸树脂的分子量分布及其与性能关系的研究

本文用HPGPC法等研究了固体酸催化醇酸树脂合成中MWD及其与性能的关系。结果表明,固体酸催化醇酸树脂化过程的MWD等物性变化规律与未加催化剂的相似,logM_w和logd与p、M_w与分散度d及logη_G与M_w之间均呈线性关系。然而在达到同样M_w和MWD时,催化新工艺所需时间大大缩短,所需温度也有较大下降,而所得树脂粘度较低,贮存稳定性更好,其成膜干性更好,漆膜硬度也较高。     

Synthesis of Novel N‐Pyridylcantharidinimides by Using High Pressure

The recently described pressure reaction in the presence of trithylamine with subsequent thermal (200°C) cyclization provided 13N‐pyridylcantharidinimides 4a‐4m from aminopyridines and cantharidin in yields of 15–83%. 2‐Amino‐3,5‐dichloropyridine failed to yield 4n .     

Characterization of Novel Aminobenzylcantharidinimides and Related Imides by Proton NMR Spectra and Their Effects on NO Induction

Various acidic anhydrides including cantharidin were converted into corresponding aminobenzylcantharidinimide 3a and analogous imides 3b～k (at the ortho, meta, and para positions) with 35%～87% yields by reacting with aminobenzylamines and triethylamine. The two methyl side chains of cantharidinimides 3ao , 3am , and 3ap, and related imides had more than two chiral centers; the lone pair of electrons of nitrogen displayed a different chemical shift and coupling constant in H‐NMR spectra when the amino group of benzylamine was in the ortho position. These cantharidinimides had parent aniline, pyridine, and naphthalene plane structures, and the primary amine nucleophilicity and basicity might reflect the inductive electron’s negative effect on chemical shifts. We prepared cantharidinimides by heating the reactants cantharidin 1a , aliphatic and aromatic acid anhydrides, primary benzylic amines, and aniline derivatives to ca. 200 °C with 3 mL of dry toluene, and 1～2 mL of triethylamine in high‐pressure sealed tubes (Buchi glasuster 0032) to produce cantharidinimides and their analogues in good yields. The para‐aminobenzylic imides showed greater inhibition of nitric oxide (NO) synthesis by NO synthase (NOS) than did ortho‐ and meta‐aminobenzylic imides. Compound 3fp , para‐aminobenzylic norbonane‐imide, had the most potent effect on inducible NOS among the tested compounds and showed 35% inhibition.     

单分散二氧化钛超微粒子的制备

以四丁氧基钛为原料，采用溶胶－凝胶法制备了超微二氧化钛粉末．改变热处理气氛、升温速率、水与四丁氧基钛的摩尔比以及溶剂，分别得到７ｎｍ球形单相锐钛矿以及四方形（４０ｎｍ×１０ｎｍ）、球形（４４ｎｍ）的主相金红石超微粒子．     

Chains, ladders and sheets of d metal–organic polymers generated from the flexible bipyridyl ligands

By use of the three-layer diffusion method, reactions of flexible bipyridyl ligands (4,4′-bpp or 3,3′-bpp) with M(II) salts (M = Zn, Cd) and multi-carboxylate ligands resulted in the formation of four interesting d¹⁰ metal–organic coordination polymers: [Zn(μ-4,4′-bpp)Br₂]_n (1), [Zn(μ-4,4′-bpp)(1,2-bdc)]_n · nH₂O (2), [Zn(μ-3,3′-bpp)(1,3-bdc)]_n · nCH₃OH · 2nH₂O (3) and [Cd(μ-3,3′-bpp)(C₄H₂O₄)]_n · 3nH₂O (4) (4,4′-bpp = 2,2′-bis(4-pyridylmethyleneoxy)-1,1′-biphenylene; 3,3′-bpp = 2,2 ′-bis(3-pyridylmethyleneoxy)-1,1′-biphenylene; bdc=benzenedicarboxylate, C₄H₄O₄ = fumaric acid). Complex 1 has a 2D sheet structure consisting of two unusual zigzag Zn(II) chains which are nearly perpendicular to each other. Complex 2 is comprised of two-leg ladders, in which [Zn(4,4′-bpp)] chains serve as the side rails and 1,2-bdc ligands serve as the cross rungs. In complex 3, every two 1,3-bdc ligands connect the neighbouring Zn(II)-3,3′-bpp dimetallic rings in η¹ coordination modes into an interesting chain structure. Complex 4 consists of an anionic macrocycle-containing cadmium dicarboxylate sheets that are separated by 3,3′-bpp. These d¹⁰ metal complexes exhibit high thermal stabilities and strong luminescence efficiencies.