Compton散射下固体温度变化对光声信号强度的影响

应用多光子非线性Compton散射模型,研究了固体温度变化对光声信号强度的影响。结果表明,在Compton散射光和入射光形成的耦合光强度和频率不变时,随固体温度的升高,光声信号强度非线性迅速增强;固体温度不变时,随耦合激光强度和频率的增大,光声信号强度几乎趋于0。     

xTeO2-(98-x)PbO-2Bi2O3玻璃的结构表征及在硅太阳能电池正面银浆中的应用

采用熔体冷却法制备了xTeO2-(98-x) PbO-2Bi2O3(x=40mol;、45mol;、50mol;、55mol;、60mol;)玻璃试样,利用红外和拉曼光谱对玻璃结构随TeO2含量的变化进行了分析,同时研究了TeO2含量对玻璃软化温度(Tf)、热膨胀系数(α)及化学稳定性(DR)的影响;将以上玻璃粉与银粉以及有机载体按一定比例配制成银浆,在硅基片正面经丝网印刷和快速烧结制得正面电极,研究了玻璃粉对硅基片表面所镀减反膜的腐蚀效果以及正面电极附着力(T)和电阻率(p)的影响.结果表明:随着TeO2含量的增加,玻璃主要结构单元逐渐由[TeO3]三角锥和[PbO4]四方锥体转变为[TeO4]三角双锥,当x=55mol;时,主要结构单元为[TeO3]三角锥和[TeO4]三角双锥,此时碲酸盐玻璃的综合性能良好:r =540℃,α=16×10-6/℃,DR=6.5605×10-8 g·cm-2·min-1玻璃粉对减反膜的腐蚀作用较明显,正面电极与硅基片附着力较大,电阻率较低,T=4.4 N,ρ=2.617μΩ·cm.     

Structure of D Pair in Collective States of Nuclei

As a successive work a modified D pair independent of the S pair treated in our previous papers is introduced to avoid the seniority mixing problem. The structure amplitudes of this D pair and S pair are determined simultaneously and self-consistently by iteration.     

Palladium-Catalyzed Tandem Carbonylative Aza-Wacker-Type Cyclization of Nucleophile Tethered Alkene to Access Fused N-Heterocycles

Although tandem reactions offer rapid access to structurally complex molecules in one-pot reaction,the selectivity issue needs to be addressed particularly when incompatible step reactions are involved.Herein,we report the selective synthesis of fused N-heterocycles from nucleophile-tethered alkenylamide and carbon monoxide via palladium(Pd)-catalyzed tandem carbonylative aza-Wacker-type cyclization.The electron-deficient nature of amide N—H and the intramolecular coordination of Pd with alkene accelerate the aminopalladation and effectively prevent the side oxidative carbonylation of diamine moiety to form urea.It is also found that the reported acyl Pd chloride intermediate may not be involved in this tandem cyclization.This work not only provides an efficient synthetic route to fused 1,4-diazepanones and 1,4-diazepanes but also inspires further development of tandem reactions for the diverse synthesis of heterocycles.     

光交联法合成水凝胶的研究

合成了一种新型光敏性功能单体N -肉桂酰氧甲基丙烯酰胺 (CMMAM)及其与丙烯酸 (AA)的共聚物(CMMAM -AA) ,通过光交联法进一步合成水凝胶 .测定了CMMAM和CMMAM -AA聚合物的红外光谱 ,测定了水凝胶的DSC并对它的溶胀性能进行了初步研究     

Ce0.5-xZr0.5-xBa2xO2负载TiO2光催化降解气相苯

在密闭不锈钢反应器内研究了Ce0.5-xZr0.5-xBa2xO2负载锐钛型TiO2光催化降解气相苯的性能.确定了该系列光催化剂的最佳Ba含量,并应用X射线衍射、紫外-可见漫反射光谱以及X射线光电子能谱对催化剂进行了表征.结果表明,TiO2在载体表面均匀分散.在210~400 nm范围内,TiO2/Ce0.5-xZr0.5-xBa2xO2比TiO2吸收更多的紫外光.TiO2/Ce0.5-xZr0.5-x-Ba2xO2包含Ti和O两种元素,TiO2/Ce0.5-xZr0.5-xBa2xO2的Ti 2p结合能向低能端偏移.Ce0.5-xZr0.5-xBa2xO2表面负载TiO2能有效提高催化剂的光催化活性.Ce0.5-xZr0.5-xBa2xO2的作用是转移电子和使催化剂在紫外区的吸收增强.     

Rapid characterization of the sucrose esters from oriental tobacco using liquid chromatography/ion trap mass spectrometry

Sucrose esters (SEs) from oriental tobacco are normally characterized by gas chromatography/mass spectrometry (GC/MS) after a long saponification and derivatization procedure. To simplify the process, a rapid method has been developed by using liquid chromatography coupled with electrospray ion trap mass spectrometry (LC/ESI-MSn). Using the characteristic fragmentation behavior of abundant SEs identified by GC/MS after purification by gel permeation chromatography (GPC) from cuticular waxes of green oriental tobacco leaf, two types of SEs from green and cured oriental tobacco were identified by MSn analysis. The first is one of three types reported formerly and has 13 SE homologues. However, the presence of unsaturation in one of the acyl substituents of this first type gave rise to a new series with three homologues. The other was found to be a new type and had three homologues. The proposed method enables the rapid and sensitive characterization of SEs from oriental tobacco.     

Application of preparative high-speed counter-current chromatography for separation and purification of arctiin from Fructus Arctii

Following an initial clean-up step on the AB-8 resin (polystyrene resin, 0.3-1.25 mm: NanKai Chemical Factory, Tianjin, China), high-speed counter-current chromatography (HSCCC) was used to purify an arctiin from an extract of the fruits of the Arctium lappa L. Arctiin is a major lignan compound in the traditional Chinese medicinal herb A. lappa L. The two-phase solvent system used was composed of ethyl acetate-n-butanol-ethanol-water at an optimized volume ratio of 5:0.5:1:5 (v/v/v/v). The upper phase was used as the mobile phase in the head to tail elution mode. A total amount of 159 mg of arctiin at 98% purity was obtained from 350 mg of the crude extract (containing 49% arctiin) with 91% recovery. The preparative isolation and purification of arctiin by HSCCC was completed in 5 h in a separation. Identification of the target compound was performed by LC-electrospray ionization MS and 13C-NMR. The structure of the product was further confirmed by comparison with authentic sample (National Institute of the Control of Pharmaceutical and Biological Products, Beijing, China).     

GPS局域增强系统基准站多路径抑制消除技术

GPS局域增强系统(LASS)作为飞机精密进场和着陆的最重要的导引系统,使得飞机进场过程实现全面GPS化。但是,由于DGPS多路径效应误差的存在极大地影响了LASS系统的性能,降低了飞机进场过程的导航精度。因此从多路径效应误差产生原理入手,通过分析多路径效应误差的特性和建立多路径效应误差信道模型,并在此基础上提出了运用特殊设计的多路径抑制天线以及利用动态基准站和双差测量技术抑制多路径误差的方法。运用该方法,不仅能避免飞机机身反射信号所引起的多路径效应,还可以对地面及地面物体反射引起的多路径效应误差起到很好的消除作用,从而极大地改善LASS的性能,提高飞机进场过程的安全性和导航精度。     

足部安装MEMS-IMU个人导航系统

为了实现室内外环境下个人自主导航,研究了足部安装的MEMS-IMU个人导航系统。根据人行走时足部具有周期性零速的特征,以加速度计输出矢量和、滑动方差和陀螺仪输出的角速度矢量和为检测量,设计了一种多条件零速检测算法,有效地提高了零速检测的准确性。针对MEMS惯性传感器零漂大、精度低的问题,导航定位算法以传统的捷联解算算法为基础,进行了适应性改进。引入零速修正(ZUPT)技术,设计了以速度信息作为伪量测的Kalman滤波器。在零速阶段对系统速度,姿态,位置误差进行估计,将估计结果反馈以修正导航解算的累积误差。实验结果表明,基于上述导航修正算法可以有效地消除MEMS惯性传感器零漂引起的累积误差,使得多组多种行走路径下系统的定位误差均小于行程的2%。