qq-2-树整子图的色性

研究具有与qq-2-树整子图有相同色多项式的图的结构,利用分类法,得到当q至少为2至多为5时qq-2-树整子图的色性.     

一般非线性扩散方程Cauchy问题广义解的渐近性质

本文研究了比较一般的非线性扩散方程的Cauchy问题广义解的渐近性质.利用试验函数与积分估计的方法,获得了广义解当t→∞时的渐近性质以及其广义整体解u(x,t),推广了该类方程Cauchy问题广义解的性质.     

Effect of manganese substitution on the crystal structure and decomposition kinetics of siderite

In this study, Mn-substituted siderites with different substitution amounts were prepared and characterized by using XRD (X-ray diffraction), TEM (transmission electron microscope), TG and DTG (thermogravimetry and derivative thermogravimetry) and Raman spectroscopy. The effect of Mn substitution on the crystal structure of siderite and thermal decomposition processes of synthetic siderite was investigated. The substitution of Mn for Fe in the crystal structure of siderite resulted in an increase in a and c dimensions from 4.702 and 15.374 to 4.718 and 15.43 Å as the substitution amount increased from 0 to 7.4%, respectively. The substitution of Mn also decreased the crystallinity of siderite. The thermal decomposition of synthetic siderite took place at approximately 350 °C. However, the substitution of Mn for Fe increased the decomposition temperature and improved the activation energy (E_d) values from 126.3, 155.7, 156.8 to 164.5, 167.6, 170.3 kJ mol⁻¹ when Mn substitution increased from 0 to 7.4 mol%.

     

高温超导氧化物中非平衡载流子的能量弛豫与电声相互作用

利用超导体中非平衡能量平衡模型,研究室温下YBa₂Cu₃O_7-δ(δ=0.1,0.4,0.8)和PrBa₂Cu₃O₇外延膜中光激活非平衡载流子的弛豫动力学,计算了电声耦合常数λ发现随着氧含量的降低及用Pr替代Y,Cu-O面上空穴Fermi面向Cud⁹/d¹⁰带方向移动,非平衡载流子的驰豫时问增加而电声耦合常数明显减小.这一结果与瞬态反射谱测量结果符合得很好.这表明载流子浓度的降低减弱了电声相互作用,而这种作用可能是一种实空间的局域相互作用.     

微秒级时间分辨傅里叶变换红外光谱激发系统研究

本文阐述了自行研制的、与FTIR仪器连接运行的时间分辨FTIR系统,包括光激发和电场激发两套系统。检验和测试了系统的工作参数和性能,获得了微秒-毫秒级时间分辨光谱图。     

b≤2000,m≤10的广义Fermat素数

设b为偶数，本文基于作者的原有结果，进一步改进了算法，对于b≤2000,m≤10给出了所有广义Fermat素数F(b,m)=b^2m 1，其中最大的是1632^1024 1,有3290位。     

Determination of nine volatile N‐nitrosamines in tobacco and smokeless tobacco products by dispersive solid‐phase extraction with gas chromatography and tandem mass spectrometry

A method was developed for the determination of nine volatile N‐nitrosamines in tobacco and smokeless tobacco products. The targets are N‐nitrosodimethylamine, N‐nitrosopyrrolidine, N‐nitrosopiperidine, N‐nitrosomorpholine, N‐nitrosoethylmethylamine, N‐nitrosodiethylamine, N‐nitrosodipropylamine, N‐nitrosobuylmethylmine, and N‐nitrosodibutylamine. The samples were treated by dispersive solid‐phase extraction using 1 g of primary secondary amine and 0.5 g of carbon and then analyzed by gas chromatography with tandem mass spectrometry with an electron impact ion source. The recoveries for the targets ranged from 84 to 118%, with <16% relative standard deviations at three spiking levels of 0.5, 1.25, and 2.5 ng/g. The limits of detection ranged from 0.03 to 0.15 ng/g. With the use of the proposed method, we detected the presence of six nitrosamines in the range of 0.4–30.7 ng/g. The study demonstrated that the method could be used as a rapid, convenient, and high‐throughput method for N‐nitrosamines analysis in tobacco matrix.     

Quantification of cis-Abienol in Oriental Tobacco Leaves by LC

A rapid and accurate method for the quantification of cis-abienol in oriental tobacco leaves by normal phase liquid chromatography was developed. Freeze-dried tobacco samples were sonicated in methylene chloride for 10 min. The supernatant was purified using a silica gel solid phase extraction cartridge. Ten milliliter of the resulting methylene chloride eluate was collected, then separated on a 250 × 4.6 mm, 5 μm particle-size CN column with n-hexane: ethyl acetate, 100:2 (v/v) at a flow rate of 1 mL min⁻¹. cis-Abienol was detected by UV absorption at 254 nm. The linear range was from 2.14 × 10⁻⁴ to 4.28 × 10⁻² mg mL⁻¹ and the correlation coefficient was 1.000. The average recovery was 98.7, 105.2 and 103.1% in five replicated sets of tobacco samples spiked with 0.2856, 0.7140 and 1.904 mg cis-abienol. The relative standard deviations (RSDs) were 1.04, 0.63 and 1.25%, respectively (n = 5). Limit of detection (S/N = 3) was 21.84 μg g⁻¹ and limit of quantification (S/N = 10) was 72.80 μg g⁻¹. The method was found to be suitable for determination of cis-abienol in oriental tobacco leaves. Furthermore, pure cis-abienol used for method validation was obtained by preparative reversed phase high-performance liquid chromatography. Identification was performed by UV detection, nuclear magnetic resonance and mass spectrometry.     

Application of preparative high-speed counter-current chromatography for separation and purification of arctiin from Fructus Arctii

Following an initial clean-up step on the AB-8 resin (polystyrene resin, 0.3-1.25 mm: NanKai Chemical Factory, Tianjin, China), high-speed counter-current chromatography (HSCCC) was used to purify an arctiin from an extract of the fruits of the Arctium lappa L. Arctiin is a major lignan compound in the traditional Chinese medicinal herb A. lappa L. The two-phase solvent system used was composed of ethyl acetate-n-butanol-ethanol-water at an optimized volume ratio of 5:0.5:1:5 (v/v/v/v). The upper phase was used as the mobile phase in the head to tail elution mode. A total amount of 159 mg of arctiin at 98% purity was obtained from 350 mg of the crude extract (containing 49% arctiin) with 91% recovery. The preparative isolation and purification of arctiin by HSCCC was completed in 5 h in a separation. Identification of the target compound was performed by LC-electrospray ionization MS and 13C-NMR. The structure of the product was further confirmed by comparison with authentic sample (National Institute of the Control of Pharmaceutical and Biological Products, Beijing, China).     

An NHC-Stabilized H2GeBH2 Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains

The synthesis, characterization and reactivity studies of the NHC-stabilized complex IDipp ⋅ GeH₂BH₂OTf ( 1 ) (IDipp=1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) are reported. Nucleophilic substitution of the triflate (OTf) group in 1 by phosphine or arsine donors provides access to the cationic group 13/14/15 chains [IDipp ⋅ GeH₂BH₂ERR¹R²]⁺ ( 2 E=P; R, R¹=H; R²=^tBu; 3 E=P; R=H; R¹, R²=Ph; 4 a E=P; R, R¹, R²=Ph; 4 b E=As; R, R¹, R²=Ph). These novel cationic chains were characterized by X-ray crystallography, NMR spectroscopy and mass spectrometry. Moreover, the formation of the parent complexes [IDipp ⋅ GeH₂BH₂PH₃][OTf] ( 5 ) and [IDipp ⋅ GeH₃][OTf] ( 6 ) were achieved by reaction of 1 with PH₃. Accompanying DFT computations give insight into the stability of the formed chains with respect to their decomposition.