瑶药野葛花中6种无机元素的测定

用原子吸收光谱法测定野葛花原生药、野葛花汤剂中的 Ca、Mg、Cu、Zn、Fe、Mn等 6种无机元素含量。结果表明 ,原药和水煎液中 Ca、Mg含量比较丰富 ;各种元素的煎出率存在着较大的差异 ,其中 Cu、Zn、Fe的煎出率较高 ,Zn最高 ,达到了 82 .5 6 % ;Ca最低 ,为 5 .5 8%。并且将其结果与葛根的无机元素做了比较。为探讨无机元素与中药药效之间的关系提供了基础数据。     

Ultrasonic investigation of amorphous carbon in various frequencies at low temperatures from 2.1 to 300 K

Using pulse echo overlap measurement, the elastic behavior of amorphous carbon has been studied at ambient and low temperatures. The smaller ratio B/G of the bulk modulus to shear modulus and smaller Poisson's ratio σ at room temperature indicate that there is an intrinsic stiffening of transverse acoustic phonons in the amorphous carbon. The acoustic velocity and attenuation for longitudinal modes have been measured between 2.1 and 300 K at three frequencies of 7, 21 and 35 MHz, respectively. Their frequency and temperature dependence are observed. The elastic constant C₁₁ increases with decreasing temperature and show enhanced stiffening at low temperatures. In the 130-220 K region, the abnormal change and effect of longitudinal velocity and attenuation with temperature and frequency, and a phase transition associated with structure relaxations are discussed.     

Q-正则Loewner空间中的拟对称映射

本文在Q-正则Loewner空间中用环模不等式刻划了拟对称映射.另外,在 Q-维Ahlfors-David正则空间中建立了拟对称映射作用下的Grotzsch-Teichmuller型 模不等式,它是通过伸张系数的积分平均来表示.     

A theorem of Grünwald-type for Hermite-Fejér interpolation of higher order

In this paper we give a theorem of Grünwald-type for (0, 1,...,m-1) Hermite-Fejér interpolation (m=2, 4,...), which extends the famous result for a strongly normal system of nodes in the casem=2 given by Grünwald in [1].     

Viscosity-splitting scheme for the Navier-Stokes equations

A viscosity-splitting scheme for the initial boundary value problems of the Navier-Stokes equations is considered. In the scheme, the Stokes equation is solved in conjunction with a nonhomogeneous boundary condition which connects the tangent flow with a no-slip flow. Convergence is proved.     

Irradiation-induced reduction and luminescence properties of Sm doped in BaBPO5

Usually, Sm²⁺ ions could be reduced by heating the materials in reducing atmospheres. Exposure to ionizing radiations is also known to cause Sm³⁺→Sm²⁺ conversion. In this work, BaBPO₅ doped with the samarium ion was prepared by high temperature solid-state reaction. Sm²⁺ ions were obtained by two different reduction methods, i.e., heating in H₂ reduced atmosphere and X-ray irradiation. The measurements of X-ray diffraction (XRD), and scanning electron microscope (SEM) were investigated. It is found that the conversion of Sm³⁺→Sm²⁺ is very efficient in BaBPO₅ hosts after X-ray irradiation. Sm²⁺ ions under these two reduction methods exhibit different characteristics that were studied by measurements of luminescence and decay. The results showed that the luminescence properties of Sm²⁺ ions in BaBPO₅ were highly dependent on the sample preparation conditions.     

Synthesis of grafted poly(p‐phenyleneethynylene) with energy donor–acceptor architecture via atom transfer radical polymerization: Towards nonaggregating and hole‐facilitating light‐emitting material

In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007     

First Total Synthesis of 12-Hydroxy-13-methylpodocarpa-9, 11, 13-trien-3-one

12-Hydroxy-13-methylpodocarpa-9, 11, 13-trien-3-one 9 was isolated from the twigs ofCroton salutaris1. Many diterpenes exhibit significant bioactivities, such as antibac-terial and antitumour and 9 has a rare structure. In order to study the relationshipb…