二维大U-Hubbard模型的铁磁相研究

本文利用Zou和Anderson的spinon-holon有效哈密顿量,在较大的库仑排斥U下,通过研究玻色子holon的涨落效应,考虑了平方格点上铁磁性问题。 关键词：     

YAlO3:Nd3+的吸收光谱

从0.33—5.7μm的波长范围内系统地测定了温度为10K、90K和30OK时YAlO₃:Nd³⁺的吸收光谱,定出Nd³⁺在晶体场作用下的斯塔克(Stark)子能级。并在10K到663K的温度范围内,观察了部分光谱线的温度效应,得到一些有意义的结果。 关键词：     

重力热管弹状流工况的简化分析

对重力热管弹状流工况进行简化分析，定量描述工业热管工作过程中蒸发段内汽泡的喷涌现象，给出液塞在弹状汽泡载带下的提升高度Ｌ５和体积流量与两端压力间的定量关系．     

双KTP晶体倍频过程的实验研究腔外串接倍频

双KTP晶体串接倍频可以克服离散效应并补偿相位失配。本文对串接倍频进行了理论分析与实验观测,指出最佳串接方位。理论分析与实验结果符合很好。     

三角形Toeplize矩阵的三角本原指数

讨论了三角形 Toeplize矩阵与一元多项式的关系以及非负三角形 Toeplize矩阵的三角本原指数 ,证明了 n阶非负上三角 Toeplize矩阵的三角本原指数集 Sn={1 ,2 ,… ,k-1 ,k,k1,k2 ,… ,ks,n-1 },其中 k是满足 k >4n -3 -12 和 n -1k +1 =n -1k 的最小整数 .     

从1+1=?谈到国民经济部门或产品的综合

当我们构造多部门数量经济模型的时候,往往要将千千万万种产品归结为几种产品或者几个部门.讨论如何将多种产品归结或综合成1种或少数几种产品.指出如何确定综合产品的数量与价格.并且给出相应的计算公式.指出综合产品的数量、综合产品的价格与不变价、现价、真实物价指数、通货膨胀率之间的关系.     

高TcYBa2Cu3O7/PrBa2Cu3O7超晶格的微结构分析

利用高分辨透射电子显微镜对高T_c YBa₂Cu₃O₇/PrBa₂Cu₃O₇(以下简称为YBCO/PrBCO)超晶格的微结构进行了系统的观察分析,高分辨电子显微象(HREM)表明YBCO/PrBCO超晶格层与层之间具有清晰的衬度,没有界面互扩散,通过HREM象观察,发现衬底表面的原子台阶和缺陷使薄膜最初1—2个晶胞层中出现层错等缺陷,但这些缺陷并没有向薄膜内部扩展,当薄膜厚度超过几个晶胞层后,其结构趋于完整。另外,在HREM照片上还可看出YBCO/PrBCO超晶格的调制周期存在波动,波动范围相当于一个晶胞层厚度,实验结果表明,利用YBCO/PrBCO超晶格研究CuO₂面的二维超导电性时,临界温度T_c和临界电流密度J_c的变化不仅与二维CuO₂面的失耦程度有关,还会受到各种晶格缺陷的影响,对YBCO/PrBCO超晶格和超薄YBCO膜的输运特性进行理论解释时,必须考虑衬底和晶格缺陷造成的影响。     

Fast and Selective Semihydrogenation of Alkynes by Palladium Nanoparticles Sandwiched in Metal–Organic Frameworks

The semihydrogenation of alkynes into alkenes rather than alkanes is of great importance in the chemical industry. Unfortunately, state‐of‐the‐art heterogeneous catalysts hardly achieve high turnover frequencies (TOFs) simultaneously with almost full conversion, excellent selectivity, and good stability. Here, we used metal–organic frameworks (MOFs) containing Zr metal nodes (“UiO”) with tunable wettability and electron‐withdrawing ability as activity accelerators for the semihydrogenation of alkynes catalyzed by sandwiched palladium nanoparticles (Pd NPs). Impressively, the porous hydrophobic UiO support not only leads to an enrichment of phenylacetylene around the Pd NPs but also renders the Pd surfaces more electron‐deficient, which leads to a remarkable catalysis performance, including an exceptionally high TOF of 13835 h^?1, 100 % phenylacetylene conversion 93.1 % selectivity towards styrene, and no activity decay after successive catalytic cycles. The strategy of using molecularly tailored supports is universal for boosting the selective semihydrogenation of various terminal and internal alkynes.     

A Nano‐shield Design for Separators to Resist Dendrite Formation in Lithium‐Metal Batteries

Lithium dendrite growth during repeated charge and discharge cycles of lithium‐metal anodes often leads to short‐circuiting by puncturing the porous separator. Here, a morphological design, the nano‐shield, for separators to resist dendrites is presented. Through both mechanical analysis and experiment, it is revealed that the separator protected by the nano‐shield can effectively inhibit the penetration of lithium dendrites owing to the reduced stress intensity generated and therefore mitigate the short circuit of Li metal batteries. More than 110 h of lithium plating life is achieved in cell tests, which is among the longest cycle life of lithium metal anode and five times longer than that of blank separators. This new aspect of morphological and mechanical design not only provides an alternative pathway for extending lifetime of lithium metal anodes, but also sheds light on the role of separator engineering for various electrochemical energy storage devices.