湍流边界层拟序结构的实验研究

20世纪60年代后, 先后从流动显示发现了快慢斑、猝发、上升流、下扫流和多种涡结构等湍流边界层的拟序结构. 它们对湍流边界层的摩阻、传热传质和湍动能的产生等特性有重要影响. 涡结构是上述拟序结构的核心, 它影响其它拟序结构的发展和演变. 发卡涡通常被认为是基本涡结构. 发卡涡等涡结构的再生, 是湍流边界层拟序结构能够自持续的必要的因素.壁面低速流上升产生猝发, 是湍流边界层湍能的主要来源; 条件采样是测量猝发频率和其它拟序结构出现频率的重要手段. 流动显示对湍流边界层拟序结构作了大量定性观察, 有许多减阻和增加传热率等应用性研究在此基础上发展起来. 80年代后, 出现了测量湍流边界层的瞬时流速矢量场的多热线法和PIV技术, 三维PIV技术可望将来为湍流边界层的实验研究带来重大进展. 本文评述了流动显示法、多热线法和PIV技术的优点和不足之处, 以及它们在对湍流边界层拟序结构的研究中的贡献.      

解吸电喷雾电离技术

本文介绍了一种新近发展起来的质谱离子化方法——解吸电喷雾电离（desorption electrospray ionization, DESI）及其最新研究进展。该方法首次于2004年提出后,由于其具有样品无需前处理就可以在常压条件下从各种载物表面直接分析固相,或凝固相样品等优势而得到了迅速的发展。本文描述了DESI的基本原理、离子源的结构和相关优化的参数,并对该离子化方法中所用的载物表面进行了总结。在实际应用方面,本文综述了DESI技术在常压气相化学反应产物监测,合成高聚物表征,爆炸物和化学战毒剂检测,以及在药品,生物代谢产物和生物组织表面分析方面的应用成果,同时对DESI的基础应用研究方向进行了分析和展望。     

载体焙烧温度对Co-Mo/MgO-Al2O3变换催化剂性能的影响

通过X射线衍射、N2吸附-脱附、程序升温脱附、程序升温还原和电子顺磁共振方法研究了焙烧温度对MgO-Al2O3载体物化结构和Co-Mo/MgO-Al2O3变换催化剂性能的影响.结果表明,在600～800 ℃范围内焙烧的复合氧化物以MgAl2O4-xMgO-yAl2O3无定形形式存在,载体表面存在较多的中强酸.碱位,相应的负载催化剂具有较高的水煤气变换活性.在氧化态催化剂中存在较多八面体结构的Mo物种,而硫化态催化剂中含有较多氧硫包围的Mo物种.这些钼物种与催化剂的活性紧密相关.     

十聚钨酸季铵盐的合成

利用离子液体首次合成两种十聚钨酸季铵盐{[Bmim]_4W_(10)O_(32)(Bmin=N-甲基-N'-正丁基咪唑)和[Bu~nPy]_4W_(10)O_(32)},其结构经TG,~1H NMR,~(13)C NMR,IR和元素分析表征.     

High photoluminescence efficiency in polymer containing rare earth

Three novel kinds of polymers containing rare earth europium have been synthesized and the integrating sphere technique was employed to measure the absolute photoluminescence (PL) efficiency. The PL efficiencies were found to be up to about 40%, which indicates the potential usage in organic light emitting devices (OLED). The energy transfer from ligand to Eu ions and the 5D0 → 7F2 transition of Eu3+ were analyzed under the PL process.     

Effect of preparation of titania sol on the structure and properties of acrylic resin/titania hybrid materials

Acrylic resin/titania organic–inorganic hybrid materials were prepared by mixing titania sol produced by the sol–gel process with synthesized thermoplastic acrylic resins. The effects of the amounts of water and acid on hydrolysis and condensation of the sol–gel precursor (titanium n‐butoxide) were characterized by nuclear magnetic resonance, and their corresponding influences on the structure and properties of the hybrid films were investigated by small‐angle X‐ray scattering (SAXS), atomic force microscopy, dynamical mechanical analysis, an Instron testing machine, and ultraviolet–visible spectroscopy. SAXS indicated an open structure and nanoscale size for the titania phase of the hybrids. Higher titania content and a greater amount of water or acid in the sol–gel process resulted in titania domains that were larger size and had a more compact structure. The mechanical and UV‐shielding properties of the organic polymer obviously were improved with titania embedded. As the amount of water or acid in the sol–gel process increased, integrative mechanical properties decreased, with the amount of water having a greater impact than the amount of acid on the structure and optical properties. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3682–3694, 2004     

Influence of GaAsP Insertion Layers on Performance of InGaAsP/InGaP/A1GaAs Quantum-Well Laser

We report on the use of very thin GaAsP insertion layers to improve the performance of an In GaAsP/InGaP/AIGaAs single quantum-well laser structure grown by metal organic chemical vapour deposition. Compared to the noninsertion structure, the full width at half maximum of photoluminescence spectrum of the insertion structure measured at room temperature is decreased from 47 to 38 nm indicating sharper interfaces. X-ray diffraction shows that the GaAsP insertion layers between AIGaAs and InGaP compensates for the compressive strain to improve the total interface. The laser performance of the insertion structure is significantly improved as compared with the counterpart without the insertion layers. The threshold current is decreased from 560 to 450 mA while the slope efficiency is increased from 0.61 to 0.7W/A and the output power is increased from 370 to 940mW. The slope efficiency improved is very high for the devices without coated facets. The improved laser performance is attributed to the suppression of indium carry-over due to the use of the GaAsP insertion layers.     

共振情况下m点p-Laplacian算子边值问题解的存在性

本文研究了在共振情况下m点P-Laplacian算子边值问题解的存在性问题.在非线性项f(t,u,v)有界的条件下,根据Mawhin的连续定理和m点P-Laplacian算子的边值问题的上下解理论,得出共振问题解的存在的结论.     

实用化MgB2超导材料研究进展

本文综述了实用化MgB2超导材料的最新研究进展.最新的理论和实验结果表明通过元素替代和掺杂,有希望进一步提高MgB2超导线带材的临界电流密度和磁通钉扎特性,完全可以达到实用化要求.目前MgB2超导磁体的制备技术研究已经开始,极有可能开发出采用闭路循环制冷机制冷的核磁共振成像仪(MRI)取代现在医学上使用的基于低温超导的核磁共振成像系统.     

偶数维Damek-Ricci空间的曲率

选取最低偶数维的非Riemann对称的Damek—Ricci空间，即秩为5的部分八元数Heisenberg群的一维可解扩张，构造出一种14维Damek—Ricci空间，它的截面曲率的上界可以达到0．