STUDY ON THE SYNTHESIS AND PROPERTIES OF MACRORETICULAR IPN POLYACRYLAMIDE—POLY(VINYL—ETHYLENEDIAMINE)CHELATE SORBENTS

A new series of MR-IPN polyacrylamide—poly(vinyl-ethylenediamine)chelatesorbents were prepared by the reaction of ethylenediamine with MR-IPN matrixes.The newchelate sorbent showed good sorption properties for auric and platinic ions.     

三芳基膦配体的合成研究

从间溴苯酚出发, 利用新的合成方法经五步反应合成了一系列具有不同烷氧基的芳基膦配体. 改进后的方法可方便地通用于在苯环上具有各种不同基团基的膦配体衍生物的合成, 且有原料易得、操作简单、产率较高的优点.     

Fluoride and lead adsorption on carbon nanotubes

The properties and applications of CNT have been studied extensively since Iijima discovered them in 1991[1,2]. They have exceptional mechanical properties and unique electrical property, highly chemical stability and large specific surface area. Thus far, they have widely potential applications in many fields. They can be used as reinforcing materials in composites[3], field emissions[4], hydrogen storage[5], nanoelectronic components[6], catalyst supports[7], adsorption material and so on.…     

Uniform Rice-like CdS Particles Prepared from Water-in-oil Microemulsions

IntroductionNano-sized semiconductors are of great interestdue to their special optical and electronic proper-ties[1,2].As one of the mostimportantⅡ—Ⅵsemicon-ductors,CdS has importantapplications in many fields,such as the solar cell field,non linear o…     

Chemical Constituents and Antibacterial and Antifungal Activities of Two Aglaia Species

In the course of searching bioactive natural products from the plant genus Aglaia, we selected two species, A. cordata and A. testicularis, for further chemical study. Totally twenty natural compounds were obtained and structurally elucidated with which eleven of them were discovered for the first time. Among these compounds, lignans, rocaglamides,aglains and bisamides were the main constituents of the two plant species. The results from a bioactive screening indicated that some of the lignans possess potent antibacterial and antifungal activity.     

Ni的掺入对复合氧化物LaFeO3的结构及性质的影响

合成子Ｎｉ替代铁酸稀土复合氧化物ＬａＦ３１－ｘＮｉｘＯ３（ｘ＝０．１－０．６），对样品进行了ＸＲＤ、ＩＲ及Ｍｏｓｓｂａｕｅｒ谱测试，结果表明：ｘ＝０＼１，０＼２，０＼３的样品为正交相，ｘ＝０．５，０．６的样品为菱方相；伴随相结构从正交向菱方结构的转变，ＩＲ谱上Ｆｅ（Ｎｉ）－Ｏ键伸振动谱带向高频移动近２０ｃｍ＾－１，Ｍｏｓｓｂａｕｅｒ谱测试表明Ｆｅ均处于＋３自旋态，Ｎｉ离子以＋３价进入晶格。     

Relationship between Structure and SHG Effect of Substituted Thienyl Chalcone

1INTRODUCTIONRecentlyorganicnonlinearoptical(NLO)materialsarebeingdevelopedforfre-quencyconversionoflaserinopto-electrics-Especiallybluelightisrequiredforopti-calmemoryofhighdensityrecording.Becauseadiodelaserisusedasalightsource,thenonlinearmaterialswhichhaveextremelyhighvalueofNLOcoefficientsandthetransmissionofblueregionarenecessary.Sincethesecond-orderNLOpropertyoforganiccompoundisderivedfromconjugateddelocalizedrrelectrons,thecompoundswhichhavebeenreportedhavefocusedonthenitroanil…     

An Efficient Method for the Synthesis of Acyl-diazenes Using NaNO_2/NaHSO_4·H_2O

Azo compounds are widely utilized as analytic reagents and dyes1, they can also be used in material of non-linear optics, material of optics information storing in laser disks, and dyes with oil solubility in photochromy in modern technology2. Recently, many noteworthy studies have shown that some azo compounds possess excellent optical memory and photoelectric properties3,4. For example, polymer scaffolds bearing azobenzene-potential are useful for optical information storage, azo-dye doped…     

Molecular Recognition of Bridged Bis(β-cyclodextrin)s Linked by Phenylenediseleno Tether on the Primary or Secondary Side with Fluorescent Dyes

A Novel β-cyclodextrin dimer,2,2′-o-phenylenediseleno-bridgedbis(β-cyclodextrin)(2),has been synthesized by reaction ofmono-[2-O-(p-tolylsulfonyl)]-β-cyclodextrin and poly(o-phenylenediselenide).The complexation stability constants(K_s)and Gibbs free energy changes(-ΔG°)of dimer 2 with fourfluorescence dyes,that is,ammonium 8-anilino-1-naphthalene-sulfonate(ANS),sodium 6-(p-toluidino)-2-naphthalenesul-fonate(TNS),Acridine Red(AR)and Rhodamine B(RhB)have been determined in aqueous phosphate buffer solution(pH=7.2,0.1 mol·L~(-1)at 25℃ by means of fluorescence spec-     

Sc(OTf)3-catalyzed efficient synthesis of beta,beta-bis(indolyl) ketones by the double indolylation of acetic acid 2-methylene-3-oxobutyl ester

In the presence of 5 mol% Sc(OTf)3, double indolylation of acetic acid 2-methylene-3-oxo-butyl ester with differently substituted indoles readily afforded beta,beta-bis(indolyl) ketones. The reaction may proceed via a Sc(OTf)3-catalyzed SN2'-type substitution and subsequent conjugate addition.