硼酸对亚微米级Ca3Sc2Si3O12:Ce绿色荧光粉的制备及发光性能的影响

采用凝胶-燃烧法合成了Ca₃Sc₂Si₃O₁₂ ∶Ce绿色LED用荧光粉,用X射线粉末衍射(XRD)、扫描电镜(SEM)、荧光光谱仪等对合成产物进行了分析和表征.结果表明:通过添加H₃BO₃做助熔剂,制得的荧光粉晶相纯正,颗粒形貌均呈现为较规则的类球形,而且所得荧光粉的粒径均小于1 μm.发射光谱呈现为一宽带,发射主峰位于505 nm,该宽峰对应于Ce³⁺关键词： 白光LED 荧光粉 3Sc₂Si₃O₁₂ ∶Ce')" href="#">Ca₃Sc₂Si₃O₁₂ ∶Ce 发光     

基于微结构参数建模的多孔硅绝热层热导率研究

多孔硅由于具有较低的热导率,因而可以将其作为半导体器件中的绝热层.与其他从边界散射等复杂微观热传导机制出发建模研究多孔硅的热导率不同,将多孔硅热导率影响机制更表观地归结到孔洞的存在和分布等结构因素上,把整个多孔硅视为由硅连续材料介质和孔洞连续介质通过串联和并联组合成的复合微结构,给予其低热导率一个更为易于理解和简化的解释.进一步把孔隙率对等效热导率的影响分解为两个不同的部分,即纵向部分和横向部分,半定量地给出不同的孔洞结构和分布下孔隙率与等效热导率的关系.与实验数据进行对比后验证了模型的有效性.继而从结构的角度说明了多孔硅热导率较低的原因.     

Hollow Gaussian beams in strongly nonlocal nonlinear media

The propagation of hollow Gaussian beams in strongly nonlocal nonlinear media is studied in detail.Two analytical expressions are derived.For hollow Gaussian beams,the intensity distribution always evolves periodically.However the second-order moment beam width can keep invariant during propagation if the input power is equal to the critical power.The interaction of two hollow Gaussian beams and the vortical hollow Gaussian beams are also discussed.The vortical hollow Gaussian beams with an appropriate topological charge can keep their shapes invariant during propagation.     

Investigation of fast pitch angle scattering of runaway electrons in the EAST tokamak

This paper reports that an experimental investigation of fast pitch angle scattering(FPAS) of runaway electrons in the EAST tokamak has been performed.From the newly developed infrared detector(HgCdTe) diagnostic system,the infrared synchrotron radiation emitted by relativistic electrons can be obtained as a function of time.The FPAS is analysed by means of the infrared detector diagnostic system and the other correlative diagnostic systems(including electron-cyclotron emission,hard x-ray,neutrons).It is found that the intensity of infrared synchrotron radiation and the electron-cyclotron emission signal increase rapidly at the time of FPAS because of the fast increase of pitch angle and the perpendicular velocity of the energetic runaway electrons.The Parail and Pogutse instability is a possible mechanism for the FPAS.     

Luminescence of Ce3+ in lanthanum silicon oxynitride

The luminescence properties of lanthanum silicon oxynitride(La-Si-O-N) series doped by trivalent Ce ions have been investigated to seek for tunable wavelength-conversion phosphor for white light emitting diode applications.Four compound hosts of LaSiO2N,La4Si2O7N2,La5Si3O12 N,and La2Si6O3N8 were synthesized and examined in this work.Crystallographic examination for the equal amount of Ce 3+ substitution indicated that the covalency degree decreased in a sequence LaSiO2 N > La2Si6O3N8 > La4Si2O7N2 > La5Si3O12 N,not simply in correlation to the ratio of N3/O2.Excitation and emission spectrum measurements showed the main features of Ce3+ luminescence in the series:the centre of gravity of 5d bands depends on crystal-field splitting more strongly than that on covalency of Ce-N bonding;nephelauxetic effect could not be observed clearly for the investigated series;to some extent Stokes shift was dominated by crystal-field splitting rather than Ce-N covalency degree.     

Spectral properties and energy transfer of Yb,Er:GdVO4 crystal

GdVO₄ single crystal co-doped with Yb³⁺ and Er³⁺ was grown by the Czochralski method. The X-ray powder diffraction pattern of Yb,Er:GdVO₄ crystal confirms that the as-grown crystal is isostructural with pure GdVO₄ crystal. Its polarized absorption spectra and non-polarized fluorescence spectra were measured at room temperature. The absorption band at 984 nm for π-polarization has an FWHM of about 36 nm, which is favorable for InGaAs LD laser pumping. The spectrum properties of Er³⁺ in Yb,Er:GdVO₄ crystal were investigated based on Judd–Ofelt theory. There is strong energy transfer from Yb³⁺ to Er³⁺ in this crystal. When excited with 980 nm radiation, this crystal emitted strong fluorescence at about 1529 nm and 552.5 nm. The total energy transfer rate and efficiency from Yb³⁺ to Er³⁺ is 3.33 ms^-1 and 67%, respectively. The energy transfer between Er³⁺ and Yb³⁺ ions is a multistep transfer process, and was investigated based on a random-walk model. The investigation result shows that there is strong cooperative-sensitization effect from Yb³⁺ to Er³⁺, which is the main upconversion energy-transfer process in this crystal. PACS 42.70.Hj; 81.10.Fq; 42.55.Rz     

Synthesis and magnetic properties of multilayer Ni/Cu and NiFe/Cu nanowires

Highly ordered composite nanowires with multilayer Ni/Cu and NiFe/Cu have been fabricated by pulsed electrodeposition into nanoporous alumina membrane. The diameter of wires can be easily varied by pore size of alumina, ranging from 30 to 100 nm. The applied potential and the duration of each potential square pulse determine the thickness of the metal layers. The nanowires have been characterized by transmission electron microscopy (TEM), magnetic force microscopy (MFM), and vibrating sample magnetometer (VSM) measurements. The MFM images indicate that every ferromagnetic layer separated by Cu layer was present as single isolated domain-like magnet. This technique has potential use in the measurement and application of magnetic nanodevices.     

Gamma rays from dark matter annihilation in the Draco and observability at ARGO

The CACTUS experiment recently observed a gamma ray excess above 50 GeV from the direction of the Draco dwarf spheroidal galaxy. Considering that Draco is dark matter dominated, the gamma rays may be generated through dark matter annihilation in the Draco halo. In the framework of the minimal supersymmetric extension of the standard model we explore the parameter space to account for the gamma ray signals at CACTUS. We find that the neutralino mass is constrained to be approximately in the range between 100 GeV∼400 GeV and a sharp central cuspy of the dark halo profile in Draco is necessary to explain the CACTUS results. We then discuss further constraints on the supersymmetric parameter space by observations at the ground-based ARGO detector. It is found that the parameter space can be strongly constrained by ARGO if no excess from Draco is observed above 100 GeV.     

Two-pump fiber optical parametric amplifiers using optimized photonic crystal fiber by genetic algorithm

In this paper, we investigate the gain spectra of fiber optical parametric amplifiers (FOPAs) consisting of dispersion-flattened fibers (DFFs) with different dispersion curves comparatively by means of the dispersion curve model of the DFFs. It is demonstrated that the broader gain spectrum of FOPAs can be achieved if the dispersion curve is lower and more flattened. Based on the preceding analyses, we propose to constitute FOPAs by using index-guiding photonic crystal fiber (PCF) with an anticipated ultra-flattened dispersion and ultra-low dispersion slope. The as-proposed PCF had different air-holes in the cladding rings. In total, four parameters of the PCF are optimized by using genetic algorithm. PACS 42.81.-i; 42.65.Hw; 42.65.Yj     

热加工对花生过敏原Ara h 2抗原性及构象的影响

从花生种子中分离纯化花生过敏原Ara h 2,采用酶联免疫吸附试验(ELISA)、圆二色谱(CD)、ANS荧光探针及紫外可见(UV-Vis)光谱等方法,系统研究热加工对Ara h 2抗原性和结构的影响.结果表明:Ara h 2蛋白经55或70℃处理后其抗原性略有升高,经85,100或115℃处理后,其抗原性显著降低,且随着温度和时间的增加其抗原性均不断降低.CD色谱分析表明,Ara h 2经热处理后其二级结构发生变化;ANS荧光探针光谱显示,不同的热处理均导致Ara h 2表面疏水性增加.紫外光谱显示,不同温度对Ara h 2处理30 min后(除55℃外),其紫外吸收值均升高.Ara h 2经100℃处理不同时间后,其紫外吸收值均有增加.由此推断,花生过敏原Ara h 2的构象改变导致了其抗原性的降低.