嵌段共聚物/均聚物共混体系的结晶行为 I. 非球状共聚物胶束的作用

将Leibler, Whitmore和Mayes等近期关于非晶嵌段共聚物“稀固体溶液”的理论应用于嵌段聚共聚物结晶型“稀固体溶液”结晶行为的研究。发现球状共聚物胶束既可起成核剂作用, 也可起抑制成核作用。报导了当共聚物胶束由球形变为非球形时, 共聚物胶束的上述作用都会发生较大的变化, 并根据Leibler和Mayes分别提出的球形和非球形胶束理论解释了这一实验现象。     

太赫兹GaAs肖特基混频二极管高频特性分析

在太赫兹波段,存在几种新的高频效应会限制混频二极管的高频特性.应用热电子发射理论和隧道理论,研究了外延层肖特基二极管的高频特性,并以截止频率为品质因数对二极管进行优化设计.研究表明,当二极管工作频率大于等离子频率时,二极管相当于一个电容,失去了混频性能;提高基底掺杂浓度可以减小基底等离子共振效应;外延层等离子频率非常重要并且在研究外延层等离子共振效应时必须考虑传输时间效应;减小阳极直径、减小外延层厚度、提高外延层掺杂浓度可以提高二极管的工作频率.这对太赫兹波段室温混频器件的研制具有重要的参考价值.     

Structural and electronic properties of type-I and type-VIII Ba8Ga16Sn30 clathrates under compression

The total energy and electronic structures for type-I (β phase) and type-VIII (α phase) Ba₈Ga₁₆Sn₃₀ clathrates under hydrostatic pressure have been investigated using density functional theory (DFT) calculations. It was found that the type-VIII phase is more stable than the type-I one at ambient conditions and that β→α phase transition can not occur under hydrostatic pressure. The band structures show that the type-I and type-VIII Ba₈Ga₁₆Sn₃₀ are indirect semiconductors with band gaps of 0.24 eV and 0.19 eV, respectively. The results suggested that type-I clathrate Ba₈Ga₁₆Sn₃₀ has a larger value of the thermoelectric (TE) power than that of type-VIII clathrate. We found that pressure tuning changes the k-point of conduction band minimum (CBM) in the Brillouin zone for β-phase, but it is not the case for α-phase. Furthermore, the results show that the pressure can change the interaction between guest atoms and the host lattice, and consequently results in the decrease of the band gap of β-phase and the increase of the band gap of α-phase, indicating that the pressure effect can play an important role in the magnitude of the TE power.     

CPA方程计算醇+卤代烃体系气液相平衡

醇+卤代烃混合体系,尤其是乙醇、三氟乙醇(TFE)等与卤代烃的混合工质在吸收式制冷、热泵、蒸气动力循环等领域中有着重要的应用.CPA方程可以描述缔合流体的性质,用于含醇类组元的混合体系气液相平衡性质描述.本文首先从纯物质饱和性质实验数据回归得到了CPA方程参数;将CPA方程应用于醇+卤代烃混合体系的气液相平衡计算,采用并比较了2种缔合方案;比较了CPA方程与G~E-EoS模型的相平衡计算效果.CPA状态方程在揭示分子间相互作用的基础上可准确描述醇+卤代烃混合体系的气液相平衡性质.     

矿化剂对铝酸钙粉的结构与光谱性能的影响

研究了矿化剂对制备铝酸钙粉的结构与性能的影响.研究中以铝矾土和石灰石为原料,加入一定量的矿化剂,混合均匀,经高温煅烧制得铝酸钙粉.借助于红外光谱、X射线粉末衍射、差热-热重分析等手段对不同原料的铝酸钙粉的结构、组成及性能进行了表征和研究,并对矿化剂在合成铝酸钙中的矿化机理进行探讨.研究表明:加入矿化剂后,可在更低温度条件下煅烧制备出铝酸钙粉,有利于节能减排.红外光谱分析、XRD分析、DTA-TG分析显示:未加矿化剂煅烧时,生成的产物主要是Ca3Al10O18,CaAl2Si2O8.加入矿化剂后煅烧生成的产物主要是易浸出Al2O3的CaAl3BO7和Ca3Al10O18,而不易浸出Al2O3的CaAl2Si2O8的含量大大降低.同时显示,加入矿化剂后,原料中的方解石(CaCO3)分解更容易;CaCO3与铝矾土反应更充分;更有利于促使铝矾土中的Al-Si键断裂,将铝矾土中的Al释放出来;并可降低铝酸钙的煅烧温度.研究还显示:加入矿化剂后,可以改变原产物的晶体结构与成分,有利于降低煅烧反应温度.     

Damage and fracture prediction of plastic-bonded explosive by digital image correlation processing

By digital correlation processing of Scanning electronic microscopy (SEM) images, the paper presents the deformation and damage analysis of an energetic material—the plastic-bonded explosive (PBX) on mesoscopic scale. The analysis is made by observing the deformation field resulted from the digital image correlation (DIC) processing of the images corresponding to the loading steps and comparing with the surface profiles of the composite material so as to visualize the matter damage near a preset crack. The results show that the local deformation disturbance can reveal the material damage even happened underneath the specimen surface. The strain distribution in the front of the preset crack, can be used to predict the propagating route of the microcrack initiated from the tip of the pre-crack, which is related to the splitting fracture of the granular-based composite under compressive loading.     

Perturbation to Mei Symmetry and Adiabatic Invariants for Nonholonomic Systems in Terms of Quasi-Coordinates

Based on the concept of adiabatic invariant, the perturbation to Meisymmetry and adiabatic invariants for nonholonomic mechanical systems interms of quasi-coordinates are studied. The definition of the perturbationto Mei symmetry for the system is presented, and the criterion of theperturbation to Mei symmetry is given. Meanwhile, the Mei adiabaticinvariants for the perturbed system are obtained.     

Measuring the performance of the coaxial HOM coupler on a 2-cell TESLA-shape copper cavity

Coaxial High Order Mode (HOM) couplers have been fabricated at Peking University and their RF performance has been measured on a test device consisting of a coaxial transmission line and a 2-cellTESLA-shape copper cavity. The test results on the 2-cell TESLA-shape copper cavity with HOM couplers indicate that the coupler can cut off the fundamental mode TM010 and absorb HOMs effectively after a careful adjustment. The optimal angle of the HOM coupler with the beam tube is found. The initial test results of HOM couplers are presented in this paper.     

偏瘫患者辅助下肢外骨骼设计与仿真分析

针对偏瘫患者外骨骼康复机器人降低外骨骼质量的要求,设计了一种辅助下肢外骨骼机器人,采用柔索驱动的膝关节,具有结构简单,质量轻的特点。同时利用ADAMS建立了外骨骼关节柔索驱动的动力学模型,绳索模块建立了柔索驱动模型,通过Ariel生物运动分析软件,采集髋、膝、踝关节运动数据,运用Spline函数进行了仿真分析。经过仿真分析柔索驱动在上台阶运动过程中的不同拉簧预紧力和拉簧刚度下传动特性和驱动力矩,为进一步研究设计下肢外骨骼提供依据。