三光气与酚制备三氯甲氧基甲酸芳酯研究

研究了不同取代酚与三光气的反应,得到七种未见报道的新化合物,以IR、MS、1H NMR、13C NMR对产物进行了表征,并探索得到合适的反应催化剂、反应物浓度配比、反应时间,讨论了酚上不同取代基对反应的影响,收率在78.5～90.5%之间。     

Effects of the laser surface treatment on the mechanical properties of CuZr-based bulk metallic glasses

Surfaces of three types of CuZr-based bulk metallic glasses (BMGs) were modified by laser surface treatment (LST), and the influence of the treatment on structure and mechanical properties of these alloys was investigated. The phase structure of as-cast and laser-treated samples was characterized by XRD and the morphology of the alloys after fracture was examined by SEM. The compressive plasticity of treated Cu47.5Zr47.5Al5 and Cu46.5Zr47.5Al5Co1 BMGs can be improved from 0.5% to 2.0% and from 1.2% to 5.7% respectively compared with the as-cast ones, while (Cu0.55Zr0.40Al0.05)99Er1 BMG shows insignificant change of plasticity. The improvement in plasticity is attributed to induced crystallization of B2 CuZr phase in the treated surface zone of selected metallic glasses.     

Optical bistability based on surface plasmon coupled between two noble metal films involving Kerr materials

We successfully investigate an optical bistability phenomenon in a layered structure consisting of Kretschmann configuration involving the Kerr-type nonlinear and the silver film. Pure theoretical approaches are employed to investigate that the surface plasmon could easily be coupled and both the reflection and transmission curves versus the incident intensity forms optical bistability. The transmission curves are greatly influenced by the thickness of the second silver film. These results may be useful for designing novel surface plasmon-based optical devices and will be essential for future classical and quantum information processes.     

Legendre函数加权的声纳宽频带恒定束宽波束特性分析*

为了处理水声信号,声纳阵列通常需要形成宽频带恒定束宽的波束。采用两种阵元加权方法分析二维圆弧形恒定束宽换能器声纳阵列:球面Legendre函数加权方法和柱面Legendre函数加权方法。分别对球面阵、柱面阵和平面阵这三种几何结构的声纳阵列进行分析,并且计算波束宽度和波束方向。结果表明,在宽频带范围内,除了柱面Legendre函数加权的球面阵之外,其余Legendre函数加权的声纳阵列均能利用简单的、不随频率变化的阵元权重和阵元延时,形成恒定束宽的波束,并且具有较小的旁瓣,此外波束方向与预设方向也较为一致。相对于其他恒定束宽波束形成方法,Legendre函数加权方法能利用较低的计算复杂度来实现良好的宽频带恒定束宽的波束特性。     

中德化学启蒙教材有机内容比较

就化学启蒙教育阶段有机化学教学内容,将德国的《今日化学SⅠ》、国内的沪教版、人教版、鲁教版4套教材,从知识内容的选取、组织呈现等角度进行了比较,并在实验设计、作业设计、拓展学习3方面向教材编写和教学实践提出了建议。     

A STUDY ON REAL-TIME LOW-FREQUENCY SPATIAL FILTERING PROCESS OF AN OPTICAL IMAGE USING LiNbO3:Fe CRYSTAL

The optimum image processing result of low-frequency filtering was obtained when LiNbO₃:Fe crystal as a spatial filter was placed at a certain position behind the spatial-frequency spectral plane of an optical Fourier transform system, which corresponds to the minimum transmittance ratio in Z-scan curve. The experimental results show that self-defocusing due to photorefractive negative-lens effect is the main factor responsible for the low- frequency filtering.     

SYSTEMATIC STUDY OF POLARIZATION OF TWO-PHOTON ABSORPTION IN SYMMETRY ASSIGNMENTS

In this paper, we have systematically analyzed the degenerate and nondegenerate two-photon polarization ratios of various point groups. We present the maximum of symmetry assignments of two-photon transition with the combination of degenerate and nondegenerate two-photon absorption. These results provide the theoretical basis for the experimental assignments.     

Pr3+在SBN晶体中的发光特性

通过测量Ｐｒ：ＳＢＮ晶体的吸收光谱和荧光光谱来确定Ｐｒ³⁺在ＳＢＮ晶体中的能级位置。由于Ｐｒ³⁺离子占据晶体中的不同格位而引起荧光带呈现双峰结构。测量荧光寿命随温度的变化关系，表明Ｐｒ³⁺在ＳＢＮ晶体中 ³Ｐ₀态的无辐射弛豫主要是 ³Ｐ₀→¹Ｄ₂多声子弛豫过程。 关键词：     

KTiOPO4晶体纵横模劈裂的喇曼谱

在室温下测量了ＫＴｉＯＰＯ₄单晶的偏振喇曼散射谱，应用９０°散射及背散射得到了各模的峰位值，其中Ｂ₁（ＬＯ）模、Ｂ₂（ＬＯ）模的喇曼谱测量尚未见报道过。根据ＬＯ－ＴＯ劈裂的实验结果，计算出该晶体极化模的有效电荷、振子强度及沿对称轴方向的静态介电常数。 关键词：     

Traveling－Wave Electrooptical Modulator on Polymeric Film with Reversal Poling Structure

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