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使用硫杂冠醚、穴醚[2.2.2]作气相色谱固定相制备毛细管柱,考察两种固定相的使用比例、极性、热稳定性,并对甲苯-苯、乙苯-甲苯、甲基苯酚(o/p)、二氯苯(o/p,m)、硝基氯化苯(m,o)、苯-环己烷、庚醇-辛醇、苯胺-N,N二甲基苯胺等混合样品进行色谱分离.实验结果表明:两种固定相在OV-1701中的比例均为15%时有较好的分离效果,都属于中等极性的固定相.硫杂冠醚、穴醚[2.2.2]的平均极性分别为815、832,其中硫杂冠醚固定相的热稳定性较好,有较高的使用温度(185℃),而穴醚[2.2.2]的最高使用温度为120℃,因此穴醚[2.2.2]的使用温度受到一定的限制.从它们较好的分离性能看,固定相硫杂冠醚、穴醚[2.2.2]均具有较好的应用前景. 相似文献
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Crosslinking is one of the effective routes for improving the orientation stability of poledpolymer films. The derivative of polyvinyl alcohol containing 4-nitro-4'-alkoxystilbene andphoto-crosslinkable cinnamyl groups as side chains has been synthesized. The in-situ simul-taneous photo-crosslinking poling of synthesized polymer films has been performed. Thesecond order nonlinear optical coefficient d_(33) of poled film is 11 pm/V. The SHG mea-surements show that the break-over temperature of SHG signal is raised obviously afterirradiation, its orientation stability is doubled as compared with that of non-crosslinkingsamples. 相似文献
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We develop an anisotropic perfectly matched layer (PML) method for solving the time harmonic electromagnetic scattering problems in which the PML coordinate stretching is performed only in one direction outside a cuboid domain. The PML parameters such as the thickness of the layer and the absorbing medium property are determined through sharp a posteriori error estimates. Combined with the adaptive finite element method, the proposed adaptive anisotropic PML method provides a complete numerical strategy to solve the scattering problem in the framework of FEM which produces automatically a coarse mesh size away from the fixed domain and thus makes the total computational costs insensitive to the choice of the thickness of the PML layer. Numerical experiments are included to illustrate the competitive behavior of the proposed adaptive method. 相似文献
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In this paper we propose and study a generalized time dependent Ginzburg-Landau model for superconductivity in which the temperature appears as a variable rather than a parameter. The model is derived by using the general theory of thermodynamics for non-isothermal phase transitions developed by Penrose-Fife and Alt-Pawlow. The global existence of classical solutions of the model is established by using Leray-Schauder fixed point theorem 相似文献
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高中化学教科书是发展学生化学学科核心素养的重要载体和资源平台。依据《普通高中化学课程标准(2017年版)》编写的人教版普通高中化学必修教科书作为分析文本,着重从栏目系统、图像系统、习题系统角度对其呈现方式进行分析,具体特点表现为:栏目系统强化功能性,图像系统凸显直观性,习题系统体现针对性、情境性、开放性,以期为高中化学教师有效使用教科书、落实化学学科核心素养的培养发挥积极作用。 相似文献
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A vertex‐centered linearity‐preserving discretization of diffusion problems on polygonal meshes 下载免费PDF全文
This paper introduces a vertex‐centered linearity‐preserving finite volume scheme for the heterogeneous anisotropic diffusion equations on general polygonal meshes. The unknowns of this scheme are purely the values at the mesh vertices, and no auxiliary unknowns are utilized. The scheme is locally conservative with respect to the dual mesh, captures exactly the linear solutions, leads to a symmetric positive definite matrix, and yields a nine‐point stencil on structured quadrilateral meshes. The coercivity of the scheme is rigorously analyzed on arbitrary mesh size under some weak geometry assumptions. Also, the relation with the finite volume element method is discussed. Finally, some numerical tests show the optimal convergence rates for the discrete solution and flux on various mesh types and for various diffusion tensors. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
39.
Benjamin Klemmed Dr. Lucas V. Besteiro Dr. Albrecht Benad Maximilian Georgi Prof. Zhiming Wang Prof. Alexander Govorov Prof. Alexander Eychmüller 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(4):1713-1719
Solar radiation is a versatile source of energy, convertible to different forms of power. A direct path to exploit it is the generation of heat, for applications including passive building heating, but it can also drive secondary energy-conversion steps. We present a novel concept for a hybrid material which is both strongly photo-absorbing and with superior characteristics for the insulation of heat. The combination of that two properties is rather unique, and make this material an optical superheater. To realize such a material, we are combining plasmonic nanoheaters with alumina aerogel. The aerogel has the double function of providing structural support for plasmonic nanocrystals, which serve as nanoheaters, and reducing the diffusion rate of the heat generated by them, resulting in large local temperature increases under a relatively low radiation intensity. This work includes theoretical discussion on the physical mechanisms impacting the system's balanced thermal equilibrium. 相似文献
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