动力排水固结法加固吹填黏性土的模型试验研究

为了研究动力排水固结法加固吹填土地基的效果,研发了大比例尺的室内模拟试验装置并开展了试验。重点对夯沉量、土体内孔隙水压力的瞬时和长期变化进行了监测和分析,得到如下结论:夯击产生的能量以波的形式向土体内部传播,由于波的作用造成土体拉伸形成裂隙,这些裂隙成为初期的排水通道; 孔隙水压力的动态变化具有明显的脉动特性,夯击瞬间出现负增长,然后再累积增长; 不同深度土体的孔隙水压力增幅不一样; 土体表面铺设的砂垫层不仅可以用做排水,还可以作为静力荷载,有助于土体的排水固结。     

A pair of integrated optoelectronic transceiving chips for optical interconnects

In this Letter, a pair of integrated optoelectronic transceiving chips is proposed. They are constructed by integrating a vertical cavity surface emitting laser unit above a positive-intrinsic-negative photodetector unit. One of the transceiving chips emits light at the wavelength of 848.1 nm with a threshold current of 0.8 mA and a slope efficiency of 0.81 W/A. It receives light between 801 and 814 nm with a quantum efficiency of higher than 70%.On its counterpart, the other one of the transceiving chips emits light at the wavelength of 805.3 nm with a threshold current of 1.1 mA and a slope efficiency of 0.86 W/A. It receives light between 838 and 855 nm with a quantum efficiency of higher than 70%. The proposed pair of integrated optoelectronic transceiving chips can work full-duplex with each other, and they can be applied to single fiber bidirectional optical interconnects.     

一种新的基于PageRank算法的学术论文影响力评价方法

基于PageRank算法的学术论文影响力研究中忽视了两个问题：1）论文影响力随时间变化的现象;2）不同学科间引用的差异。针对这两个问题,通过统计方法,引入时间因子和学科因子,建立了一种新的基于PageRank算法的学术论文影响力评价模型。结果能够有效地刻画论文影响力随时间变化和学科间的引用区别,更加实时、全面、客观地衡量论文的影响力。     

基于差分方程的货运市场占有率模型

合理估计产品的市场占有率是企业做出营销决策时需要考虑的最重要的因素之一。总结国内外部分有关市场占有率的研究献；建立关于铁路、公路货运量在全社会货运中市场占有率的差分方程组模型，运算后得出铁路、公路货运在整个货运市场中的占有率将趋向相对稳定的结论；通过利用历史统计数据计算，验证了该模型的可行性。     

Integrated optoelectronic chip pair for transmitting and receiving optical signals simultaneously

An integrated optoelectronic chip pair, which can transmit and receive optical signals simultaneously, is proposed in this Letter. The design and optimization of its key structure, the vertical cavity surface emitting laser's distributed Bragg reflector, are presented. Analysis is also done for its influence on the integrated chip's performance. Moreover, the chip pair's performance under dynamic conditions is analyzed. Their 3 dB modulation bandwidths are higher than 10 GHz, and their 3 dB photo-response bandwidths are around 23 GHz. Their applications will further improve the performances of the optical interconnects.     

Magnetic interactions in a proposed diluted magnetic semiconductor(Ba_(1-x)K_x)(Zn_(1-y)Mn_y)_2P_2

By using first-principles electronic structure calculations, we have studied the magnetic interactions in a proposed BaZn_2P_2-based diluted magnetic semiconductor(DMS). For a typical compound Ba(Zn_(0.944)Mn_(0.056))_2P_2 with only spin doping, due to the superexchange interaction between Mn atoms and the lack of itinerant carriers, the short-range antiferromagnetic coupling dominates. Partially substituting K atoms for Ba atoms, which introduces itinerant hole carriers into the p orbitals of P atoms so as to link distant Mn moments with the spin-polarized hole carriers via the p–d hybridization between P and Mn atoms, is very crucial for the appearance of ferromagnetism in the compound. Furthermore, applying hydrostatic pressure first enhances and then decreases the ferromagnetic coupling in(Ba0.75 K0.25)(Zn_(0.944)Mn_(0.056))_2P_2 at a turning point around 15 GPa, which results from the combined effects of the pressure-induced variations of electron delocalization and p–d hybridization. Compared with the BaZn_2 As_2-based DMS, the substitution of P for As can modulate the magnetic coupling effectively. Both the results for BaZn_2 P_2-based and BaZn_2As_2-based DMSs demonstrate that the robust antiferromagnetic(AFM) coupling between the nearest Mn–Mn pairs bridged by anions is harmful to improving the performance of these Ⅱ–Ⅱ–Ⅴ based DMS materials.     

聚吡咯电化学制备实验的改进——一个开放式综合实验设计

聚吡咯作为一种具有特异光电性能的π-共轭类导电高分子,其制备实验也逐步走进大学课堂,成为融合化学、物理、材料等多个学科知识的代表性实验。项目组以本校“聚吡咯的电化学制备实验”为基础,将其从一个简单的任务式制备实验,改进成一个集制备条件自主选择以及导电性能表征为一体的综合性开放式实验：首先在三电极体系下进行电化学聚合,并以此为切入点,展开对聚合条件的开放式探索,然后使用循环伏安法对所得聚吡咯薄膜进行电致变色实验,最后测试其电导率并展开讨论和分析。本改进实验内容丰富,有助于学生综合技能的提升和科学思维的培养,更加贴合现代化学学科发展。     

Li0.5Bi0.5MoO4对Li2Zn2(MoO4)3陶瓷的微波介电性能影响

采用传统固相反应法制备了xLi_0.5Bi_0.5MoO₄-(1-x)Li₂Zn₂(MoO₄)₃ [xLBM-(1-x)LZM]复合陶瓷,研究添加不同质量分数(x=25%,30%,35%,40%和45%)的LBM对LZM陶瓷的烧结特性、物相组成、微观结构以及微波介电性能的影响。结果表明:添加一定量的LBM不仅能将LZM的谐振频率温度系数(τ_f)调节近零,还能降低LZM的烧结致密化温度;LBM可与LZM共存,且不发生化学反应生成其他新相。随着LBM添加量增加,复合陶瓷的烧结致密化温度逐渐降低、体积密度先增大后减小、介电常数(ε_r)与τ_f逐渐增大而品质因数(Q×f)逐渐减小。当LBM添加量为40%时,LZM-LBM复合陶瓷在600 ℃烧结2 h获得最大体积密度为4.41 g/cm³,以及优异的微波介电性能:ε_r为13.8,Q×f为28 581 GHz,τ_f为-4×10^-6/℃。     

城市污水处理厂污泥中卤代甲基磺酸的液相色谱-串联质谱分析方法研究

建立了测定城市污水处理厂污泥样品中5种卤代甲基磺酸的高效液相色谱-串联质谱(HPLC-MS/MS)方法。通过对萃取溶剂、提取方式和萃取次数等条件进行优化,确定最佳萃取条件为:萃取溶剂为甲醇-水(体积比1∶1)混合溶液,摇床振荡提取1 h,萃取1次。在该条件下对一氯甲基磺酸(Cl-MSA)、二氯甲基磺酸(Cl_2-MSA)、三氯甲基磺酸(Cl_3-MSA)、一溴甲基磺酸(Br-MSA)和三氟甲基磺酸(F_3-MSA)的萃取效率分别为(48. 4±2. 8)%、(68. 3±0. 9)%、(81. 0±4. 8)%、(38. 0±1. 1)%和(99. 1±1. 2)%。该方法的线性范围为0. 05~50μg·kg~(-1),相关系数(r)大于0. 991,各化合物的检出限(S/N=3)为0. 003~0. 018μg·kg~(-1),定量下限为0. 010~0. 059μg·kg~(-1);对实际样品的加标回收率为73. 8%~101%,相对标准偏差为2. 3%~12. 5%,可满足污泥样品中痕量卤代甲基磺酸的分析需求。