金属钨及其合金中微量氧的分析

探讨了检测系统、坩埚、Ｎｉ囊、熔池空白和不同分析方法对分析金属钨及其合金中微量氧的影响。基于镍囊助熔法和熔池法相结合技术,建立了测定金属钨及其合金中微量氧的新方法,本方法已用于金属钨、钨－铝合金、钽－钨合金等材料中质量分数为＜１．０×１０－４％的氧的测定。     

一种席夫碱Al3+荧光探针的制备及细胞成像应用

以4-（二乙氨基）水杨醛与奥肼缩合制备了一例席夫碱类荧光探针1,通过¹H NMR、¹³C NMR和电喷雾电离质谱表征了1的结构。光谱分析实验结果显示,探针1可选择性与Al³⁺作用,在495 nm处荧光发射峰显著增强。探针对Al³⁺的检测灵敏度高,检测限低至1.44 μmol·L^-1。结合理论计算,证实探针以三齿配位的模式,与Al³⁺形成1∶1型稳定配合物。此外,该探针还可用于活细胞中Al³⁺的检测。     

大功率AlGaInP红光LED散热基板热分析

采用有限体积数值模拟、瞬态热阻测试方法以及热沉温度一峰值波长变化的关系,对三种散热基板上大功率AIGaInP红光发光二极管(LED)进行热特性分析.三种LED采用相同型号、规格,散热基板,区别在于散热通道以及材料.测量样品的瞬态温度响应曲线,基于结构函数理论模型对温度响应曲线进行数学处理,得出包含热阻与热容的结构函数,区分出样品内部热流通道上各个区域的热阻与热容,进而发现散热瓶颈区域.测试样品在不同热沉温度下的电致发光光谱,通过热沉温度一峰值波长系数为区别样品散热性能提供定性判断依据.通过模拟与测试结果比较,为优化陶瓷基板内部散热结构,设计最佳的散热模型提供重要参考依据.     

《探索性数据分析》

原著名：ＵｎｄｅｒｓｔａｎｄｉｎｇＲｏｂｕｓｔａｎｄＥｘｐｌｏｒａｔｏｒｙＤａｔａＡｎａｌｙｓｉｓ译人员：陈忠琏、郭德嫒校译人员：杨振海书评：探索性数据分析是美国当代著名统计学家ＪｏｈｎＷＴｕｋｅｙ在本世纪６０年代开创的一个新的统计研究方向。１９６２年他发表了《ＴｈｅＦｕｔｕｒｅｏｆＤａｔａＡｎａｌｙｓｉｓ》,做了奠基性的工作。在１９７０年他出版了这个新领域的第一本专著《ＥｘｐｌｏｒａｔｏｒｙＤａｔａＡｎａｌｙｓｉｓ》。之后,Ｔｕｋｅｙ与ＦｒｅｄｅｒｉｃｋＭｏｓｔｅｌｌｅｒ和ＤａｖｉｄＣＨｏ…     

诺贝尔物理学奖得主知识交流网络结构研究

将诺贝尔物理学奖得主作为结点，在有知识交流的两位得主间添加一条连接，由此得到诺贝尔物理学奖得主知识交流网络。本文对此网络的结构特征进行研究，结果表明该网络的结构具有一般社会网络共有的Seale-free、度协调、负相关特征，而直径较一般社会网络大，聚集系数则明显较小。     

复杂网络幂律度分布和层次聚集函数标度指数的一种新的估计方法

提出一种估计复杂网络幂律度分布和层次聚集函数标度指数的新方法,并给出求解这些指数的数值算法．该方法可以克服目前网络研究中采用的图形线性拟合估计方法存在的偏差和不准确等不足之处．此外,通过对10个CNN网络进行KS检验统计量的比较,证实该方法比图形方法具有更好的拟合效果．     

First neutron spectrometry measurement at the HL-2A Tokamak

A compact neutron spectrometer based on the liquid scintillator is presented for neutron energy spectrum measurements at the HL-2A Tokamak. The spectrometer was well characterized and a fast digital pulse shape discrimination software was developed using the charge comparison method. A digitizer data acquisition system with a maximum frequency of 1 MHz can work under an environment with a high count rate at HL-2A Tokamak. Specific radiation and magnetic shielding for the spectrometer were designed for the neutron spectrum measurement at the HL-2A Tokamak. For pulse height spectrum analysis, dedicated numerical simulation utilizing NUBEAM combined with GENESIS was performed to obtain the neutron energy spectrum. Subsequently, the transportation process from the plasma to the detector was evaluated with Monte Carlo calculations. The distorted neutron energy spectrum was folded with the response matrix of the liquid scintillation spectrometer, and good consistency was found between the simulated and measured pulse height spectra. This neutron spectrometer based on a digital acquisition system could be well adopted for the investigation of the auxiliary heating behavior and the fast-ion related phenomenon on different tokamak devices.     

Investigation of Kinematics of the Portevin-Le Chatelier Deformation Bands with Dynamic Digital Speckle Pattern Interferometry

The Portevin-Le Chatelier (PLC) effect with typical temporal instabilities in the recorded stress is closely associated with local inhomogeneities of deformation. By employing the dynamic digital speckle pattern interferometry technology, the characterizations for the PLC deformation bands of type A (continuous propagation along the specimen), type B (“hopping“ propagation along the specimen) and type C (random nucleation in the sample) were distinctly clarified. The corresponding positions of deformation bands were traced throughout the whole tensile process. By systemic experiments, the range of the applied strain rates for each type of bands existing was investigated respectively. The evolution of the band velocity (for types A and B) was also statistically investigated and qualitatively interpreted.     

Observation of intermolecular double-quantum coherence signal dips in nuclear magnetic resonance

The correlated spectroscopy revamped by asymmetric Z-gradient echo detection (CRAZED) sequence is modified to investigate intermolecular double-quantum coherence nuclear magnetic resonance signal dips in highly polarized spin systems. It is found that the occurrence of intermolecular double-quantum coherence signal dips is related to sample geometry, field inhomogeneity and dipolar correlation distance. If the field inhomogeneity is refocused, the signal dip occurs at a fixed position whenever the dipolar correlation distance approaches the sample dimension. However, the position is shifted when the field inhomogeneity exists. Experiments and simulations are performed to validate our theoretic analysis. These signal features may offer a unique way to investigate porous structures and may find applications in biomedicine and material science.     

基于FPGA小型化谱仪控制台的设计

针对核磁共振波谱仪中控制台的功能需求,考虑到仪器小型化的趋势,提出了基于FPGA和ARM的小型化控制台设计方案. 该方案具有体积小、处理速度快、控制精准、开发周期短和成本低等特点. 该文着重介绍了FPGA在系统中的功能实现,包括命令字接收、参数配置、脉冲发射和数据采样模块. ARM嵌入式模块实现控制台与上位机的以太网通信,以及和FPGA的高速并行总线通信,使控制台内部运行不受网络状况的干扰. 最后针对该设计方案提出几点改进建议.