Synthesis and Characterization of Ordered Mesoporous Aluminosilicate Molecular Sieves with High Stability in High-Temperature Steam

The ordered mesoporous aluminosilicate molecular sieve （MASMS-1） stable in the high-temperature steam has been successfully synthesized from the assembly of diluted ZSM-5-type precursor with mesoporous MCM-41. The material was characterized by XRD, N2 adsorption-desorption, FE-SEM, TEM, FT-IR spectroscopy and 27A1 MAS NMR techniques. This mesoporous material shows high stability in the high-temperature steam [H2O （φ=20%） in N2 at 800 ℃ for 4 h], which might be ascribed to the synergistic effect of both thick walls containing zeolite-like five-membered ring subunits and highly condensed surface silanol groups.     

低温等离子体与催化耦合脱除NOx的研究进展

大气污染严重威胁着人类的生存.氮氧化物(NOx)是造成大气污染的主要污染源之一.据1994年美国环保局统计,全球人类活动向大气中排放的NOx为3000万吨(millions of metric tons)[1].其中,汽车尾气中的NOx约占全球大气中NOx排放物的60%,另一部分主要来自发电厂和工业锅炉.NOx中NO的毒性比CO对人体的危害还大,其与人体血液中血红蛋白的亲和力是CO的1000多倍.人体吸收少量的NO可以导致呼吸困难、呼吸道感染和哮喘等症状.NOx对环境的危害主要表现在它与烃类反应所造成的光化学烟雾、酸雨、温室效应和臭氧层空洞效应这四大环境问题.随着世界…     

CuO/Sn0.8Ti0.2O2催化剂的表征及对NO+CO反应活性研究

Reducibility and characteristics of CuO/Sn_0.8Ti_0.2O₂ catalysts were examined by using a microreactor-GC NO+CO reaction system, BET, TG-DTA, FTIR, XRD and H2-TPR techniques. CuO/Sn_0.8Ti_0.2O₂ had high activity in NO+CO reaction, showing 93% NO conversion at 300 ℃ in air, and 100% NO conversion at 225 ℃ after H₂ pretreatment. The pore size distribution of Sn_0.8Ti_0.2O₂ was mainly as micro-pores and meso-pores (1~5 nm), and the specific surface area and total pore volume of Sn_0.8Ti_0.2O₂ were 69 m²·g^-1 and 0.15 cm³·g^-1, respectively. As shown by XRD analysis, there was no CuO crystal diffraction peak at 9%CuO loading, but two CuO crystal diffraction peaks at 2θ 35.5° and 38.7° were present at 12% CuO loading. FTIR detected the adsorption of NO and CO on the surface of reduced 12%CuO/Sn_0.8Ti_0.2O₂. The Cu²⁺ sites and support surface adsorbed NO, and the process of NO adsorption led to the formation of N₂O and NO₃^-. In contrast, the Cu⁺、Cu⁰ sites and support surface adsorbed CO, and when the mixed gases of NO and CO were adsorbed by support surface, no NO₃^- was formed. H₂-TPR showed four reduction peaks (α, β, γ and δ). The α, β and γ peaks were the reductions of CuO species, and the δ peak was the reduction of Sn_0.8Ti_0.2O₂.     

介孔MCM-41分子筛载钯配合物催化Heck反应的性能

以MCM 41分子筛作为固载材料 ,经氨基功能化后与各种钯化合物形成MCM 41载钯配合物。采用XRD、XPS等技术对其结构及表面性能进行了表征 ,并研究了催化剂的制备条件等因素对催化Heck芳基化反应性能的影响 ;同时 ,以共轭烯烃和各种芳基碘的Heck芳基化反应考察了MCM NH2 ·Pd(0 ,Ⅱ )配合物的催化性能。结果表明 ,MCM NH2 固载钯配合物具有高的催化活性和立体选择性 ,高得率地生成了一系列取代的反式产物。     

氧化锰八面体分子筛的合成、表征及其催化燃烧性能

通过回流法和固相法合成了隐钾锰矿型氧化锰八面体分子筛OMS-2催化剂,采用XRD、FE-SEM、O2-TPD-MS和H2-TPR等表征技术考察了分子筛催化剂的形态和表面氧的热脱附性能及还原性能,并将其应用于甲苯和甲醛的催化燃烧反应.实验结果表明,合成方法对制备的催化剂的表面性质和催化燃烧性能具有显著影响.回流法制备的催化剂对于甲苯的燃烧具有较高的活性,而固相法合成的催化剂在甲醛的燃烧中具有更好的催化活性.催化燃烧性能取决于催化剂的表面形态和氧物种的种类.回流法制备的样品因具有较大的比表面积和较活泼的α氧物种,有利于甲苯的催化燃烧,而固相法合成的催化剂中质量分数较高的β氧物种对甲醛分子的燃烧更具促进作用.     

不同粒径的Ni/SiO2催化剂上CH4和CO2吸附活化的漫反射傅里叶变换红外光谱研究

 采用原位漫反射傅里叶变换红外光谱研究了CH4和CO2在不同粒径的Ni/SiO2催化剂上的吸附及活化. 结果表明,在不同粒径的催化剂上,检测到有CH4解离生成的CHx(x=1～3)物种,以及催化剂表面吸附的CHx物种与表面-OH 作用生成的CHx-O物种. CH4的裂解强烈依赖于催化剂表面Ni颗粒的大小,在粒径8 nm左右的Ni颗粒上, CH4较易解离; CO2难以直接在Ni/SiO2催化剂表面发生解离吸附,但CH4解离生成的吸附H对CO2的解离吸附具有明显的促进作用; CH4与CO2共吸附时,较小粒径的Ni可以促进CO2与表面氧物种发生反应,生成单齿表面碳酸盐物种.     

载体对负载钴催化剂CH4/CO2重整反应的影响

重整制合成气;载体对负载钴催化剂CH4/CO2重整反应的影响     

甲烷芳构化反应催化剂的研究——Mo-M/HZSM-5在无氧条件下的催化性能和表面性质

苯;甲烷芳构化反应催化剂的研究——Mo-M/HZSM-5在无氧条件下的催化性能和表面性质     

用TPR技术研究脱铝天然丝光沸石催化性能

本文应用程序升温反应(TPR)技术研究了盐酸脱铝天然丝光沸石的催化性能。通常,由于结晶条件的差别,天然丝光沸石的孔径较合成的小得多。我们用盐酸脱铝来增大孔径;从而改进了天然丝光沸石的催化性能,增加了B酸强度,增大的孔径对邻二甲苯异构化有较好的适应性。这样,脱铝天然丝光沸石有可能在其些方面代替合成丝光佛石用于石油化学工业。还用X射线衍射、比表面测定和热重分析等方法考察了催化剂的性能和结构。