4，4′—二偶氮苯重氮氨基偶氮苯与Ag（I）的显色反应及其应用

本文报道了4,4′ -二偶氮苯重氮氨基偶氮苯在Triton X-100存在下与Ag(Ⅰ)的显色反应.在pH10.0的硼砂-氢氧化钠缓冲溶液中,试剂与Ag(Ⅰ)形成1∶1的红色配合物,其最大吸收波长为540nm,表观摩尔吸光系数为7.55×104L*mol-1*cm-1,Ag(Ⅰ)的浓度在0-0.28mg/L范围内符合比耳定律.应用于显影废液和钮扣电池液中Ag的测定,结果令人满意.     

葡萄糖粉末的近红外光谱

糖尿病患者的自我监测是减少由糖尿病引发并发症的重要手段。无创血糖监测的近红外光谱分析方法是最具有应用前景的一种，葡萄糖近红外光谱则是研究无损血糖检测基础。本文通过实验采集了葡萄糖粉末的近红外光谱，并对结果作了详细分析。     

高功率脉冲激光对阶跃折射率多模光纤损伤机理

 理论分析和模拟仿真研究了激光点火系统中光纤端面损伤、光纤初始输入段损伤和光纤内部损伤机理。结果显示：端面损伤主要是由光纤端面的杂质和缺陷引起；光纤初始输入段损伤是由光束的初次反射造成光纤局部激光能量密度增大引起的；光纤内部体损伤主要由于激光自聚焦效应引起损伤和光纤受到的意外应力产生微小碎片，吸收激光能量，引起光纤局部损伤。给出了激光点火系统中提高光纤损伤阈值的一般方法，主要包括光纤端面处理、设计合理的激光注入耦合装置。     

低温热管传热性能的实验研究

热管是一种高效的传热元件,低温热管可望在超导磁体冷却、空间探索方面获得广泛应用.本文对热虹吸管的传热特性进行了实验研究.研究结果表明,在同样加热功率的条件下,与相同形状和尺寸的紫铜导热棒相比,在加热功率较高的条件下,低温热管的传热性能远远优于紫铜棒的传热性能,完全能够满足超导磁体的冷却要求.     

Stationary Fluid Dynamic Behaviour of V-Shaped Diffuser/Nozzle Elements for Valveless Micropump

A novel type of V-shaped （isosceles triangle cross-section） diffuser/nozzle element is proposed for use for valveless micropump. Stationary fluid dynamic behaviour of V-shaped diffuser/nozzle elements in a valveless micropump is investigated by experiment and simulation. Both the results agree well with each other when the Reynolds number is higher than 100 and the pressure loss coefficient ratio of micropump nearly always keeps a constant. For a single V-shaped diffuser, the general trends of variation of pressure loss coefficient with opening angle and Reynolds number are opposite in small and large angles. Compared with conical and flat-wall diffusers, V-shaped diffuser shows the smallest pressure loss when the Reynolds number is 200.     

Nitrogen Dioxide Sensing Properties and Mechanism of Copper Phthalocyanine Film

Copper phthalocyanine film, a p-type organic semiconductor, is synthesized by vacuum sublimation and its surface morphology is characterized by SEM. A silicon-based copper phthalocyanine film gas sensor for NO2 detection is fabricated by MEMS technology. The results show that the resistance and sensitivity of copper phthalocyanine film decrease obviously as the NO2 concentration increases from Oppm to lOOppm. However, the sensitivity nearly keeps a constant of O. 158 between 30 ppm and 70 ppm. The best working temperature of the gas sensor is 90℃ for NO2 gas concentrations of lOppm, 20ppm and 30ppm, which is much lower than that of general metal oxide gas sensor.     

Measurements of AIM for Visible Wavelength Based on Individual Eye Model

We measure and calculate the aerial image modulation （AIM） of human retina for visible wavelengths based on the individual eye model. By employing the optical design software ZEMAX, we obtain the modulation transfer function （MTF） of human eye in visible wavelengths. Using CSV-1000 and VAF-1000, the contrast sensitivity function （CSF） and the visual acuity （VA） for the same eye are measured. Then the AIM of human retina could be acquired by the relations between MTF and CSF and between MTF and VA. The AIM of human retina is independent of MTF, and the values of AIM for normal eyes （without retina disease） are similar, so the assembly average for large numbers of normal eyes can be a standard AIM curve, which is helpful for the diagnosis of diseases in the retina system.     

水体的温度变化对测定溶解有机物浓度的影响

用激光诱导荧光(LIF)方法研究了水体的温度变化对溶解有机物(DOM)发射荧光强度的影响。随着温度的增加,DOM的荧光强度和水的拉曼散射强度不断降低。在20～75 ℃范围之内,对归一化荧光强度与温度关系曲线进行线性拟合,计算出归一化荧光强度随温度升高的变化梯度平均值为-5.24×10-4 ℃-1,根据归一化荧光强度与浓度的关系,给出了所测DOM的浓度随着温度升高的平均下降速率为-3.45×10-3 (mg·L-1)·℃-1。因此,在这一温度范围内测量时,假设归一化荧光强度不变,则温度变化将引起DOM浓度最大为8.45%的相对变化。     

Nd:LuVO_4晶体的拉曼光谱研究

采用不同的几何配置测量了Nd:LuVO4晶体的室温拉曼光谱,根据群论对称性分类计算了该晶体的红外和拉曼活性振动模并与实验结果做了比较,指认了测定的特征谱线。测量并分析了Nd:LuVO4晶体A1g全对称类的高温拉曼光谱,讨论了拉曼频移随温度变化的关系,认为晶体的热膨胀是引起拉曼频移变化的主要原因。