Light scattering of nanocrystalline TiO2 film used in dye-sensitized solar cells

This paper studies the light scattering and adsorption of nanocrystalline TiO2 porous films used in dye-sensitized solar cells composed of anatase and/or rutile particles by using an optical four-flux radiative transfer model. These light properties are difficult to measure directly on the functioning solar cells and they can not be calculated easily from the first-principle computational or quantitative theoretical evaluations. These simulation results indicate that the light scattering of 1 25 nm TiO2 particles is negligible, but it is effective in the range of 80 and 180 nm. A suitable mixture of small particles （10 nm radius）, which are resulted in a large effective surface, and of larger particles （150 nm radius）, which are effective light scatterers, have the potential to enhance solar absorption significantly. The futile crystals have a larger refractive index and thus the light harvest of the mixtures of such larger rutile and relatively small anatase particles is improved in comparison with that of pure anatase films. The light absorption of the 10μm double-layered films is also examined. A maximal light absorption of double-layered film is gotten when the thickness of the first layer of 10 urn-sized anatase particles is comparable to that of the second larger rutile layer.     

高能e~+e~-湮没中多粒子产生的管状袋模型

本文提出了一种研究高能e~+e~-湮没过程中多粒子产生的管状袋模型.利用袋参数β确定强子化几率密度与物质化能量的平方成正比,成功地解释了最新实验数据(TASSO,HRS)给出的近似KNO标度无关性.     

对插型阵列微带电极的制作及其电化学特性研究

用微电子光刻方法制作了对插型阵微带电极（ＩＤＡ），并通过ＳＥＭ对ＩＤＡ电极进行了表征，将微Ａｇ／ＡｇＣｌ参比电极和微铂丝对电极固定在ＩＤＡ电极附近，构成了微电解池，考察了该电极的循环伏安及计时电流特性，并用微带电极的扩散理论和Ｃｏｔｔｒｅｌｌ 公式对ＩＤＡ电极的准稳太电流进行了处理，指出了它们之间产生偏差的原因，研究了ＩＤＡ电极的“发生－收集”效应，测定了该电极的屏蔽因子、反馈因子和收集效率。     

彩色电视屏用光敏磷光体粉浆的研磨条件

美国电化学学会第145次会议文章摘要中,有53篇和发光材料、显示器件有关。我们从中选译了一部份,陆续刊登以供参考。这次刊出的是和彩色电视有关的文章摘要,参考资料目录一律从略。     

On generalized hamiltonian systems

1. PreliminaryIt is well known that{1] a 8ymPlectic form is invariant along the trajectory of a Hamilto-nian system. Based on this fundamental property, certain techniques have been developed.The purpose of this paper is to extend such an approach to a wider class of dynamic systeIns,namely, genera1ized Hamiltonian systems. Our purpose is to investigate a class of dynaInicsystems, which possess a certain "geometric structure".Deflnition 1.1[1'2]. Let M be a tIlallifo1d. w E fl'(M) is call…     

基于选择性支持向量机集成的混沌时间序列预测

提出了一种基于聚类的选择性支持向量机集成预测模型.为提高支持向量机集成的泛化能力，采用自组织映射和K均值聚类算法结合的聚类组合算法，从每簇中选择出精度最高的子支持向量机进行集成，可以保证子支持向量机有较高精度并提高了子支持向量机之间的差异度.该方法能以较小的代价显著提高支持向量机集成的泛化能力.采用该方法对Mackey-Glass混沌时间序列和Lorenz系统生成的混沌时间序列进行预测实验，结果表明可以对混沌时间序列进行准确预测，验证了该方法的有效性. 关键词： 支持向量机 集成 混沌时间序列 聚类     

ZnTe（ZnTe：Cu）多晶薄膜的XPS研究

用共蒸发法在室温下制备了ZnTe及ZnTe：Cu多晶薄膜，测量了电导率温度曲线，发现不掺杂的ZnTe薄膜的暗电导随温度的增加而线形增加，呈常规的半导体材料特征；掺Cu的ZnTe薄膜在温度较低时，lnσ随温度升高而缓慢增加，随后缓慢降低，达到一极小值，当温度继续升高时又陡然增加，呈现异常现象。用XPS研究了N2气氛下退火前后表面状态，发现不掺Cu的ZnTe薄膜呈现富Te现象。掺Cu后Te氧化明显，以ZnTe形式存在的Te明显减少；ZnTe：Cu薄膜中Zn的含量在退火前后变化明显，退火前，Zn主要以ZnTe形式存在，退火后Zn原子向表面扩散，使表面成分更加均匀，谱峰变宽；退火时，部分Cu原子进入晶格形成CuxTe相，引起载流子浓度变化，导致ZnTe：Cu多晶薄膜的电导温度关系异常。     

Strongly Correlated Effect in TiS2

The thermoelectric compound TiS2 is studied by using the full-potential linearized augmented plane-wave method on the density functional theory with the generalized gradient approximation （GGA） as well as the on-site Coulomb interaction correction （＋U）. The Seebeck coefficient of TiS2 is calculated based on the electronic structure obtained within the GGA under the consideration of the on-site Coulomb interaction. The calculated Seebeck coefficient at 300K shows that Coulomb interaction U in the range of 4.97-5.42eV is important to reproduce the experimental data. The obtained energy gap Eg around 0.05 eV indicates that TiS2 is an indirect narrow-gap semiconductor.     

道路约束条件下的移动机器人跟踪

为提高移动机器人的位置估计精度和跟踪效果,提出一种基于道路约束条件下的移动机器人鲁棒约束H∞滤波(CHF)跟踪算法.首先,将机器人移动的道路网络作为跟踪的约束条件,并利用当前统计模型对机器人的运动进行建模.其次,将道路约束条件作为机器人跟踪的非线性状态约束,利用最小协方差估计推导了鲁棒CHF递推方程.通过拉格朗日乘子法对非线性约束优化估计问题进行求解,并利用约束信息对CHF算法的状态更新过程进行了改进.最后,通过对CHF算法和无约束的H∞滤波算法的跟踪性能进行了对比分析和验证.仿真结果表明,该算法可以实现机器人的跟踪,且跟踪精度优于HF算法.