The second Hopf bifurcation in lid-driven square cavity

To date, there are very few studies on the second Hopf bifurcation in a driven square cavity, although there are intensive investigations focused on the first Hopf bifurcation in literature, due to the difficulties of theoretical analyses and numerical simulations. In this paper, we study the characteristics of the second Hopf bifurcation in a driven square cavity by applying a consistent fourth-order compact finite difference scheme recently developed by us. We numerically identify the critical Reynolds number of the second Hopf bifurcation located in the interval of(11093.75, 11094.3604) by bisection. In addition, we find that there are two dominant frequencies in its spectral diagram when the flow is in the status of the second Hopf bifurcation, while only one dominant frequency is identified if the flow is in the first Hopf bifurcation via the Fourier analysis. More interestingly, the flow phase portrait of velocity components is found to make transition from a regular elliptical closed form for the first Hopf bifurcation to a non-elliptical closed form with self-intersection for the second Hopf bifurcation. Such characteristics disclose flow in a quasi-periodic state when the second Hopf bifurcation occurs.     

固态组合化学及其在材料科学中的应用

概述了固态组合化学的概念及其在新材料开发中的应用 ,着重阐述了材料化合物薄膜库的组合制备方法和筛选技术的特点 ,简述了固态组合化学技术在超导、巨磁阻、磷光、催化剂、沸石等新材料开发中的应用以及固态组合化学现有技术中的困难和今后的发展方向     

Application of Galerkin spectral method for tearing mode instability

Magnetic reconnection and tearing mode instability play a critical role in many physical processes. The application of Galerkin spectral method for tearing mode instability in two-dimensional geometry is investigated in this paper. A resistive magnetohydrodynamic code is developed, by the Galerkin spectral method both in the periodic and aperiodic directions. Spectral schemes are provided for global modes and local modes. Mode structures, resistivity scaling, convergence and stability of tearing modes are discussed. The effectiveness of the code is demonstrated, and the computational results are compared with the results using Galerkin spectral method only in the periodic direction. The numerical results show that the code using Galerkin spectral method individually allows larger time step in global and local modes simulations, and has better convergence in global modes simulations.     

大气压射流等离子体中O及OH自由基的发射光谱在线诊断

OH自由基及氧原子在大气化学、表面处理及化学污染物分解等方面有着重要的作用。利用发射光谱技术在线测量了大气压射流等离子体中OH自由基紫外波段与O自由基777,844 nm波段的发射光谱。研究了OH自由基与氧原子光谱强度随放电功率及放电体系中所加入的氧浓度的变化。将实验测得的OH自由基光谱图与用Lifbase数据库模拟光谱图进行比较,估算了OH自由基的转动温度。结果表明:OH自由基的转动温度随放电功率的增加而增加,随工作气体流速的增加而减小。     

重排函数的一些应用

利用重排的方法找到了H~p空间的一类函数,这类函数的H~p范数和Lp范数是等价的(0p≤1).对于每一个f∈L~p(R~n),存在一个函数g∈H~p(R~n)满足其分布函数相等d_f=d_g,并且||g||Lp≤||g||H~p≤Cp||g||Lp.另外,还介绍了一种构造H~p空间的L~∞-原子的方法.     

香水中邻苯二甲酸酯总量测定及其暴露评估

建立了快速测定香水中邻苯二甲酸酯(PAEs)的前处理方法。将香水中的PAEs水解为邻苯二甲酸(PA),再利用磷酸三丁酯萃取酸化液中的PA,使用高效液相色谱-二极管阵列检测器定量分析,并评估了PAEs的暴露量。实验考察并优化了影响PAEs水解率的因素,包括KOH的浓度和体积、乙醇的体积、水解时间和温度,优化后的水解条件:10 mL 4 mol/L KOH,1 mL乙醇,水解时间20 min,水解温度80℃。目标分析物的线性范围为3~240μmol/L(R2=0.999 1),LOD和LOQ分别为4.6μmol/kg和5.9μmol/kg,加标回收率为83.4%~92.7%,日内和日间精密度(RSD)不大于6.8%(n=5)。选择35种香水进行测定,PAEs总量范围在LOD~77.738 mmol/kg之间,成年女性经由香水途径接触PAEs的最大暴露水平为0.474 2μg/(kg·d)。该方法前处理过程简单,可靠性高,适用范围广,可以作为检测香水中PAEs的新选择。     

手性螺环双膦氧化物催化的不对称还原-Aldol反应(英文)

以螺环膦氧化合物为催化剂及三氯硅氢为还原剂,发展了手性Lewis碱催化的烯酮与醛的不对称还原-Aldol反应.该类催化剂在查耳酮以及类似物与各种醛的不对称还原-Aldol反应中表现出较高的反应活性和良好的立体选择性,以较好的产率(45%-88%)、中等到优秀的非对映选择性(8:92-100:0)以及最高达95%的ee值得到相应的还原Aldol产物.     

pH值对L-抗坏血酸―赖氨酸/甲硫氨酸Maillard反应产物的抗氧化活性的影响

对不同pH值对L-抗坏血酸―赖氨酸/甲硫氨酸模型体系发生的美拉德(Maillard)反应所得到产物(MRPs)的抗氧化性活性的影响进行了研究。结果表明,MRPs的pH值在酸性条件下增大,在碱性条件下减小;在pH=5时,其紫外吸光度、棕色指数、还原力和DPPH自由基清除能力均达到最大;Fe2+螯合能力随着pH值的增大而增大。因此可以得出结论:pH值对抗坏血酸的MRPs的抗氧化活性有较大影响,且在pH=5时,抗坏血酸的Maillard反应产物的抗氧化活性最强。     

Acoustic Rotation Modes in Complex Plasmas

Acoustic rotation modes in complex plasmas are investigated in a cylindrical system with an axial symmetry. The linear mode solution is derived. The mode in an infinite area is reduced to a classical dust acoustic wave in the region away from the centre. When the dusty plasma is confined in a finite region, the breathing and rotating-void behaviour are observed. Vivid structures of different mode number solutions are illustrated.