排序方式: 共有59条查询结果,搜索用时 203 毫秒
41.
A Comparison between AIN Films Grown by MOCVD Using Dimethylethylamine Alane and Trimethylaluminium as the Aluminium Precursors
下载免费PDF全文
![点击此处可从《中国物理快报》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Aluminium nitride (AIN) films grown with dimethylethylamine Mane (DMEAA) are compared with the ones grown with trimethylaluminium (TMA). In the high-resolution x-ray diffraction Ω scans, the full width at half maximum (FWHM) of (0002) AIN films grown with DMEAA is about 0.70 deg, while the FWHM of (0002) AIN films grown with TMA is only 0.11 deg. The surface morphologies of the films are different, and the rms roughnesses of the surface are approximately identical. The rms roughness of AIN films grown with DMEAA is 47.4nm, and grown with TMA is 69.4nm. Although using DMEAA as the aluminium precursor cannot improve the AIN crystal quality, AIN growth can be reached at low temperature of 673 K. Thus, DMEAA is an alternative aluminium precursor to deposit AIN film at low growth temperatures. 相似文献
42.
43.
本文应用统计力学方法,以简单的几何平均法则作为气体分子力参数(σ及ε)关联的特征组合规则,提出一则可供确定实际混合气体虚拟混合规则的新的简单关联式.应用新混合规则与本课题组于1983年所提出的三次维里型对比状态方程相结合,能使该状态方程对化工机械实际混合气体得以有效的开发.本文新方法计算结果与实验数据十分吻合. 相似文献
44.
45.
46.
Meerwein芳基化反应是在烯键上导入芳基的一种重要方法:ArN2Cl+RCH=CHZ→ArCR=CHZ+ArCHRCHClZ化合物RCH=CHZ中Z为电子取代基时,反应容易进行,Z为OAc、OR时,也可以起芳基化反应,但烯胺(Z=NR2)与芳基重氮盐作用,只得到偶联产物。烯胺与N,N-二烷基苯胺为插烯物(Vinglogs),由于氮原子上的未共电子对与π键共轭,使烯键或苯环碳原子上电子密度增加,容易起偶联反应。 相似文献
47.
We report on temperature-programmed growth of graphene islands on Ru(0001) at annealing temperatures of 700°C,800°C,and 900°C.The sizes of the islands each show a nonlinear increase with the annealing temperature.In 700°C and 800°C annealings,the islands have nearly the same sizes and their ascending edges are embedded in the upper steps of the ruthenium substrate,which is in accordance with the etching growth mode.In 900°C annealing,the islands are much larger and of lower quality,which represents the early stage of Smoluchowski ripening.A longer time annealing at 900°C brings the islands to final equilibrium with an ordered moir’e pattern.Our work provides new details about graphene early growth stages that could facilitate the better control of such a growth to obtain graphene with ideal size and high quality. 相似文献
48.
设计并制备了Y形两亲性嵌段聚合物(mPEG)2-HDI-PEA,以六亚甲基二异氰酸酯三聚体为反应物,分别与聚乙二醇单甲醚、聚醚胺进行官能团偶合生成Y形聚氨酯,其在水溶液中自组装行为。通过1H NMR、FT-IR和GPC对分子结构进行表征,通过透射电镜(TEM)和原子力显微镜(AFM)对自组装形貌进行表征。聚合物(mPEG)2-HDI-PEA在不同温度和不同浓度下自组装形成的聚集体形貌,表明分子间的氢键作用对聚集体形貌起着重要作用。(mPEG)2-HDI-PEA嵌段聚合物在室温下自组装,形成新颖的形貌,表面具有“沟壑”的球状胶束,随着浓度增加形成的球状胶束表面“沟壑”越明显,排列越有序;当嵌段聚合物(mPEG)2-HDI-PEA在60 ℃水溶液中自组装时,形成蠕虫状胶束,并随着浓度的增加从蠕虫状转变成网状;聚合物溶液在60 ℃环境中静置1个月后,在AFM下观测到蠕虫状胶束长度增加,当蠕虫装胶束从60 ℃冷却至室温胶束形貌、尺寸未改变,当稀释并静置在60 ℃3天后胶束从蠕虫状转变成棒状或者椭球状,展现出动态组装与解离的过程。
相似文献
49.
50.
以双键改性聚轮烷为滑动结构、DSDMA为互锁结构,与甲基丙烯酸甲酯、丙烯酸甲酯进行自由基聚合,制备了不同配比 (0.25%, 0.5%, 0.75%, 1%, 1.25%) 的丙烯酸酯级联结构形状记忆高分子材料,其结构与性能经DSC、DMA表征。研究了不同配比对其凝胶含量、Tg与储能模量和记忆性能的影响。结果表明:随着配比的增加,凝胶含量增加,Tg向高温区移动,初始储能模量升高,当配比大于0.75,其固定率稳定在98%左右,回复率在0.5%两侧都呈现升高的趋势。 相似文献