YGG:Cr晶体的光谱特性

本文利用10K下的吸收谱,拟合计算了YGG:Cr的晶场能级,估算了黄昆因子和平均声子能量,讨论了R线随温度的红移和宽化.     

308nm准分子激光对C60薄膜的刻蚀特性研究

测量在空气和真空中３０８ｎｍ准分子激光对Ｃ６０薄膜的刻蚀速率和刻蚀阈值，讨论了环境中氧气对刻蚀特性的影响。     

Darboux Transformation and Variable Separation Approach： the Nizhnik-Novikov-Veselov Equation

Darboux transformation (DT) is developed to systematically find variable separation solutions for the Nizhnik-Novikov-Veselov equation. Starting from a seed solution with some arbitrary functions, the one-step DT yields the variable separable solutions, which can be obtained from the truncated Painleve analysis, and the two-step DT leads to some new variable separable solutions, which are the generalization of the known results obtained by using a guess ansatz to solve the generalized trilinear equation.     

Symmetries and Strong Symmetries of the （3＋1）-Dimensional Burgers Equatio

The strong symmetries (recursion operators) and the inverse strong symmetries of a (3 1)-dimensional Burgers equation are given explicitly.Infinitely many symmetries of the considered model are obtained by acting the strong symmetries and the inverse strong symmetries on some seeds.An infinite-dimensional full Lie point symmetry algebra is also given.     

渔山列岛潮间带生物生态学初步研究

本次调查共鉴定出潮间带生物116种,其中环节动物3种,占总生物种类的2.6%;软体动物45种,占38.8%;甲壳类19种,占16.4%;棘皮动物6种,占5.2%;藻类37种,占31.9%;其他种类6种,占5.2%.潮间带生物资源总平均生物量6760.21g·m-2,平均栖息密度为2750.36 ind·m-2.生物种类数、生物量和栖息密度均为低潮区中潮区高潮区.断面分布不均匀,生物量以大白礁最高,为16006.2g·m-2,小澳次之,为2499.3g·m-2,大沙岙里生物量最低,仅为大白礁生物量的1/10.优势种明显,日本笠藤壶生物量在优势种中占首位,最大生物量达970.91g·m-2;其次为角偏顶蛤,最大生物量为4088.29g·m-2;其他优势种主要有厚壳贻贝、覆瓦小蛇螺和条纹隔贻贝,生物量分别为1406.37,1012.82和949.39g·m-2.     

苯丙氨酸酯类衍生物对映异构体的拆分

利用手性Ｃｈｉｒａｌｃｅｌ ＯＤ柱高效液相色谱对一系列苯丙氨酸酯类衍生物对映异构体进行了拆分，获得了良好的分离结果。讨论了化合物的结构对拆分效果的影响。     

用高效液相色谱测定食物中维生素B_1、B_2含量

本文着重介绍使用高效液相色谱荧光测定天然食品中维生素B_1、B_2含量。在测试维生素B_1时,使用键合C_(18)分析柱,流动相为CH_3OH-0.01M KH_2PO_4 45/55,流速1.5ml/min,Ex:390nm,EM:470nm,柱温45℃;测维生素B_2时用强阳离子交换柱,流动相CH_3OH/0.01M KH_2PO_4,CH_3OH由30～70分钟梯度淋洗,流速1.5ml/min,柱温45℃,Ex:449nm,EM:530nm。在上述条件下所测部分食物中维生素B_1的回收率是92.51～101.85%,变异系数2.14～6.57%;维生素B_2的回收率为89.91～95.18%,变异系数0.19～6.19%。部分食物样品的测试结果令人满意。     

头发检测与疑难病诊断

综述了我国用头发诊断疑难病,包括恶性肿瘤、心脑血管疾病、尘肺的研究概况。20余年来,中国科技人员创造了4类利用头发微量元素谱诊断疾病的方法。18项研究报告表明,头发微量元素谱可将癌症病人与健康人正确区分开来,为临床癌症诊断奠定了坚实的实验基础,也为利用头发样本代替血液样本作人群癌症筛查提供了理论依据;11项研究结果表明,借助头发微量元素谱,可相当准确地判别待测样本的健康属性,可以诊断和预报疾病,可以筛选高危人群,对心脑血管病的早发现、早诊断、早治疗具有重要的潜在应用价值;9项研究结果证明,测量头发元素,建立判别方法,可以从待检样品准确诊断尘肺患者和找出尘肺高危人群,并可提早3～5年对尘肺的发生作出预报。实践表明,头发检测是疑难病筛查的一种简便、经济、实用、有效的新方法。     

新型含氟姜黄素类似物的合成、晶体结构及抗肿瘤活性

采用活性基团拼接法将含氟苯甲醛与酮反应, 合成了5个含氟单羰基姜黄素类似物, 结构经IR, ¹H NMR及ESI-MS确认. 对所合成的化合物进行了抗肿瘤活性测试(MTT法), 结果表明, 部分化合物对肿瘤细胞有较强的选择性抑制活性, 其中2,6-二(4-氟亚苯基)环己酮(3a)和2,6-二(2-氟亚苯基)环己酮(3b)的抗肿瘤谱广, 活性较好, 就此对化合物3b作了单晶培养, 并就晶体结构进行了X衍射分析. 结构表明化合物3b属三斜晶系, 空间群 P-1. 晶胞参数 a＝0.9222(2) nm, b＝0.9732(2) nm, c＝1.0127(2) nm, α＝88.920(4)°, β＝75.672(3)°, γ＝62.404(3)°, V＝0.7755(3) nm³, Z＝2, D_c＝1.329 Mg•m^－3, μ＝0.097 mm^－1, F(000)＝324, 最终偏离因子R＝0.0590, wR＝0.1841.     

SUSPENSION-SWELLING GRAFT COPOLYMERIZATION——SYNTHESIS OF ACS RESINS*

Acrylonitrile (AN)-chlorinated polyethylene (CPE)-styrene (St) (ACS) terpolymer was synthesized by suspension-swelling graft copolymerization method, in which two key factors such as dispersing system and time were studied. Highly effective comples dispersing system was chosen and determined, and two-layer protection model was put forward to clarify the stable effect mechanism Varying the swelling time of CPE in AN and St monomer mixture, some results such as grafting effect, particle characteristics, rubber particle morphology and its size distribution, and properties of ACS resins were investigated , thus the optimum swelling time was proposed.