超临界CO2中苯乙烯RAFT分散聚合

以末端带有三硫代碳酸酯的聚二甲基硅氧烷(PDMS-TTC)为大分子链转移剂,在超临界CO2中通过苯乙烯的可逆加成-断裂链转移(RAFT)聚合制备了聚二甲基硅氧烷-b-聚苯乙烯(PDMS-b-PS)嵌段共聚物,对聚合反应动力学以及产物的组成、分子量和形貌等进行了表征.由于PDMS链段可溶于超临界CO2而PS链段不溶,因此在超临界CO2中制备PDMS-b-PS嵌段共聚物的过程是以嵌段共聚物自身作为分散稳定剂的RAFT分散聚合,产物为粒径较均一的球形颗粒.     

线性规划消耗系数矩阵灵敏度分析的某些探讨

讨论了线性规划模型中 ,消耗系数矩阵 A中某个基变量或某个约束方程的系数向量变化以及增减约束方程时 ,对最优基、最优解、目标函数值和影子价格的影响 .     

3,5-二碘水杨醛缩2,6-二氨基吡啶席夫碱及其金属配合物的制备及与ct-DNA的作用研究

由3,5-二碘水杨醛和2,6-二氨基吡啶反应合成了席夫碱配体,将其与4种过渡金属硝酸盐反应生成相应的配合物,通过元素分析、电子光谱、红外光谱、TG-DTA及摩尔电导率确定配合物的结构和组成为[M(NO3)L]·H2O,由Gaussian03程序对其进行了优化计算,给出了配合物的主要键参数.通过紫外吸收光谱、荧光发射光谱...     

Role of the zonal flow in multi-scale multi-mode turbulence with small-scale shear flow in tokamak plasmas

The structural characteristics of zonal flows and their roles in the nonlinear interaction of multi-scale multi-mode turbulence are investigated numerically via a self-consistent Landau-fluid model. The multi-mode turbulence here is composed of a shorter wavelength electromagnetic (EM) ion temperature gradient (ITG) mode and a Kelvin-Helmholtz (KH) instability with long wavelengths excited by externally imposed small-scale shear flows. For strong shear flow, a prominent periodic intermittency of fluctuation intensity except for dominant ITG component is revealed in turbulence evolution, which onset time depends on the ion temperature gradient and the shear flow amplitudes corresponding to different KH instabilities. It is identified that the intermittency phenomenon results from the zonal flow dynamics, which is mainly generated by the KH mode and back-reacts on it. It is demonstrated that the odd symmetric components of zonal flow (same symmetry as the external flow) make the radial parity of the KH mode alteration through adjusting the drift velocities at two sides of the resonant surface so that the KH mode becomes bursty first. Afterwards, the ITG intermittency follows due to nonlinear mode coupling. Parametric dependences of the features of the intermittency are elaborated. Finally, associated turbulent heat transport is evaluated.     

左截断右删失数据下分位密度估计的重对数律

在左截断右删失数据下，我们基于乘积限估计给出了分位密度估计， 获得了分位密度估计及其导数的重对数律。     

Damage effects and mechanism of the silicon NPN monolithic composite transistor induced by high-power microwaves

A two-dimensional model of the silicon NPN monolithic composite transistor is established for the first time by utilizing the semiconductor device simulator, Sentaurus-TCAD. By analyzing the internal distributions of electric field,current density, and temperature of the device, a detailed investigation on the damage process and mechanism induced by high-power microwaves(HPM) is performed. The results indicate that the temperature elevation occurs in the negative half-period and the temperature drop process is in the positive half-period under the HPM injection from the output port.The damage point is located near the edge of the base–emitter junction of T2, while with the input injection it exists between the base and the emitter of T2. Comparing these two kinds of injection, the input injection is more likely to damage the device than the output injection. The dependences of the damage energy threshold and the damage power threshold causing the device failure on the pulse-width are obtained, and the formulas obtained have the same form as the experimental equations, which demonstrates that more power is required to destroy the device if the pulse-width is shorter. Furthermore,the simulation result in this paper has a good coincidence with the experimental result.     

Ti3SiC2/Inconel718摩擦副的高温摩擦学性能

本文考察了Ti3SiC2-Inconel 718摩擦副从室温到800 ℃范围内的摩擦磨损性能.结果表明:温度的升高有利于改善Ti3 SiC2-Inconel 718摩擦副的摩擦磨损性能,在800℃时,其摩擦磨损性能优异.随着温度的升高,摩擦系数从室温的0.71降至800℃时的0.37,Ti3SiC2的磨损率从4×10-3 mm3/(N·m)降至10-5mm3/(N·m)以下.高温塑性变形和摩擦氧化物层的形成导致摩擦系数的降低,300℃以下,晶粒的断裂、拔出与脱落以及材料向合金的转移造成了Ti3SiC2高的磨损率,从400℃至800℃,Ti3 SiC2晶粒的断裂与脱落受到明显抑制,其磨损率显著降低.     

仿真转台伺服系统动态模型辨识与计算

仿真转台广泛应用于光电制导导引头及其对抗的仿真,对某型仿真转台进行高精度模型辨识可以有效提高系统的动态控制精度和设计效率。基于此,提出了一种转台伺服系统频率特性自动测试方法,根据测试数据采用参数递阶辨识方法分段拟合得到了被控对象的高精度传递函数模型。辨识结果与实测数据相比:在体现伺服系统重要特征的中低频段,幅度绝对误差1 d B,相位绝对误差2°;在高频段,得到了复杂的机械谐振环节特性,验证了被控对象传递函数模型的准确性。对于转台的动态精度计算,采用频率设计分析建模方法,结合被控对象高精度传递函数和实际校正环节模型得到了转台的动态精度计算模型,通过比较同一输入情况下实测动态误差与模型输出误差数据验证了模型准确性,结果表明了该方法的有效性。建立的动态精度计算模型能够反映实际系统的动态过程和动态误差变化规律,也为同类设备伺服系统的模型辨识和动态精度分析计算提供了方法。     

脐橙果皮的室温和热辅助表面解吸常压化学电离质谱的比较

以脐橙果皮为研究对象,比较了室温和热辅助表面解吸常压化学电离源(DAPCI)的解吸电离特性,结合串联质谱技术,对果皮中香气、糖、黄酮类等主要成分进行了鉴定,并通过主成分分析(PCA)方法对热辅助DAPCI-MS所获外果皮指纹谱图信息进行分析,进而区分了3个不同产地脐橙。 结果表明,室温DAPCI-MS对脐橙果皮中的香气成分具有较强的解吸电离能力,而热辅助DAPCI-MS则更适合于分析果皮中的黄酮类和糖类及其衍生物。 DAPCI-MS具有灵敏度高、分析速度快等特点,有望成为农产品品质快速检测与产地识别研究的新方法。     

具有侧挂胆固醇液晶元的两亲嵌段功能大分子的合成及自组装研究

采用可逆加成-断裂链转移(RAFT)聚合法, 合成了系列具有刚性疏水胆固醇液晶元的聚甲基丙烯酸甘油酯-嵌段-聚甲基丙烯酸亚己基胆固醇酯(PGMA-b-PMA6Chol)两亲嵌段功能大分子. 运用核磁共振(NMR)和凝胶渗透色谱(GPC)表征了其化学结构及分子量, 并对其热性质、液晶相结构及相转变行为分别运用热台偏振光显微镜(POM)、热重分析仪(TGA)、示差扫描量热仪(DSC)和二维小角X射线散射(2D-SAXS)表征. 采用纳米沉淀法研究了所得嵌段大分子的溶液自组装, 动态光散射(DLS)和扫描电子显微镜(SEM)的研究发现溶液自组装聚集体为尺寸0.7～2.0 μm的球形结构, 其中含有较高刚性链段质量比例的嵌段大分子组装形成开口中空结构的聚集体, 且其尺寸随着溶液温度的升高减小, 呈现可逆温度变化响应性. 结果表明刚性疏水胆固醇液晶单元和具有多羟基结构的亲水性甲基丙烯酸甘油酯的嵌段共聚可以调控该类嵌段大分子自组装及溶液聚集体形貌.