Fabrication and Magnetic Properties of Co-Doped TiO2 Powders Studied by Nuclear Magnetic Resonance

Co0.04 Ti0.96O2 powders are fabricated by sol-gel method. The structure and magnetic properties are investigated under different annealing conditions systematically with emphasis on the influence of oxygen pressure. Pure anatase structure was acquired for all the samples annealed at 450℃ for one hour. The samples annealed in air exhibit evident room-temperature ferromagnetism (RTFM) with a small magnetic moment of 0.029μB per Co atom and coercivity Hc of 26 Oe, while the samples annealed in vacuum have strong RTFM with a larger magnetic moment of 1.18μB per Co atom and Hc of 430 Oe. The zero-field spin echo nuclear magnetic resonance spectrum of ^59Co is obtained to prove the existence of Co dusters in the latter samples, implying that the Co dusters are responsible for the strong RTFM in the samples annealed in vacuum. No Co cluster could be observed using both XPS and NMR techniques in the samples annealed in air, implying that the RTFM found in these sample sis intrinsic.     

长链单不饱和脂肪醇乙酸酯的红外和拉曼光谱研究

本文研究了鳞翅目昆虫性外激素——长链单不饱和脂肪醇乙酸脂系列化合物的红外和拉曼光谱。对主要谱带进行了归属。探讨了十一种系列化合物在室温液态和低温固态的光谱差异,得到了某些特征带与链结构的关系。结合其它物理性质,它们可用于估计同系物的双键位置和链长。     

Ce掺杂Bi2MoO6/TiO2纳米纤维异质结的制备及可见光催化性能

以静电纺丝技术制备的TiO_2纳米纤维为基质,通过溶剂热法制备了异质结型稀土Ce掺杂Bi_2MoO_6/TiO_2复合纳米纤维。利用X射线衍射(XRD)、扫描电子显微镜(SEM)、X射线光电子能谱(XPS)、透射电镜(TEM)、紫外-可见漫反射光谱(UV-Vis DRS)以及荧光光谱(PL)等分析测试手段对样品的物相、形貌和光学性能等进行表征。以罗丹明B为模拟有机污染物,研究了样品的可见光催化性能。结果表明:在稀土掺杂样品中,Ce离子进入Bi_2MoO_6晶格,部分取代Bi3+,导致晶胞膨胀,晶格畸变,形成缺陷;与TiO_2复合形成异质结,有利于光生电荷的产生、转移和有效分离,从而提高TiO_2纳米纤维的光催化活性。可见光照射180 min,罗丹明B的降解率达到95.1%。经5次循环光催化降解活性基本不变,样品具有良好的光催化稳定性。     

新型有机镁试剂的研究进展

介绍了双格氏试剂、镁杂碳环化合物和含有多官能团的格氏试剂的制备、反应化学及在有机合成中的应用等。     

带依状态切换的扩散过程的稳定性

该文研究一类带依状态切换的扩散过程的稳定性. 应用耦合方法证明了这类过程的 Feller 连续性. 进一步, 在某些合理的条件下, 也证明了这类过程的强 Feller 连续性和指数遍历性. 最后, 对这类过程的正则性进行了简短讨论.     

基于W5300的嵌入式网络管理控制系统设计

简单网络管理协议以其易于使用、扩展性强、功能强大等优点在网络管理系统中有广泛应用。针对测控设备的网络管理需求,以单片机为核心,设计了一种基于以太网控制器W5300的嵌入式网络管理控制系统。详细讨论了W5300作为网络接口的软硬件实现方法,以及单片机对简单网络管理协议报文进行处理的软件设计方法。该系统可以实现网络管理站、代理站及测控设备分机的网络通信,数据传输可靠有效。本系统结构简单、实时性强、可靠性高,有效保证了网络管理控制系统的网络管控能力。     

REPRESENTATIONS OF AFFINE HECKEALGE BRAS OF TYPE G2

Let k be a field and q a nonzero element in k such that the square roots of q are in k. We use Hq to denote an affne Hecke algebra over k of type G2 with parameter q. The purpose of this paper is to study representations of Hq by using based rings of two-sided cells of an affne Weyl group W of type G2. We shall give the classification of irreducible representations of Hq. We also remark that a calculation in [11] actually shows that Theorem 2 in [1] needs a modification, a fact is known to Grojnowski and Tanisaki long time ago. In this paper we also show an interesting relation between Hq and an Hecke algebra corresponding to a certain Coxeter group. Apparently the idea in this paper works for all affne Weyl groups, but that is the theme of another paper.     

带马氏切换的马氏过程的指数收敛速度

设 (X(t), Z(t))是以[0,∞) ×{1, 2,…, n₀} 为状态空间的强马氏过程, 其第一分量 X(t) 依赖于第二分量 Z(t), 而第二分量 Z(t) 是一个马氏链. 应用耦合方法, 估计了(X(t), Z(t)) 的转移概率依全变差范数收敛于其不变概率测度的指数收敛速度.