基于多重自我假设的人质困境问题

囚徒困境及其变形模型,揭示了个体理性与群体理性选择之间的矛盾,从个体利益出发的行为往往不能实现团体的最大利益.本文以多重自我替代传统经济学中理性人的假设,将双曲贴现应用到人质困境中,解决短期利益与长期利益的不一致性给决策带来的困扰,从而实现个人利益与社会利益的统筹协调.     

Estimation of vector static magnetic field by a nitrogen-vacancy center with a single first-shell ~(13)C nuclear(NV–~(13)C)spin in diamond

We suggest an experimental scheme that a single nitrogen-vacancy(NV) center coupled to a nearest neighbor~(13) C nucleus as a sensor in diamond can be used to detect a static vector magnetic field. By means of optical detection magnetic resonance(ODMR) technique, both the strength and the direction of the vector field could be determined by relevant resonance frequencies of continuous wave(CW) and Ramsey spectrums. In addition, we give a method that determines the unique one of eight possible hyperfine tensors for an(NV–~(13) C) system. Finally, we propose an unambiguous method to exclude the symmetrical solution from eight possible vector fields, which correspond to nearly identical resonance frequencies due to their mirror symmetry about~(14)N–Vacancy–~(13) C(~(14)N–V–~(13) C) plane.     

Loss of cold atoms due to collisions with residual gases in free flight in a magneto-optical trap

The loss rate of cold atoms in a trap due to residual gas collisions differs from that in a free state after the cold atoms are released from the trap. In this paper, the loss rate in a cold rubidium-87 atom cloud was measured in a magneto-optical trap(MOT) and during its free flight. The residual gas pressure was analyzed by a residual gas analyzer, and the pressure distribution in a vacuum chamber was numerically calculated by the angular coefficient method. The decay factor, which describes the decay behavior of cold atoms due to residual gas collisions during a free flight, was calculated. It was found that the decay factor agrees well with theoretical predictions under various vacuum conditions.     

分子印迹固相萃取/高效液相色谱法分离和富集枳实中4种黄烷酮

采用沉淀聚合法以橙皮素为模板分子,2-乙烯基吡啶为功能单体,二甲基丙烯酸乙二醇酯为交联剂,合成了橙皮素分子印迹聚合物。利用紫外光谱法确定了最佳功能单体与配比,优化了合成条件。采用傅立叶变换红外光谱、扫描电子显微镜、静态吸附对聚合物进行表征。实验结果表明,分子印迹聚合物的吸附性能明显优于空白印迹聚合物,且此聚合物对柚皮苷、橙皮苷、柚皮素和橙皮素的相对选择系数分别为1.40,1.39,1.59和2.89,表明该分子印迹聚合物对4种黄烷酮有较好的选择性。将印迹聚合物作为固相萃取填料,对枳实提取液进行分离和富集,结果表明上述4种黄烷酮的提取率分别为72.6%,61.1%,95.4%和93.5%,分离富集效果良好,大大提高了枳实中4种黄烷酮的提取效率。     

上海电视塔球形部件的压力分布和气动力

通过风洞试验研究了上海电视塔上下球体的风压和气动力．结果表明：两球体的压力分布均不同于光滑圆球，阻力比超临界光滑圆球大得多．     

ANALYSIS OF INTERPHASE MECHANICAL BEHAVIOR WITH INTERFACE ELEMENT IN THE COMPOSITE MATERIALS

ＡＮＡＬＹＳＩＳＯＦＩＮＴＥＲＰＨＡＳＥＭＥＣＨＡＮＩＣＡＬＢＥＨＡＶＩＯＲＷＩＴＨＩＮＴＥＲＦＡＣＥＥＬＥＭＥＮＴＩＮＴＨＥＣＯＭＰＯＳＩＴＥＭＡＴＥＲＩＡＬＳＡＮＡＬＹＳＩＳＯＦＩＮＴＥＲＰＨＡＳＥＭＥＣＨＡＮＩＣＡＬＢＥＨＡＶＩＯＲＷＩＴＨＩＮ...     

N-芳基马来海枞酸单甲酯二酰亚胺位阻异构化反应及其动力学特性

在合成松香基手性试剂(4a~4f)的过程中,首次发现N-(1-萘基)-马来海枞酸二酰亚胺(4f)的位阻异构现象,而与其结构类似的N-苯基-马来海枞酸二酰亚胺(4a)、N-(2-羧基苯基)-甲酯化马来海松酸二酰亚胺(4b)、N-(2-硝基苯基)-甲酯化马来海松酸二酰亚胺(4c)、N-(2-氯苯基)-甲酯化马来海松酸二酰亚胺(4d)和N-[1-(2-氨基)-苯基]-甲酯化马来海松酸二酰亚胺(4e)则没有该位阻异构现象.化合物4a~4f的结构通过核磁共振、质谱和红外光谱等方法进行了表征.采用变温条件下的1H NMR谱图研究了化合物4f的位阻异构化动力学特性.