铜催化苯甲酰胺有氧环化合成7-叔烷基异喹啉二酮

发展了一种高效、简单的铜/空气催化体系催化的苯甲酰胺串联自由基环化合成7-叔烷基异喹啉二酮的反应。 在廉价CuI存在下,空气环境中,N-烷基-N-甲基丙烯酰基苯甲酰胺与AIBN发生串联自由基加成/环化/碳碳偶联反应,以52%~73%的产率合成了一系列的7-取代异喹啉二酮。 此研究为合成具有潜在药用价值的含氰取代异喹啉二酮提供了一条快速、简单、温和的构建途径。     

1, 1, 2, 3, 4, 5-六苯基硅杂环戊二烯X射线谱的理论研究

近年来苯基硅杂环戊二烯作为一类高效的有机发光二极管材料被广泛研究。本工作利用密度泛函理论结合芯态空穴近似研究了1, 1, 2, 3, 4, 5-六苯基硅杂环戊二烯分子中碳原子K壳层和硅原子L壳层的X射线光电子能谱和近边X射线吸收精细结构谱,与实验谱线符合较好。通过理论结果对实验测量的1, 1, 2, 3, 4, 5-六苯基硅杂环戊二烯分子的X射线谱进行了分析和标定。我们发现碳原子K壳层X射线光电子能谱在低能区283.8eV处的谱峰是由于与硅原子成键的两个电负性较强的碳原子导致的。碳原子K壳层近边X射线吸收精细结构谱中最强的吸收峰与苯分子的吸收峰类似。硅原子L壳层近边X射线吸收精细结构谱两个主要吸收峰分别来自于σ_Si-C^*和π_Si-Ph^*跃迁。     

金属介电常数的色散模型对光学Tamm态的影响

比较银介电常数三种色散模型对光学Tamm态的影响,根据三种色散模型的复折射率随波长的变化研究银-光子晶体-银结构TE波和TM波的光学Tamm 态随入射角、银层厚度及周期数的变化.得出：三种色散模型下银-光子晶体-银结构中都会出现两个光学Tamm 态（OTS1和OTS2）.三种色散模型下的光学Tamm 态的波长随入射角、银层厚度及周期数的变化规律一致.但是光学Tamm 态的透射峰值随入射角、银层厚度及周期数的变化规律不一致.Drude-Lorentz模型和Lorentz模型能够描述银的特征,而Drude模型不能.     

Enhancing parameter precision of optimal quantum estimation by quantum screening

We propose a scheme of quantum screening to enhance the parameter-estimation precision in open quantum systems by means of the dynamics of quantum Fisher information.The principle of quantum screening is based on an auxiliary system to inhibit the decoherence processes and erase the excited state to the ground state.By comparing the case without quantum screening,the results show that the dynamics of quantum Fisher information with quantum screening has a larger value during the evolution processes.     

Particle Size Influence on the Effective Permeability of Composite Materials

The energy method, which estimates the effective permeability of composite material is proposed. We approximate the effective static magnetic permeability by energy method and Maxwell-Garnett method for spherical particles dispersing system. Considering the effect of the interface layer between the medium and the particle, we study the nanoparticles embedded in a medium exactly. The interface layer property plays a significant factor for the effective permeability of the composite material in which nano-sized particles embedded.     

绕不同涂层水翼片状空化运动特性的实验研究

本文采用高速全流场显示技术和粒子图像测速系统(PIV)实验方法讨论了绕不同涂层水翼片状空化流动结构、运动特性的影响。结果表明:涂层的粗糙度和材质共同影响绕水翼片状空化流动结构和运动特性。实验中观察流动结构,发现粗糙表面比光滑表面更易于出现片状空化,氟碳涂层比环氧涂层更能够抑制片状空化;运动特性方面,表面粗糙度与涂层材质相比较,材质对片状空化的运动特性影响更大:表面光滑的氟碳涂层的低速区最小且区内速度波动也最弱,但区内的涡量分布更为集中;不同涂层造成水翼表面速度旋涡的位置不同,导致空穴脱落的位置不一样,空穴发展长度不同。     

DL-8型高压强电离真空计的另一种高灵敏度状态

通过数值模拟和实验证明,在取阴极电势低于50V且辅助极电势低于阴极电势时,DL-8型高压强电离真空计可获得与现有电极电势配置相当甚至更高的测量灵敏度.这一现象可以用新的电极电势配置下电场对阳极接近柱对称,使电子可以有更长的轨迹来解释.     

Measurement of H→μ~+μ~- production in association with a Z boson at the CEPC

The Circular Electron-Positron Collider(CEPC) is a future Higgs factory proposed by the Chinese high energy physics community. It is planned to operate at a center-of-mass energy of 240–250 Ge V and is expected to accumulate an integrated luminosity of 5 ab~(-1) over ten years of operation. At the CEPC, Higgs bosons will be dominantly produced from the ZH associated process. The vast number of Higgs events collected will enable precise studies of its properties, including Yukawa couplings to massive particles. With GEANT4-based simulation of detector effects, we study the feasibility of measuring the Higgs boson decaying into a pair of muons at the CEPC.The results with and without information from the Z boson decay products are provided, showing that a signal significance of over 10 standard deviations can be achieved and the H-μ-μ coupling can be measured within 10%accuracy.     

尿素醇解法制氨基甲酸甲酯体系的反相高效液相色谱分析

采用反相高效液相色谱法,在两根串联的C18柱上以甲醇-水为流动相,在8min内将尿素和氨基甲酸甲酯进行分离,在215nm波长下检测。在甲醇溶液中的质量浓度0~16%和0~50%范围内其峰面积和质量浓度呈良好的线性关系,线性回归方程分别为AUrea=148565x-39384,R2=0.9995;AMC=69055x-90493,R2=0.9985。     

波长可调谐超短光脉冲的简便高质的生成技术

提出了一种以处于增益开关调制状态下的法布里珀罗(Fabry-Pérot)半导体激光器作为光源,采用简单的自激注入锁定方式,以生成波长可调谐的超短光脉冲的实验系统。该实验装置中,激光器的外腔包括两个串联在一起的布拉格光纤光栅,一个掺铒光纤放大器(EDFA),一个光耦合器和两个环行器,其作用是选模,以及增强并控制反馈回激光器内腔的光强。该实验系统简单而高效,在24nm的波长调谐范围内获得了边模抑制比高于40dB的单模光脉冲输出;而在1521.8nm和1550.0nm之间28.2nm的波长调谐范围内,边模抑制比高于35dB。所得到的各个单波长激光脉冲的时域半峰全宽为140~260ps,各个脉冲的光谱半峰全宽皆为0.1nm。