全文获取类型
收费全文 | 8618篇 |
免费 | 1581篇 |
国内免费 | 2377篇 |
专业分类
化学 | 4119篇 |
晶体学 | 34篇 |
力学 | 1335篇 |
综合类 | 42篇 |
数学 | 2352篇 |
物理学 | 4694篇 |
出版年
2023年 | 164篇 |
2022年 | 178篇 |
2021年 | 141篇 |
2020年 | 144篇 |
2019年 | 116篇 |
2018年 | 180篇 |
2017年 | 77篇 |
2016年 | 182篇 |
2015年 | 211篇 |
2014年 | 355篇 |
2013年 | 314篇 |
2012年 | 419篇 |
2011年 | 399篇 |
2010年 | 379篇 |
2009年 | 297篇 |
2008年 | 219篇 |
2007年 | 458篇 |
2006年 | 439篇 |
2005年 | 542篇 |
2004年 | 511篇 |
2003年 | 340篇 |
2002年 | 421篇 |
2001年 | 521篇 |
2000年 | 412篇 |
1999年 | 507篇 |
1998年 | 223篇 |
1997年 | 145篇 |
1996年 | 185篇 |
1995年 | 255篇 |
1994年 | 207篇 |
1993年 | 211篇 |
1992年 | 203篇 |
1991年 | 153篇 |
1990年 | 190篇 |
1989年 | 184篇 |
1988年 | 218篇 |
1987年 | 225篇 |
1986年 | 191篇 |
1985年 | 254篇 |
1984年 | 169篇 |
1983年 | 114篇 |
1982年 | 107篇 |
1981年 | 88篇 |
1975年 | 114篇 |
1959年 | 83篇 |
1958年 | 125篇 |
1957年 | 123篇 |
1956年 | 109篇 |
1955年 | 118篇 |
1954年 | 90篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
911.
A novel Schiff base type polyester containing 2,2’-diamino-4,4’-bithiazole(DABT) was prepared by low-temperature interface polycondensation of 1,4-benzenedicarbonyl dichloride with 4,4’-(4,4’-bithiazole-2,2’-diylbis(imine-2,1-diyl)diphenol(BDDP), which is derived from a 2,2’-diamino-4,4’-bithiazole(DABT) Schiff base reacted with a 4-hydroxybenzaldehyde monomer.The newly generated polyester was evaluated based on characterization of its solubility,FTIR spectroscopy,elemental analysis,X-ray diffraction measurements and thermogravimetric analysis(TGA) studies. 相似文献
912.
Xiubin Ren Xiangyun Guo . College of Chemistry Chemical Engineering Xi’an University of Science Technology Xi’an Shaanxi China . State Key Laboratory of Coal Conversion Institute of Coal Chemistry Chinese Academy of Sciences Taiyuan Shanxi 《天然气化学杂志》2011,20(5):503-506
Monte Carlo method was applied to simulate the oscillatory behavior during partial oxidation of methane under non-isothermal condition. The simulation was performed to examine the influences of heat transfer constant and particle size on the kinetic oscillation. The oscillatory period and amplitude were observed to increase with the increase of heat transfer constant. The increase of catalyst particle size was found to result in short oscillatory period and more or less regular oscillations combined with the formation of oxide down to L=100. 相似文献
913.
Instudyonnewpharmaceuticalsandagrochemicals,theapplicationofheterocyclesisaveryimportantmethod,whichcanimprovethebiologicalactivities.Intheseyears.moreandmorenewagrochemicalshavebeensynthesizedwhichhavethestructurescontainingheterocycles.especiallypy... 相似文献
914.
A New Capillary Electrophoresis Apparatus with Piezoelectric Ceramics High Voltage Source and Amperometric Detector 总被引:13,自引:0,他引:13
Zuan Guang CHENI Jin Yuan MO Xiao Yun YANG Li Shi WANG Xue Ting MEIZ Min Sheng ZHANGI 《中国化学快报》1999,(3)
IntroductionHighperformancecapiliar}'electrophoresis(HPCE)isanewanalyticaltechnology'rapidly'developedinrecentyears.Withtheadvantagesofsmallsample.highsensitivity,highresolution.rapidanalysisandverycheaprunning,ithasbeenappliedinchemistry'.lifescienc... 相似文献
915.
ZHANG Feng zhang ** XU Liang shu HUANG He qing LONG Min nan QIU Xue hui CHEN Zhong 《高等学校化学研究》1999,(3)
IntroductionNitrogenasefromavarietyofN2-fixingorganismsiscomposedoftwo-componentprotein,MoFe-proteinandFe-protein.Fe-proteincontainsasingleFe4S4-cluster,whichhasthefunctionoftransferingelectronsfromdonortoMoFe-protein.MoFe-proteincontainsP-clusterpai… 相似文献
916.
α-Oxo Ketene Dithioacetals Chemistry-A Facile Route to the Synthesis of Fused Heterocyclic Compounds
Q-Oxo ketene dithioacetals and related compounds are versatile synthons in organicsynthesis'-'. The substitution reaction of or-oxo ketene dimethylthio acetals with diamineis one of the impel'tant applications for the synthesis of corresponding a-oxo ketenecyclic N, N-acetals. Junjappa and co-workers described this reaction ill a review'.However, since some kinds of ketene dimethylthio acetals are not easy to prepare, themethod melltioned above is limited. Zhu and co-workers had successfully… 相似文献
917.
A Novel Synthesis of Methyl 4, 6-O-Benzylidene-α-D-Glucopyranoside 2, 3-Cyclic Phosphite Ethyl Ester
Itiswellknownthatnearlyallthebiochemicalmetabolicprocessesofcarbohydratesinlivingorganismsinvolvetheparticipationofphosphorus.Forexample.glycosylphosphatesareofgreatsignificanceforthebiologicalactivityofglycoconjugatesandcanserveasintermediatesinbiologicalglycosyltransfer.Theyarealsoofgreatimportanceasglycosyldonorsinpreparationofoligosaccharides,whichareconstituentsofbiologicallyimportantcompoundssuchasantibiotics,glycolipids,glycoproteins.andimmunodeterminants'.Hencetheinvestigationofphospho… 相似文献
918.
Gnetifolin L and O, Two Dimeric Stilbenes from Gnetum Montanum 总被引:1,自引:0,他引:1
GnetuI)1monlanlImgr0wsinthes0uthernpart0fChinaandhasbeenusedf0rthetreatment0fbronchitisandarthritisinf0lkmedicinel.Previously,aninvestigationofthisspeciesledt0theis0lationofs0meaIkal0idsanddibenzyletherderivatives2.lnourstudies,tenc0mp0nentsincludingresveratr0l,is0rhapontigenin,daucoster0l,O-sitosterol,stearicacid,gnetif0linE,gnet0l,is0rhapontigenin-3-O-6-gluc0pyra(-)8-viniferinandgnetifolinCwere0btainedfromthisplant'.Inthefurtherstudy,f0urnewdimericstilbenesnamedgnetif0IinMandN',gnetifoli… 相似文献
919.
L.tibeticaHook.f.etThorns.isanimportantTibetanmedicineusedfortreatmentofmanydiseases'.Thelignanglycosidesandtriterpenesfromthisplanthavebeenreported"'byHuidiZhangetal.ThispaperdescribesthestructureelucidationofanewIignanglucoside,namedtibeticosideA1... 相似文献
920.
Synthesis and Characterization of Liquid Crystal with Lower Temperature of Phase Change of meso-tetra-(4-n-lauroyloxyphenyl)porphyrin 总被引:2,自引:0,他引:2
Metalloporphyrincomplexeshavebeenextensivelystudiedinmanyfunctionalchemistrytieldssuchasphoto-eletronicconversionnon-linearoptics,biomimeticstudiesandcatalyticefttcts.TOourknowledge,thefirstliquidcrystallineporphyrinwassynthesizedbyGoodbyelall.In1987,Greggetapreportedthesynthesisandtheliquidcrystallinepropertiesofaseriesofporphyrinoctanolesters.In1987,Greggelal3synthesizedoctakis(0-hydroxyethyl)porphyrin.In1991,tetrakis(4-n-lauroylphenyl)porphyrinwaspreparedbyShimizuetal#.In1994,5.15-disubs… 相似文献