首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   231篇
  免费   9篇
  国内免费   4篇
化学   207篇
晶体学   3篇
力学   4篇
数学   12篇
物理学   18篇
  2024年   1篇
  2023年   2篇
  2022年   3篇
  2021年   5篇
  2020年   15篇
  2019年   21篇
  2018年   15篇
  2017年   7篇
  2016年   13篇
  2015年   16篇
  2014年   11篇
  2013年   15篇
  2012年   25篇
  2011年   14篇
  2010年   19篇
  2009年   17篇
  2008年   12篇
  2007年   10篇
  2006年   4篇
  2005年   6篇
  2004年   1篇
  2003年   2篇
  2002年   2篇
  2001年   1篇
  1999年   1篇
  1998年   1篇
  1993年   1篇
  1992年   1篇
  1985年   1篇
  1980年   1篇
  1975年   1篇
排序方式: 共有244条查询结果,搜索用时 15 毫秒
81.
In the current protocol, the arene diazonium saccharin derivatives were initially produced from various substituted aromatic amines; subsequently, these intermediates were treated with a greener organic iodide for the preparation of the aryl iodide. We tried to choose low-cost, commercially available, biodegradable, recoverable, ecofriendly, and safe reagents and solvents. The arene diazonium saccharin intermediates could be stored in the liquid phase into a refrigerator for a long time with no significant loss activity. The outstanding merits of the current protocol (a) included the partial recovering of saccharin and tetraethylammonium salt, (b) reduce the use of solvents and the reaction steps due to eliminating separation and purification of intermediates, (c) good yield of the sterically hindered substrates, and (d) avoid the generation of heavy metal or corrosive waste.  相似文献   
82.
We describe a method for the modification of gold nanoparticles (Au-NPs) with benzo-15-crown-5 that led to the development of a colorimetric assay for Ag(I) ion. The brown color of a solution of the modified Au-NPs turns to purple on addition of Ag(I) ion. The ratio of the UV–vis absorption at 600 nm and 525 nm is proportional to the concentration of Ag(I) ions in the range from 20 to 950 nM, and the detection limit is 12.5 nM. Other metal ions do not interfere if present in up to millimolar concentrations. The method enables a rapid determination of Ag(I) in lake and drinking water and is amenable to bare-eye readout.
Figure
The selective colorimetric detection of Ag+ ion using gold nanoparticles modified with benzo crown ether is reported with a color detection limit ~50 nM by naked-eye. The feasibility and simplicity of this cost-effective sensing system demonstrates great potential for the detection of sliver ion in real samples.  相似文献   
83.
In the present work, adhesion, leak rate, and chemical compatibility of a series of borosilicate-based glasses, belonging to the ternary BaO–SiO2–B2O3 system, with AISI 430 alloys as interconnect were investigated for solid oxide fuel cell applications. Wetting angle and deformation behavior of the selected glasses with temperature and time were initially characterized with the hot-stage microscope. It was observed that the temperature ranges of wetting for all combinations were greater than 1000 °C. Significant deformation did not appear in the samples over soaking time at sealing temperature. In the next step, the leakage tests of AISI430/glass-ceramic couples were performed. The sample containing 32 % molar BaO (Ba32) had no gas leakage; a low leak rate of 10?7to 10?8 Pam3 s?1 was obtained for the glass with 37 % molar BaO (Ba37) and big leak of the system (10?3to 10?4 Pam3 s?1) for Ba42. Possible interfacial reactions between the as-received glass and cell ingredients and aging up to 100 h were studied by scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy and X-ray dot mapping. The results showed that the Ba32 and Ba37 glasses coupled with AISI had fine adhesion, which remained stable under these conditions and were compatible with the interconnect. So, the use of these glass-ceramics will probably be successful in joining the ceramic electrolytes to the metallic interconnect.  相似文献   
84.
85.
The new dibasic NNO ligand H2L (H2L = allyl N′-2-hydroxy-3-methoxybenzylidenecarbamohydrazonothioate) was synthesized by condensation of 2-hydroxy-3-methoxybenzaldehyde with the product resulting from the reaction of thiosemicarbazide with allyl bromide. Four dioxidomolybdenum(VI) complexes with the general formula [MoO2L(S)] (S=MeOH, EtOH, DMSO, and 1-methylimidazole) were synthesized and characterized by elemental analysis, FT-IR, EI-MS and UV-Vis spectroscopy, and by X-ray crystallography. Spectroscopic evidence indicates that the cis-MoO2 chelates have octahedral geometry in which H2L coordinates via the phenolate oxygen, azomethine nitrogen and deprotonated thioamide nitrogen. The other sites are occupied by two oxido and an additional ligand (S). Density functional theory calculations of spectral parameters were also carried out for these systems.  相似文献   
86.
Differential pulse and cyclic voltammetry were applied for the oxidation of mixture of uric acid and ascorbic acid at the surface of carbon paste/cobalt Schiff base composite electrode. The electrooxidation of these compounds at bare electrode is sluggish, and there is no suitable peak separation between them. However, using cobalt methyl salophen as modifier, two well-defined anodic waves with a considerable enhancement in the peak current and a remarkable peak potential separation near 315 mV are obtained. It can improve the kinetics of electron transfer for both compounds remarkably. All these improvements are created because of the electrocatalytic property of cobalt Schiff base complex. The effect of some parameters such as pH and scan rates were studied. All the anodic peak currents for the oxidation of ascorbic acid and uric acid shifted toward more negative potential with an increase in pH, revealing that protons have taken part in their electrode reaction processes. The best peak separation with appropriate current was obtained for pH 4.0. A linear range of 5.0?×?10?4 to 1.0?×?10?8 and 1.0?×?10?3 to 1.0?×?10?8 M with detection limit of 8.0?×?10?9 and 8.0?×?10?9 M was obtained for ascorbic acid and uric acid using differential pulse voltammetry at the surface of modified electrode, respectively. Analytical utility of the modified electrode has been examined successfully using human urine samples and vitamin C commercial tablets.  相似文献   
87.
In this work, the small signal gain (γ0) and signal saturation power (Psat) of a continuous wave (CW) single-frequency ytterbium-doped (YD) double-clad (DC) fiber master oscillator power amplifier (MOPA) array has been determined in the optimum length. At first, we have obtained output versus input signal powers in the amplifier, using the coupled steady-state rate equations for the various end diode pumping such as co/counter propagation and bidirectional modes. On the other hand, the steady-state amplification relation was employed at a presumed γ0 and Psat as initial guess, to generate output signals. Then, using the least square method (LSM), those input/output signal powers were fitted by the best regression curve obtained from the amplification relation to determine the converged γ0 and Psat values. The analytical formulae for γ0 and Psat were derived using the rate equations as well.  相似文献   
88.
Based on Lagrangian multiplier method (LMM), the gain spectrum of distributed multi-pump Raman amplifier (DMRA) is optimized. Beside of governing rate equations in Raman amplifiers, we consider two applicable constrains on cost function for optimizing the gain spectrum. Because of more accurate and controllable designing of DMRAs, a maximum power for each input pump wave is considered as well as average gain value as two constrains. LMM reduces the optimization problem with constrains to solve a two-point boundary value problem for each solution. This method is applied to minimizing gain ripple of full bandwidth (60 nm) a 100 Km Raman amplifier for different number of pumps.  相似文献   
89.
An effective route to functionalized furamide derivatives is described. This involves reaction of N-alkyl-3-oxobutanamides, derived from the addition of amines to the diketene, and dibenzoylacetylene in the presence of triphenylphosphoine. The reactive 1:1 intermediate obtained from the addition of triphenylphosphine to dibenzoylacetylene was trapped by OH-acids such as N-alkyl-3-oxobutanamide to produce functionalized furamide derivatives.  相似文献   
90.
Treatment of pyridine-2,6-dicarboxylic acid and 2-aminopyrimidine with Co(NO3)2?6H2O under hydrothermal conditions led to a new Co (II) complex [Co(amp)(pydc)(H2O)2]?H2O (1), which was characterized by infrared spectroscopy, elemental analysis as well as X-ray diffraction studies. The DNA-binding behavior of the complex has been studied by UV–Vis absorption and fluorescence spectroscopic titration, viscosity measurements, thermal denaturation and circular dichroism (CD). The experimental results indicated that Co (II) complex was bound to DNA by an intercalative mode. The intrinsic binding constant of Co (II) complex with DNA was (3.80 ± 0.02) × 104 M?1. The biological effects of the Co (II) complex were also studied by MTT assay in MCF-7 and HT-29 cancer cell lines. Treatment of MCF-7 and HT-29 cells with Co (II) complex resulted in a concentration-dependent cell growth inhibition.  相似文献   
[首页] « 上一页 [4] [5] [6] [7] [8] 9 [10] [11] [12] [13] [14] 下一页 » 末  页»
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号