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901.
Jun Shen Jue Wang Jiwei Zhai Yanzhi Guo Guangming Wu Bin Zhou Xingyuan Ni 《Journal of Sol-Gel Science and Technology》2004,31(1-3):209-213
Carbon aerogels derived from organic sol-gel process and supercritical drying are novel porous materials with interconnect structures and higher electrical conductivity, which are considered to be ideal electrode materials for supercapacitors and rechargeable batteries. The objective of the research was to synthesize carbon aerogel films at ambient conditions. Resorcinol formaldehyde (RF) and carbon aerogel films have been produced with extremely high RC ratio (molar ratio of resorcinol to catalyst) followed by subcritical drying. The structure of the porous films was investigated using electron scanning microscope. The specific surface area was measured by using nitrogen adsorption (BET) and electrical conductivity was measured with four-probe method. It was found that with extremely high RC ratio, the porous structure of RF and carbon aerogel films can be controlled from micro to macro porous at ambient conditions. With respect to the application as electrodes for fuel cells, carbon aerogel films with different porous structures on the two surfaces have been also obtained through optimizing the sol-gel process. 相似文献
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稀土环己烷酸配合物合成及振动光谱研究 总被引:2,自引:0,他引:2
The solid state complexes of trivalent lanthanid, yttrium and scandium with cyclohexane carboxylic acid have been isolated and characterized by IR and Raman spectroscopy. It was found that there are only chelated carboxylate groups in the scandium complex and that there are the chelated, bridged and chelate-bridged carboxylate groups in other rare earth complexes. The former is a mononuclear complex and the latter is a polynuclear polymer. The RE—O coordinate bonds possess the characters of convalent ionic bond. 相似文献
907.
偏最小二乘(PLS)分光光度法同时测定镉,汞,铅 总被引:6,自引:0,他引:6
本文研究了溴化十六甲铵基(CTMAB)存在时,meso-四(4-磺酸苯基)卟啉(TPPS4)与Cd(II),Hg(II),Pb(II)在室温下发生高灵敏度的显色反应条件以及应用偏最小二乘(PLS)法同时测定三组分的方法。由微型计算机处理实验数据可心到三组分的浓度,本文还定义了未知样品与标准样之间的相关系数Qr,通过Qr值的大小预报未知样测试结果的准确性,利用此法可以提高测定速度,可靠性和选择性。 相似文献
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ZHAO Haiying NI Yi JIANG Wei LUO Peiqing HUANG Meizheng YIN Guangzhong & DOU Xiaoming . Institute of Optics Engineering Shanghai Jiaotong University Shanghai China . Suzhou No. People’s Hospital Suzhou China 《中国科学B辑(英文版)》2005,48(3):240-245
In recent years, surface-enhanced Raman scattering (SERS) has been a topic of keen interest with regard to the detection of trace biological materials[1―8]. A wide range of SERS studies aimed at investigating structure, topology, and composition of biome… 相似文献
909.
CO2加氢生成醋酸的研究 总被引:2,自引:0,他引:2
CO2加氢生成醋酸的研究范宾张成芳陆岗俞丰倪燕慧(华东理工大学化工工艺研究所,上海200237)关键词二氧化碳加氢,醋酸,铑催化剂关于CO2加氢直接生成醋酸,国内外学者研究得很少,日本的Noriguki报道了[1]在CO2催化加氢反应中有少量醋... 相似文献
910.
Xi-gao Jin Zhong Jiang Ming Ni Feng-lian Bai Ren-yuan Qian Institute of Chemistry Chinese Academy of Sciences Beijing China 《高分子科学》2000,(5):465-468
The effect of self absorption on the ratio of excimer to monochromophore emission intensities, I_e/I_m, has beenexplored by experimentally changing the solution layer thickness of the emission light path traversed in the solution in theright-angle geometry. The result shows that data obtained by front-face geometry are better than those obtained by right-angle geometry even after correction to zero solution thickness. The correction formula based on geometric optics given byTsai and Torkelson is not adequate. 相似文献