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171.
Yonggang Shangguan Li Zhao Liyang Tao Qiang Zheng 《Journal of Polymer Science.Polymer Physics》2007,45(13):1704-1712
The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007 相似文献
172.
The clusters of Eu3+ ion in Eu(DBM)3Phen-doped polymethyl methacrylate (PMMA) have been studied by three means. The relative fluorescence intensity ratio of the 5D0 → 7F2 to 5D0 → 7F1 transitions with different concentrations of Eu3+ in Eu(DBM)3Phen-doped PMMA and metastable-state (5D0) lifetime dependence on Eu3+ concentration are analyzed. The analysis indicates that there are no clustering effects in Eu3+ ions of Eu(DBM)3Phen-doped PMMA when the Eu3+ doping concentration is up to 1.0 wt.-%. At the same time, the clustering effect has not been observed by the scanning near-field optical microscopy (SNOM) in Eu(DBM)3Phen-doped PMMA with 1.0 wt.-% of Eu3+ ions. The analysis reveals that a high concentration of Eu3+ can be incorporated into polymer optical fiber (POF) without clustering effect.OCIS codes: 180.5810, 300.6280, 250.5460, 160.5690. 相似文献
173.
174.
The central zinc(II) atom in the title complex is tetrahedrally coordinated by four nitrogen atoms derived from 4‐methyl‐5‐imidazolecarboxyaldehyde ligands with Zn? N in the range 2.007(3) to 2.026(4) Å. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
175.
讨论了W12[a,b]能否扩大为含有有间断点函数的再生核空间的问题.结论是:若再生核空间W W12[a,b]含有有间断点的函数,则间断点必固定、间断点个数必有限且非端点a,b.进一步,我们构造了函数含有n个间断点的再生核空间并给出其再生核表达式. 相似文献
176.
A series of 4,6-disubstituted pyrimidines were synthesized via Suzuki and Kumada coupling reaction of 4,6-dichloropyrimidine. 相似文献
177.
Jing Lin CHEN Gang Qiang YIN Zhong Ning CHEN* State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Fuzhou 《中国化学快报》2003,(5)
Great attention is currently paid to the synthesis of polynuclear transition metal complexes as well as their photochemical, photophysical, and electrochemical properties. The design of multicomponent systems capable of performing useful light- and/or redox-induced function is of special interest1. The oxo-centered carboxylate-bridge trinuclear ruthenium clusters have been investigated extensively during recent decades because they have remarkable electron-transfer properties, intense visibl… 相似文献
178.
Zheng Yu 《manuscripta mathematica》2003,111(2):163-186
In this paper, the negative gradient flow for the L
2-integral of Ricci curvature on a 3-manifold is considered. It is not known whether the solution to this fourth order geometric
evolution equation exists, and whether it will develop singularities in finite time. Based on the trick of De Turck and the
idea of Hamilton on the flow of Ricci curvature, the local existence on any compact Riemannian manifold is obtained. In addition,
the conditions for the occurences of singularities in finite time during the evolution and the asymptotic behavior of the
flow on a 3-manifold are discussed.
Received: 22 April 2002 / Revised version: 5 January 2003
Published online: 24 April 2003
This work is partially supported by the Foundations of NNSF of China, the Foundation for University Key Teacher by MEC and
Shanghai Priority Academic Discipline. 相似文献
179.
Clifford algebra corresponds to Minkwoski space. The coupling between real object particles and light quantums can be discussed
by Minkowski space’s directional strangeness. We introduce Galilei transfomation and Schr?dinger equation into Minkowski space
and give a geometrical explanation for classical quantum theory. 相似文献
180.
Zhigang Yin Nuofu Chen Shulin Song Jun Zhong Kurash Ibrahim 《Solid State Communications》2005,135(7):430-433
Nickel-doped ZnO (Zn1−xNixO) have been produced using rf magnetron sputtering. X-ray diffraction measurements revealed that nickel atoms were successfully incorporated into ZnO host matrix without forming any detectable secondary phase. Ni 2p core-level photoemission spectroscopy confirmed this result and suggested Ni has a chemical valence of 2+. According to the magnetization measurements, no ferromagnetic but paramagnetic behavior was found for Zn0.86Ni0.14O. We studied the electronic structure of Zn0.86Ni0.14O by valence-band photoemission spectroscopy. The spectra demonstrate a structure at ∼2 eV below the Fermi energy EF, which is of Ni 3d origin. No emission was found at EF, suggesting the insulating nature of the film. 相似文献