全文获取类型
收费全文 | 1336篇 |
免费 | 137篇 |
国内免费 | 189篇 |
专业分类
化学 | 1108篇 |
晶体学 | 10篇 |
力学 | 104篇 |
综合类 | 6篇 |
数学 | 141篇 |
物理学 | 293篇 |
出版年
2024年 | 6篇 |
2023年 | 31篇 |
2022年 | 56篇 |
2021年 | 56篇 |
2020年 | 73篇 |
2019年 | 67篇 |
2018年 | 54篇 |
2017年 | 44篇 |
2016年 | 75篇 |
2015年 | 52篇 |
2014年 | 64篇 |
2013年 | 87篇 |
2012年 | 113篇 |
2011年 | 117篇 |
2010年 | 78篇 |
2009年 | 82篇 |
2008年 | 75篇 |
2007年 | 91篇 |
2006年 | 52篇 |
2005年 | 62篇 |
2004年 | 46篇 |
2003年 | 29篇 |
2002年 | 37篇 |
2001年 | 15篇 |
2000年 | 23篇 |
1999年 | 19篇 |
1998年 | 32篇 |
1997年 | 30篇 |
1996年 | 24篇 |
1995年 | 6篇 |
1994年 | 11篇 |
1993年 | 11篇 |
1992年 | 9篇 |
1991年 | 6篇 |
1990年 | 10篇 |
1989年 | 8篇 |
1988年 | 7篇 |
1986年 | 2篇 |
1979年 | 2篇 |
排序方式: 共有1662条查询结果,搜索用时 31 毫秒
141.
探索了采用CST软件和PSpice软件进行加速器场分布数值模拟的方法,利用该方法可方便地获取设备内部动态场分布图及动态电压变化规律。针对螺旋线型μs级高压长脉冲产生器系统建立了数值模拟模型,给出了详细的模拟步骤及结果。分析表明,利用场分布模拟方法获取的电压变化规律与电路模拟方法获取的结果是一致的。基于CST模拟方法,可以给出螺旋线及主开关等电气结构的瞬态电场分布,场强增强点主要出现在螺旋带的外沿及金属电极连接处,在介质支撑内部也有较高的场强分布。 相似文献
142.
In this paper, the class of total asymptotically nonexpansive mappings is considered. A weak convergence theorem of Mann-type iterative algorithm is established. Hybrid projection methods are considered for the class of total asymptotically nonexpansive mappings. Strong convergence theorems are also established in the framework of Hilbert spaces. 相似文献
143.
Donghong Yang Minxian Zi Beshen Chen Zhiqiang Gao 《Journal of Electroanalytical Chemistry》1999,470(2):114
Self-assembled monolayers of poly(3-alkylthiophene) on gold electrodes are examined by cyclic voltammetry in solutions containing electroactive species. Two well-separated electron transfer processes, namely, electron tunneling through the monolayer and electron exchange at pinholes (defects) of the monolayer are observed. The voltammetric responses of the pinhole electron transfer process take place around the standard potential of the electroactive species and resemble those of a nanoelectrode ensemble of independent individual nanoelectrodes. The voltammetric characteristics of the electron tunneling agree well with predictions of the Marcus theory. Satisfactory values of tunneling coefficient, standard rate constant and organization energy are derived from the voltammetric data. 相似文献
144.
Zhiqiang Xu 《Journal of Approximation Theory》2011,163(3):377-387
In this paper, we use multivariate splines to investigate the volume of polytopes. We first present an explicit formula for the multivariate truncated power, which can be considered as a dual version of the famous Brion’s formula for the volume of polytopes. We also prove that the integration of polynomials over polytopes can be dealt with by using the multivariate truncated power. Moreover, we show that the volume of cube slicing can be considered as the maximum value of the box spline. On the basis of this connection, we give a simple proof for Good’s conjecture, which has been settled before by probability methods. 相似文献
145.
The heat of formation of a number of key C1 and C2 chlorofluorocarbons and hydrochlorofluorocarbons have been calculated by G3, G3MP2, G3MP2B3 and G3B3 methods. Based on the results of the atomization approach, it was found that the errors are approximately dependent upon the number of C-F or C-Cl bonds. Moreover, the bond additive correction (BAC) procedure and isodesmic reactions approach improved the accuracy and decreased these system errors significantly. The extended comparison between the BAC procedure and isodesmic reaction approaches had been made; the latter yielded the best results and showed broader applicability. 相似文献
146.
trans‐Dichlorotetrapyridineruthenium(II) [trans‐RuCl2(py)4] was synthesized and the structure was determined by single crystal X‐ray crystallography. Highly efficient formation of propylene carbonate (PC) from carbon dioxide and propylene oxide was achieved by using a catalyst system composed of trans‐RuCl2(py)4 and hexadecyl trimethyl ammonium bromide under mild conditions (4h, 80 °C, 3.0 MPa). PC was obtained in nearly 100% selectivity without the formation of a polymer. The catalyst could be recycled constantly many times without any significant loss of its catalytic activity. On the basis of the results, a mechanism for the reaction was proposed. Copyright © 2010 European Peptide Society and John Wiley & Sons, Ltd. 相似文献
147.
148.
A new numerical method is proposed to solve the Boltzmann equation. A frame is set up by using a discrete velocity approximation in the infinite velocity space, but by considering only those distribution function points which are not too small. The distribution function points may occur anywhere in the infinite discrete velocity space and are not constrained to a pre-specified region. A fourth-order finite difference is used for the convection terms. A Monte Carlo-like method is applied to the discrete velocity model of the collision integral. The effort of the method is proportional to the number of discrete points. Numerical examples are given for the full Boltzmann equation and results for some benchmark problems are compared with analytical or prior solutions. 相似文献
149.
等变集压缩场的零点指标公式 总被引:4,自引:0,他引:4
本文在紧致李群作用下的Banach空间中,讨论了等变严格集压缩场的正则零点轨道的指标计算问题,推广了(1),(2)的结果。 相似文献
150.
Qi Wang Lidong Li Zhiqiang Fan 《Journal of polymer science. Part A, Polymer chemistry》2005,43(8):1599-1606
In the presence of tetraethylaluminoxane (TEAO), iron complexes were used to catalyze ethylene polymerizations with extremely high activities and generally produced polyethylene with a bimodal molecular weight distribution (MWD). This bimodal MWD of polyethylene was mainly derived from residual triethylaluminum in TEAO and was produced through a mechanism of chain transfer to aluminum. Ethylaluminoxane and tetraisobutylaluminoxane also were used to polymerize ethylene with high activities in the presence of iron complexes, and only polyethylene with a unimodal MWD was produced. The ratio of the rate constant of chain transfer to aluminum (ktrA) to the rate constant of chain propagation (kp) was determined to be 0.12 for {[ArN?C(Me)]2C5H3N}FeCl2 when Ar was 2,6‐diisopropylphenyl ( 1 ) and 2.48 for {[ArN?C(Me)]2C5H3N}FeCl2 when Ar was 2,6‐dimethylphenyl ( 2 ); these values are far larger than those for metallocene‐based catalysts. This explains why an iron complex usually produces polyethylene with a broader MWD than metallocene‐based catalysts. Additionally, it can be concluded from the great difference between 1 and 2 with respect to ktrA/kp that an iron complex with less congested aryl substituents is subjected to chain transfer to aluminum. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1599–1606, 2005 相似文献