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991.
Huang JY Ning YS Yong KS Cai YH Tang HH Shao YX Alshahateet SF Sun YM Xu GQ 《Langmuir : the ACS journal of surfaces and colloids》2007,23(11):6218-6226
The adsorption of glycine and l-cysteine on Si(111)-7 x 7 was investigated using high-resolution electron energy loss spectroscopy (HREELS) and X-ray photoelectron spectroscopy (XPS). The observation of the characteristic vibrational modes and electronic structures of NH3+ and COO- groups for physisorbed glycine (l-cysteine) demonstrates the formation of zwitterionic species in multilayers. For chemisorbed molecules, the appearance of nu(Si-H), nu(Si-O), and nu(C=Omicron) and the absence of nu(O-H) clearly indicate that glycine and l-cysteine dissociate to produce monodentate carboxylate adducts on Si(111)-7 x 7. XPS results further verified the coexistence of two chemisorption states for each amino acid, corresponding to a Si-NH-CH2-COO-Si [Si-NHCH(CH2SH)COO-Si] species with new sigma-linkages of Si-N and Si-O, and a NH2-CH2-COO-Si [NH2CH(CH2SH)COO-Si] product through the cleavage of the O-H bond, respectively. Glycine/Si(111)-7 x 7 and l-cysteine/Si(111)-7 x 7 can be viewed as model systems for further modification of Si surfaces with biological molecules. 相似文献
992.
The highly ordered Si nanotube (SiNT) arrays have been fabricated and demonstrated to be an attractive matrix to accommodate macromolecules, such as proteins, and exhibit facile direct electrochemistry of cytochrome c without any pretreatment. A pair of well-defined redox waves can be observed in the aqueous solution containing cytochrome c on this SiNT electrode using cyclic voltammetry. The peak separation (DeltaEp) between the anodic and the cathodic peaks is 63 mV at the sweep rate of 10 mV/s, and the peak current is proportional to the square root of the sweep rates, which indicates that the redox process is a quasi-reversible process. The experimental results show that the good biocompatibility and nanoscale hollow structure of the SiNT arrays can be applicable to preparing Si-based biosensors and protein characterizations. 相似文献
993.
邵孝湟 《应用数学和力学(英文版)》1991,12(10):1001-1008
In this paper,using the differentiability of the solution with respect to the initial value and the parameter,we present a method which,different from Liapunov’s direct method.will determine the stability of the non-stationary solution of the initial value problem when the non-stationary solution remains unknown. 相似文献
994.
995.
996.
以丁基替换环己基,合成了20种二丁基一环己基锡羧酸酯。利用IR、NMR及元素分析表征了化合物的结构,确定了化合物的质谱裂解机制。对化合物进行了生物活性普筛试验。结果表明,这类化合物同时具有高效杀菌和杀螨活性。 相似文献
997.
998.
Y.H. Ren Q.H. Chen Y.B. Yu Z.A. Xu W.B. Shao Z.K. Jiao 《The European Physical Journal B - Condensed Matter and Complex Systems》1999,7(4):651-656
Within the framework of the second-order Rayleigh-Schr?dinger perturbation theory, we investigate the effects of the interaction
of the electron and longitudinal-optical phonons in two-dimensional semiconductive quantum dots with respect to a general
potential. We propose a simple expression for the ground state energy, and compare it with those obtained by Landau-Pekar
strong coupling theory. It is shown both analytically and numerically that the results obtained from the second-order Rayleigh-Schr?dinger
perturbation theory could be better than those from Landau-Pekar strong coupling theory when the coupling constant is sufficiently
small. Moreover, some interesting problems, such as polarons in quasi-one-dimensional quantum wires, and quasi-zero-dimensional
asymmetric or symmetric quantum dots can be easily discussed only by taking different limits. After the numerical calculations,
we find that there exists a simple dimensional scaling and symmetry relation for the ground state polaron energy. Furthermore,
we apply our results to some weak-coupling polar semiconductors such as GaAs, CdS. It is shown that the polaronic effects
are found to be quiet appreciable if the confinement lengths and smaller than a few nanometers.
Received: 3 December 1997 / Revised: 6 July 1998 / Accepted: 17 September 1998 相似文献
999.
2-羟基-3-羧基-5-磺酸基苯基重氮氨基偶氮苯吸光光度法测定微量钯 总被引:2,自引:0,他引:2
于pH9.3~10.6Na_2CO_3-NaHCO_3缓冲介质中,在Triton N-101存在下,Pd(Ⅱ)与2-羟基-3-羧基-5-磺酸基苯基重氮氨基偶氮苯(HCSDAA)形成组成比为1:2的红色配合物,其最大吸收波长为530nm,表观摩尔吸光系数为1.05×10~5,线性范围为0~0.7μg·ml~(-1) .结合丁二酮肟螯合,氯仿萃取,方法用于贵金属二次合金中微量钯的测定,相对标准偏差为2.0%(n=6).加标回收率为93.8%~99.3%. 相似文献
1000.
研究了在常压下,由甲酸甲酯与NH3反应生产甲酰胺的催化新工艺,比较了不同反应器、加或不加催化剂。催化剂活性组分含量、催化剂粒度大小及装量等对反应的影响,并考察了不同反应温度、NH3流量、反应时间与甲酰胺收率的关系,结果表明用催化新工艺在2g-M-10催化剂上,加20mL甲酸甲酯,NH4流量为4L/h,反应温度7℃,反应2h后,甲酰胺收率可达99%。 相似文献