Solvent-free cross-dehydrogenative coupling reactions under high speed ball-milling conditions applied to the synthesis of functionalized tetrahydroisoquinolines

Solvent-free reaction using a high-speed ball milling technique has been first applied to cross-dehydrogenative coupling (CDC) reactions between tetrahydroisoquinolines and three types of pronucleophiles such as nitroalkanes, alkynes, and indoles. All coupling products were obtained in good yields at short reaction times (no more than 40 min). When alkynes and indoles were used as pronucleophile, the reactions can be catalyzed efficiently by recoverable copper balls without any additional metal catalyst.     

Constrained large-eddy simulation of turbulent flow over inhomogeneous rough surfaces

In this work we extend the method of the constrained large-eddy simulation(CLES) to simulate the turbulent flow over inhomogeneous rough walls. In the original concept of CLES, the subgrid-scale(SGS) stress is constrained so that the mean part and the fluctuation part of the SGS stress can be modelled separately to improve the accuracy of the simulation result. Here in the simulation of the rough-wall flows, we propose to interpret the extra stress terms in the CLES formulation as the roughness-induced stress so that the roughness inhomogeneity can be incorporated by modifying the formulation of the constrained SGS stress. This is examined with the simulations of the channel flow with the spanwise alternating high/low roughness strips. Then the CLES method is employed to investigate the temporal response of the turbulence to the change of the wall condition from rough to smooth. We demonstrate that the temporal development of the internal boundary layer is just similar to that in a spatial rough-tosmooth transition process, and the spanwise roughness inhomogeneity has little impact on the transition process.     

圆柱螺旋电磁Wiggler的场形分析

 利用载流圆柱螺旋线系统内部的磁标势满足的Laplace方程, 以及系统磁矢势的积分形式, 定出Laplace方程通解的未知系数, 求得左(右)旋单绕圆柱螺旋线的磁标势。应用磁场的叠加原理以及积分法, 给出了各种类型如双绕、双双绕、交叉绕等螺旋形Wiggler的场形分布公式。     

Arrayed waveguide grating multiplexer with high thermal stability on silicon

In this paper, certain important parameters are optimized for a polymer/Si arrayed waveguide grating (AWG) multiplexer by using grating theory. A 32-channel multiplexer is designed and fabricated using newly synthesized fluorinated poly (ether ether ketone) with a high thermal stability. The measured wavelength channel spacing is 0.796 nm, and center wavelength and 3-dB bandwidth are 1548 nm and 0.3 nm, respectively.     

中红外光纤技术用于腮腺肿瘤诊断的研究

采用傅里叶变换红外光谱法与中红外光导纤维联用技术对１１例肿瘤，７例正常腮腺和１例舍格伦综合症的红外光谱进行了对比研究。结果发现正常腮腺和舍格伦综合症的红外光谱很相似，而与肿瘤的光谱存在着明显差别，同时也观察到良性与恶性肿瘤的光谱在若干波段处也有所不同．     

六层加侧混合型摇摆器磁场的理论计算与数值模拟

 利用文献[1，2]给出的结果，提供了六层加侧混合型摇摆器中永磁体磁场的计算公式和软铁磁场计算的积分方程式。对周期长度lw =1.6cm，磁极间隙g=0.5cm的情况，计算了单向聚焦和双向聚焦两种不同构形的磁场分布，并得到了g /lw =1/3条件下，峰值磁场Bw超过1特斯拉的设计指标。     

基于平行投影法的三维流场重建

在行处理方法的基础上提出了一种基于平行投影的迭代方法，对传统的行处理方法不同，它不是通过向某一超平面作垂线进行迭代，而是作某个超平面的平行线与另一超平面相交进行迭代。与传统方法相比，它明显加快了迭代速度。     

Nickel Complexes Bearing Bidentate Schiff Base as Ethylene Oligomerization Catalysts

Several nickel complexes [N,N]NiBr2, in which IN,N] indicates bidentate nitrogen-containing ligands (1: [N,N]=N-(2,6-diisopropylphenyl)pyridine-2-carboxaldimine (Cl8H22N2); 2: N-(2,6-diisopropylphenyl)-6-methylpyridine-2-carboxaldimine (C19H24N2); 3: N-(2,4,6-trimethylphenyl)pyridine-2-carboxaldimine(Cl5Hl6N2); 4: N-(2,4,6-trimethylphenyl)-6-methylpyridine-2-carboxaldlmlne (Cl6Hl8N2) were synthesized. Some of the nickel complexes exhibit high activity for ethylene oligomerization in the presence of an organoaluminum activator. The main factor affecting the activity and the structure of oligomers is the steric effect of substituents on [N,N] ligands. Methylaluminoxane (MAO) -activated catalysts showed higher activities and produced oligomers with higher molecular weight than Et2AlCl-activated ones. The oligomerization in toluene rather than hexane results in much higher activity, and the oligomers produced in toluene have relatively high molecular weight. With activation of MAO or Et2AlCl,the [N,N]NiBr2 system tended to produce highly branched oligomers with low α-olefin content, but the α-olefin content could be increased by changing the reaction conditions.