Synthesis of double silylene-bridged binuclear titanium complexes and their use as catalysts for ethylene polymerization

Five new double silylene-bridged binuclear titanium complexes were synthesized by the reaction of RCpTiCl₃ and Li₂[μ,μ-(SiMe₂)₂ (C₅H₃)₂] in toluene. They were all well characterized. These complexes activated with methylaluminoxane (MAO) are highly active catalysts (2.33 × 10⁵ g PE/mol Cat h) for the polymerization of ethylene even at low Al/Ti (Al/Ti = 300). The molecular weight distribution of the polymer indicates broad or bimodal (MWD = 26.76) distribution.     

关于Tchebycheff—Fourier级数的（H,λ）平均的逼近

我们定义了（Ｈ，λ）求和法，它含有（Ｎ，ｐｎ），（Ｒ＾ｒｎ）和（Ｖｍｎ）求和法。讨论了函数ｆ（ｘ）∈Ｃ＾ｒ［－１，１］（ｒ∈Ｎ０）以及ｆ（ｘ）∈Ｗ＾ｒＨ＾ａ（ｒ∈Ｎ０，０＜ａ＜１）的切比晓夫－富里埃级数的逼近阶。     

加权增量卡尔曼滤波法在ICP－AES中的应用

卡尔曼滤波法用于ＩＣＰ－ＡＥＳ分析时，在白色噪音情况下能给出准确的分析结果，当试样的某些组分未知时，测量噪音将不是白色的，分析结果将不准确。本文提出了一种加权增量卡尔曼滤波法来解决这个问题。     

受激布里渊散射相位共轭现象的二维数值模拟

 使用P.H.Hu等人[3，4]提出的计算途径，数值解了A.Flusberg等人[2]提出的零级方程。计算了布里渊池内随位置而变化的斯托克斯光强度、泵浦光强度和保真度，得到了布里渊池内几个位置上的斯托克斯光相位和强度的横向分布，并计算了泵浦光入口处的反射率和保真度。     

气密性碳涂覆光纤筛选强度与电阻关系研究

通过实验分析确立了把光纤电阻作为衡量气密性碳涂覆光纤通过２％应变筛选的过渡标准。要拉制２％应变筛选的碳涂覆光纤，其电阻值应小于３０ｋΩ／ｃｍ。     

激光二极管泵浦的高重复频率Nd：YAG激光器

报道两个１．５Ｗ连续激光二极管端面泵浦的声光调ＱＮｄ：ＹＡＧ激光器，输出激光脉冲的最高重复频率为３０ｋＨｚ重复频率１ｋＨｚ时，最窄脉宽为１２ｎｓ，最高峰值功率为１２．１ｋＷ。     

MnBiDy(Sm)永磁膜的结构和磁性

报道了采用真空蒸镀的方法制备的MnBiDy(Sm)永磁膜的结构和磁性.Mn:Bi:Dy(Sm)的投料比为2:1:0.10.薄膜经过退出处理(350—425℃,保温4h)后,具有NiAs型hcp结构,C轴垂直膜面,剩余磁感应强度B=3.4-6.5kG,内禀矫顽力_MH_c≈3-8kOe,最大磁能积(BH)_(max)=13.39MG·Oe.实验发现,薄膜厚度对MnBiDy(Sm)永磁膜的结构和磁性具有很大的影响. 关键词：     

Bombieri's theorem in short intervals

The well-known Bombieri-A. I. Vinogradov theorem states that (1) $$\sum\limits_{q \leqslant x^{\tfrac{1}{2}} (\log x)^{ - s} } {\mathop {\max }\limits_{(a,q) = 1} \mathop {\max }\limits_{y \leqslant x} } \left| {\psi (y,q;a) - \frac{y}{{\varphi (q)}}} \right| \ll \frac{x}{{(\log x)^A }},$$ whereA is an arbitrary positive constant,B=B(A)>0, and as usual, $$\psi (x,q;a) = \sum\limits_{\mathop {n \leqslant x}\limits_{n = a(q)} } {\Lambda (n),}$$ Λ being the Von Mangoldt's function. The problem of finding a result analogous to (1) for short intervals was investigated by many authors. Using Heath-Brown's identity and the approximate functional equation for DirichletL-functions, A. Perelli, J. Pintz and S. Salerno in 1985 established the following extension of Bombieri's theorem: Theorem 1. (2) $$\sum\limits_{q \leqslant Q} {\mathop {\max }\limits_{(a,q) = 1} \mathop {\max }\limits_{h \leqslant y} \mathop {\max }\limits_{\frac{x}{2}< \approx \leqslant x} } \left| {\psi (z + h,q;a) - \psi (z,q;a) - \frac{h}{{\varphi (q)}}} \right| \ll \frac{y}{{(\log x)^A }}$$ where A>0 is an arbitrary constant,y=x ^θ $$\frac{7}{{12}}< \theta \leqslant 1, Q = x^{\frac{1}{{40}}} .$$ ,Q=x ^1/40. By improving the basic lemma which A. Perelli, J. Pintz and S. Salerno used as the main tool to prove Theorem 1, we obtain Theorem 2.Under the same condition as in Theorem 1,for Q=x ^1/38.5, (2)still holds.     

三氯乙酸根离子选择电极的研制

以长链季铵盐为活性物研制成功PVC膜三氯乙酸根离子选择电极。该电极在1×10~(-1)～2×10~(-6)M Cl_3CCOO-离子浓度范围内显示良好的Nernst响应,检测下限为1.2×10~(-6)M。用固定干扰法测定了该电极对Ac~-、Cl~-,SO_4~-、H_2PO_4~-、HCO_3~-、CO_3~-,Cl_2CHCOO~-、NO_3~-等离子的选择性系数,仅NO_3~-有明显干扰。电极适用于中性、偏碱性溶液,在1×10~(-3)M Cl_3CCOONa溶液中,pH 7.0～12.5电势读数稳定。电极连续工作五小时电势变化为±1mV,可以作为一种分析三氯乙酸盐的简便快速方法。这对控制环境污染,判断职业中毒都十分重要。