New data on the stereochemistry of the rearrangement of the carane system to the 1-methyl-4-isopropylbicyclo[3.1.0]hexane system

Conclusions NMR spectroscopy was used to find the stereochemistry of a series of compounds with bicyclo[3.1.0]hexane structure obtained from carane derivatives as a result of rearrangement with transannular participation of the cyclopropyl ring and the stereochemistry of this rearrangement was considered.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1327–1333, June, 1982.     

Syntheses based on anabasine

N-Phenacyl salts of acetyl-, benzoyl-, and methylanabasine were synthesized for the first time. Their reactions with unsaturated carbonyl compounds of the ethylene and acetylene series and acrylonitrile were studied. Methods for the synthesis of 6- and 8-(2-piperidyl)indolizines were developed. For Part 1, see Ref. 1. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 135–145, January, 2008.     

Copper(ii) and manganese(ii) complexes based on a new N,O-chelating ligand bearing the 1,3,5-diazaphosphorinane moiety

Russian Chemical Bulletin - Copper(ii) and manganese(ii) chelate complexes were synthesized using the new N,O-hybrid ligand 1,3-dibenzhydryl-5-(pyridin-2-yl)-1,3,5-diazaphosphinane 5-oxide. The...     

N-Alkylation of Aniline and Its Derivatives by Alcohols in the Presence of Copper Compounds

Russian Journal of Organic Chemistry - N-Alkyl- and N,N-dialkyl-substituted anilines were obtained in the reaction of aniline and its derivatives with primary and secondary alcohols in the presence...